Molecular Sieves

Molecular Sieves

Author: Rosemarie Szostak

Publisher: Springer Science & Business Media

Published: 2013-06-29

Total Pages: 473

ISBN-13: 9401095299

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From areport by a Lieutenant Colonel W.A. Ross (Chern. News, Nov.15, 1878, p. 236). Progress did not accelerate during the next 50 years. McBain, in his clas sic 1932 book, The Sorption oi Gases by So lids, devoted a chapter to sorp tion by chabasite, other zeolites, and permeable crystals. McBain remarked that "great interest attaches to the finding of Weigel and Steinhoff [0. Weigel and E. Steinhoff, Z. Kris!., 61, 125 (1925{raquo}) that chabasite rapidly sorbs the vapors of water, methyl and ethyl alcohol and formie acid, whereas acetone, ether and benzene are largely excluded. The significance of their results was pointed out by McBain [J.W. McBain, Colloid. Syrnp. Mon., 20, 1 (1926{raquo}) and recognized by alliater writers. It is evident that the partially dehydrated chabasite forms a nearly perfect molecular sieve or a semipermeable membrane of extremely regular structure ... ". While the significance of the above observation may have been recog nized, it had little impact. Thus, an eminent pioneer in the synthesis and characterization af zeolites, Professor R.M. Barrer, spent nearly two dec ades (following his Ph. D. studies in the 1930s) developing a firm foundation for the rapid growth in scientific understanding and industrial applications of zeolites which has taken place during the last 30 years.


Mesoporous Molecular Sieves 1998

Mesoporous Molecular Sieves 1998

Author: L. Bonneviot

Publisher: Elsevier

Published: 1998-07-08

Total Pages: 633

ISBN-13: 0080536247

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The original properties of mesoporous molecular sieves are so unique that the design of most existing catalysts could be reconsidered. It might indeed be of interest to introduce MMS either as a support or as the active phase, merely on the basis of their high surface areas, narrow pore size distribution and flexibility in composition. The recent literature provides examples of MMS based catalysts of many types such as acid-base solids, supported metals and supported oxides, mixed oxides, anchored complexes and clusters, grafted organic functional groups and others. Examples of all these developments are documented in the present proceedings including some spectacular new proposals. The new metallic (Pt) mesophases are specially worth mentioning because they represent a new approach to producing non-supported highly dispersed metals.In these proceedings the reader will find feature articles and regular papers from many worldwide groups, covering all aspects of synthesis, physical characterization and catalytic reactivity of MMS and their chemically modified forms. It is actually remarkable that this recent development brought together an even broader spectrum of scientists from traditionally unrelated fields such as those of liquid crystals, surfactants, sol-gels, amorphous oxides and mixed oxides, solid state, adsorbents and heterogeneous catalysts. Obviously, this is a fast-growing research area which triggers the imagination and creativity at the cross-road between material design, molecular surface tailoring and catalytic applications.


Introduction to Zeolite Molecular Sieves

Introduction to Zeolite Molecular Sieves

Author: Jiri Cejka

Publisher: Elsevier

Published: 2007-10-02

Total Pages: 1095

ISBN-13: 008055041X

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Introduction to Zeolite Molecular Sieves, 3rd Edition presents a collection of the most important results and ideas in the field of molecular sieve chemistry and technology, the most important experimental techniques related to the research activities in molecular sieves, and identifies new areas of molecular sieve chemistry. Chapters start at a reasonably simple entry level, but also covers the present state-of-the-art in the field. Topics covered include structure, synthesis, characterization, ion exchange, adsorption, diffusion, separations, and natural zeolites.* 6 years since the last edtion this book brings together the rapid development within the field of molecular sieve chemistry and applications * Accessible to newcomers to the field, also containing valuable information for experienced researchers * 27 chapters written by renowned scientists in their field, including updates on some 2nd edition chapters


Handbook Of Molecular Sieves

Handbook Of Molecular Sieves

Author: Rosemarie Szostak

Publisher: Springer Science & Business Media

Published: 1992-09-30

Total Pages: 620

ISBN-13: 9780442318994

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This handbook is the only up-to-date, A to Z compilation of commercial and research zeolites. The volume presents complete patent-researched reference information on structural data, synthesis parameters, and characteristic properties. For each known zeolite there is an entry on all organics which crystallize a given structure, physical data, and applications. Data is presented in tabular or graphical form with minimal text, and a cross-referenced literature review is provided.


An Introduction to Zeolite Molecular Sieves

An Introduction to Zeolite Molecular Sieves

Author: Alan Dyer

Publisher: John Wiley & Sons

Published: 1988

Total Pages: 178

ISBN-13:

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This book provides a comprehensive introduction to zeolite science. Synthetic zeolites are important major catalysts in the oil industry, they are also important in the separation of gases from the air, in the treatment of nuclear wastes and as a component in detergents. In addition they are natural minerals with a unique role in mineralogy and occurences throughout the world. The book assesses the importance of zeolites in all these applications.


Guidelines for Mastering the Properties of Molecular Sieves

Guidelines for Mastering the Properties of Molecular Sieves

Author: Denise Barthomeuf

Publisher: Springer Science & Business Media

Published: 2013-03-08

Total Pages: 424

ISBN-13: 146845787X

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Low dimensionality is a multifarious concept which applies to very diversified materials. Thus, examples of low-dimensional systems are structures with one or several layers, single lines or patterns of lines, and small clusters isolated or dispersed in solid systems. Such low dimensional features can be produced in a wide variety of materials systems with a broad spectrum of scientific and practical interests. These features, in turn, induce specific properties and, particularly, specific transport properties. In the case of zeolites, low dimensionality appears in the network of small-diameter pores of molecular size, extending in one, two or three di mensions, that these solids exhibit as a characteristic feature and which explains the term of "molecular sieves" currently used to name these ma terials. Indeed, a large number of industrial processes for separation of gases and liquids, and for catalysis are based upon the use of this low dimensional feature in zeolites. For instance, zeolites constitute the first class of catalysts employed allover the world. Because of the peculiarity and flexibility of their structure (and composition), zeolites can be adapted to suit many specific and diversified applications. For this reason, zeolites are presently the object of a large and fast-growing interest among chemists and chemical engineers.


Molecular Sieves: From Basic Research to Industrial Applications

Molecular Sieves: From Basic Research to Industrial Applications

Author: Jiri Cejka

Publisher: Elsevier

Published: 2005-08-30

Total Pages: 2190

ISBN-13: 0080473512

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Due to their unique porous properties, zeolites (also referred to as molecular sieves) are used in a variety of applications - major uses are in petrochemical cracking, ion-exchange (water softening and purification), and in the separation and removal of gases and solvents. Molecular Sieves: From Basic Research to Industrial Applications, Volume 158 A,B presents over 265 worldwide contributions on the latest developments in zeolitic research. Readers will find this book, which is divided into five sections: Synthesis, Characterization, Adsorption, Catalysis, and Novel applications, ideal for staying up to date on current research on porous materials.* Comprehensive overview of current research on porous materials* Contains experimental as well as theoretical input, reflecting the increasing overlap between theory and experiment* Contributions from the world's leading authorities


Gel Chromatography Gel Filtration · Gel Permeation · Molecular Sieves

Gel Chromatography Gel Filtration · Gel Permeation · Molecular Sieves

Author: Helmut Determann

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 205

ISBN-13: 3642950825

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The efforts spent on many a scientific book cannot be justified, no matter how many words are said about it. The opposite is true for this book and a few brief remarks upon its publication. Within a short period of time, short even by all present standards, gel chromatography has gone through a development and experienced an acceptance that is unknown to any other method. From experience, the new and unique separation technique is today known and liked in all laboratories that are concerned with substances of high molecular weight; in others, the technique is known from hearsay, the least. Soon it became evident that a comprehensive coverage of the conceptual development, the theoretical principles, and the experimental technique of the new method would be desirable. This coverage is now offered by the book of an expert. Its author has personally participated in the development from its beginning and helped to promote it. He has made possible the gel chromatography, also of 'proteins, on thin layer plates; for lipophilic substances he has contributed considerably to the transition from water to organic solvent systems and developed theoretical concepts for a better understanding of the effects that are responsible for the separation. The book, so it appears to me, is pointing in new directions. The reader does not only expect a clear presentation of facts but also that of instructions for practical applications. Both these expectations have been met by the expert.


Purification of Laboratory Chemicals

Purification of Laboratory Chemicals

Author: W.L.F. Armarego

Publisher: Butterworth-Heinemann

Published: 2009-07-23

Total Pages: 761

ISBN-13: 0080878245

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A best seller since 1966, Purification of Laboratory Chemicals keeps engineers, scientists, chemists, biochemists and students up to date with the purification of the chemical reagents with which they work, the processes for their purification, and guides readerd on critical safety and hazards for the safe handling of chemicals and processes.The Sixth Edition is updated and provides expanded coverage of the latest chemical products and processing techniques, safety and hazards. The book has been reorganised and is now fully indexed by CAS Registry Numbers. Compounds are now grouped to make navigation easier and literature references for all substances and techniques have been added, and ambiguous alternate names and cross references have been removed. - The only comprehensive chemical purification reference, a market leader since 1966, Amarego delivers essential information for research and industrial chemists, pharmacists and engineers: '... (it) will be the most commonly used reference book in any chemical or biochemical laboratory' (MDPI Journal) - An essential lab practice and proceedures manual. Improves efficiency, results and safety by providing critical information for day-to-day lab and processing work. Improved, clear organization and new indexing delivers accurate, reliable information on processes and techniques of purification along with detailed physical properties. - The Sixth Edition has been reorganised and is fully indexed by CAS Registry Numbers; compounds are now grouped to make navigation easier; literature references for all substances and techniques have been added; ambiguous alternate names and cross references removed; new chemical products and processing techniques are covered; hazards and safety remain central to the book.