Adsorption and Diffusion in Nanoporous Materials

Adsorption and Diffusion in Nanoporous Materials

Author: Rolando M.A. Roque-Malherbe

Publisher: CRC Press

Published: 2018-02-12

Total Pages: 300

ISBN-13: 1351395750

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Offering a materials science point of view, the author covers the theory and practice of adsorption and diffusion applied to gases in microporous crystalline, mesoporous ordered, and micro/mesoporous amorphous materials. Examples used include microporous and mesoporous molecular sieves, amorphous silica, and alumina and active carbons, akaganeites, prussian blue analogues, metal organic frameworks and covalent organic frameworks. The use of single component adsorption, diffusion in the characterization of the adsorbent surface, pore volume, pore size distribution, and the study of the parameters characterizing single component transport processes in porous materials are detailed.


Adsorption Analysis: Equilibria And Kinetics (With Cd Containing Computer Matlab Programs)

Adsorption Analysis: Equilibria And Kinetics (With Cd Containing Computer Matlab Programs)

Author: Duong D Do

Publisher: World Scientific

Published: 1998-09-22

Total Pages: 915

ISBN-13: 1783262249

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This book covers topics of equilibria and kinetics of adsorption in porous media. Fundamental equilibria and kinetics are dealt with for homogeneous as well as heterogeneous particles. Five chapters of the book deal with equilibria and eight chapters deal with kinetics. Single component as well as multicomponent systems are discussed. In kinetics analysis, we deal with the various mass transport processes and their interactions inside a porous particle. Conventional approaches as well as the new approach using Maxwell-Stefan equations are presented. Various methods to measure diffusivity, such as the Differential Adsorption Bed (DAB), the time lag, the diffusion cell, chromatography, and the batch adsorber methods are also covered by the book. It can be used by lecturers and engineers who wish to carry out research in adsorption. A number of programming codes written in MatLab language are included so that readers can use them directly to better understand the behavior of single and multicomponent adsorption systems.


Adsorption and Diffusion

Adsorption and Diffusion

Author: Hellmut G. Karge

Publisher: Springer Science & Business Media

Published: 2008-06-17

Total Pages: 411

ISBN-13: 3540739661

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"Molecular Sieves - Science and Technology" covers, in a comprehensive manner, the science and technology of zeolites and all related microporous and mesoporous materials. The contributions are grouped together topically in such a way that each volume deals with a specific sub-field. Volume 7 treats fundamentals and analyses of adsorption and diffusion in zeolites including single-file diffusion. Various methods of measuring adsorption and diffusion are described and discussed.


Diffusion in Nanoporous Materials, 2 Volumes

Diffusion in Nanoporous Materials, 2 Volumes

Author: Jörg Kärger

Publisher: John Wiley & Sons

Published: 2012-10-29

Total Pages: 932

ISBN-13: 352731024X

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Atoms and molecules in all states of matter are subject to continuous irregular movement. This process, referred to as diffusion, is among the most general and basic phenomena in nature and determines the performance of many technological processes. This book provides an introduction to the fascinating world of diffusion in microporous solids. Jointly written by three well-known researchers in this field, it presents a coherent treatise, rather than a compilation of separate review articles, covering the theoretical fundamentals, molecular modeling, experimental observation and technical applications. Based on the book Diffusion in Zeolites and other Microporous Solids, originally published in 1992, it illustrates the remarkable speed with which this field has developed since that time. Specific topics include: new families of nanoporous materials, micro-imaging and single-particle tracking, direct monitoring of transient profiles by interference microscopy, single-file diffusion and new approaches to molecular modeling.


Handbook of Vacuum Technology

Handbook of Vacuum Technology

Author: Karl Jousten

Publisher: John Wiley & Sons

Published: 2016-06-14

Total Pages: 1050

ISBN-13: 3527688250

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This comprehensive, standard work has been updated to remain an important resource for all those needing detailed knowledge of the theory and applications of vacuum technology. The text covers the existing knowledge on all aspects of vacuum science and technology, ranging from fundamentals to components and operating systems. It features many numerical examples and illustrations to help visualize the theoretical issues, while the chapters are carefully cross-linked and coherent symbols and notations are used throughout the book. The whole is rounded off by a user-friendly appendix of conversion tables, mathematical tools, material related data, overviews of processes and techniques, equipment-related data, national and international standards, guidelines, and much more. As a result, engineers, technicians, and scientists will be able to develop and work successfully with the equipment and environment found in a vacuum.


Adsorption

Adsorption

Author: Li Zhou

Publisher: World Scientific

Published: 2007

Total Pages: 292

ISBN-13: 9812770259

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Adsorption is the basis of various emerging technologies that will be essential for addressing the problems of technologies that will be essential for addressing the problems of energy conservation and environmental protection.This volume reviews recent progress and outlines the outlook for future development in adsorption theories, kinetics, pressure swing adsorption, SMB, and new nanoporous adsorbents. The contributions cover the fundamental knowledge and methodologies for adsorption experiments and calculations regarding equilibria, heat effects, adsorbent structural modeling, diffusion measurement, and selectivity control.The volume also includes topics concerning hydrogen storage, desulfurization of fuels, and chiral separation. The contributors are internationally renowned scholars in the field of adsorption.


Adsorption by Powders and Porous Solids

Adsorption by Powders and Porous Solids

Author: Jean Rouquerol

Publisher: Academic Press

Published: 2013-09-06

Total Pages: 647

ISBN-13: 0080970362

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The declared objective of this book is to provide an introductory review of the various theoretical and practical aspects of adsorption by powders and porous solids with particular reference to materials of technological importance. The primary aim is to meet the needs of students and non-specialists who are new to surface science or who wish to use the advanced techniques now available for the determination of surface area, pore size and surface characterization. In addition, a critical account is given of recent work on the adsorptive properties of activated carbons, oxides, clays and zeolites. - Provides a comprehensive treatment of adsorption at both the gas/solid interface and the liquid/solid interface - Includes chapters dealing with experimental methodology and the interpretation of adsorption data obtained with porous oxides, carbons and zeolites - Techniques capture the importance of heterogeneous catalysis, chemical engineering and the production of pigments, cements, agrochemicals, and pharmaceuticals


The Mathematics of Diffusion

The Mathematics of Diffusion

Author: John Crank

Publisher: Oxford University Press

Published: 1979

Total Pages: 428

ISBN-13: 9780198534112

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Though it incorporates much new material, this new edition preserves the general character of the book in providing a collection of solutions of the equations of diffusion and describing how these solutions may be obtained.


Equilibria and Dynamics of Gas Adsorption on Heterogeneous Solid Surfaces

Equilibria and Dynamics of Gas Adsorption on Heterogeneous Solid Surfaces

Author: W.A. Steele

Publisher: Elsevier

Published: 1996-12-17

Total Pages: 909

ISBN-13: 0080531199

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The fact that the surfaces of real solids are geometrically distorted and chemically non-uniform has long been realized by the scientists investigating various phenomena occurring on solid surfaces. Even in the case when diffraction experiments show a well-organized bulk solid structure, the surface atoms or molecules will usually exhibit a much smaller degree of surface organization. In addition to the results obtained from electron diffraction, this can be seen in the impressive images obtained from STM and AFM microscopies. This geometric and chemical disorder is the source of the energetic heterogeneity for molecules adsorbing on real solid surfaces. Hundreds of papers have been published showing that this heterogeneity is a major factor in determining the behaviour of real adsorption systems.Studies of adsorption on energetically heterogeneous surfaces have proceeded along three somewhat separate paths, with only minor coupling of ideas. One was the study of adsorption equilibria on heterogeneous solid surfaces. The second path was the study of time evolution of adsorption processes such as surface diffusion or adsorption-desorption kinetics on heterogeneous surfaces, and the third was the study of adsorption in porous solids, or more generally, adsorption in systems with limited dimensions. The present monograph is a first attempt to provide a synthesis of the ways that surface geometric and energetic heterogeneities affect both the equilibria and the time evolution of adsorption on real solids. The book contains 17 chapters written by a team of internationally recognized specialists, some of whom have already published books on adsorption.