Chemical Thermodynamics of Uranium

Chemical Thermodynamics of Uranium

Author: Ingmar Grenthe

Publisher: Elsevier Science & Technology

Published: 1992

Total Pages: 744

ISBN-13:

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This volume provides a comprehensive overview on the chemical thermodynamics of those elements that are of particular importance in the safety assessment of radioactive waste disposal systems. This is the first volume in a series of critical reviews to be published on this subject. The book provides an extensive compilation of chemical thermodynamic data for uranium. A description of procedures for activity corrections and uncertainty estimates is given. A critical discussion of data needed for nuclear waste management assessments, including areas where significant gaps of knowledge exist is presented. A detailed inventory of chemical thermodynamic data for inorganic compounds and complexes of uranium is listed. Data and their uncertainty limits are recommended for 74 aqueous complexes and 199 solid and 31 gaseous compounds containing uranium, and on 52 aqueous and 17 solid auxiliary species containing no uranium. The data are internally consistent and compatible with the CODATA Key Values. The book contains a detailed discussion of procedures used for activity factor corrections in aqueous solution, as well as including methods for making uncertainty estimates.


Nature's Building Blocks

Nature's Building Blocks

Author: John Emsley

Publisher: Oxford University Press, USA

Published: 2003

Total Pages: 556

ISBN-13: 9780198503408

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A readable, informative, fascinating entry on each one of the 100-odd chemical elements, arranged alphabetically from actinium to zirconium. Each entry comprises an explanation of where the element's name comes from, followed by Body element (the role it plays in living things), Element ofhistory (how and when it was discovered), Economic element (what it is used for), Environmental element (where it occurs, how much), Chemical element (facts, figures and narrative), and Element of surprise (an amazing, little-known fact about it). A wonderful 'dipping into' source for the familyreference shelf and for students.


Update on the Chemical Thermodynamics of Uranium, Neptunium, Plutonium, Americium and Technetium

Update on the Chemical Thermodynamics of Uranium, Neptunium, Plutonium, Americium and Technetium

Author: R. Guillaumont

Publisher:

Published: 2003-11-04

Total Pages: 976

ISBN-13:

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This volume is part of the series on "Chemical Thermodynamics", published under the aegis of the OECD Nuclear Energy Agency, and updates and expands the thermodynamic data on inorganic compounds and complexes of uranium, neptunium, plutonium, americium and technetium contained in the previous volumes of the series. A review team, composed of seven internationally recognized experts, has critically reviewed during five years all the scientific literature containing chemical thermodynamic information for the above mentioned systems that has appeared since the publication of the earlier volumes. The results of this critical review carried out following the Guidelines of the OECD NEA Thermochemical Database Project have been documented in the present volume, which contains new tables of selected values for formation and reaction thermodynamical properties and an extensive bibliography.


The Chemistry of the Actinide and Transactinide Elements (3rd ed., Volumes 1-5)

The Chemistry of the Actinide and Transactinide Elements (3rd ed., Volumes 1-5)

Author: L.R. Morss

Publisher: Springer Science & Business Media

Published: 2007-12-31

Total Pages: 4059

ISBN-13: 1402035985

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The Chemistry of the Actinide and Transactinide Elements is a contemporary and definitive compilation of chemical properties of all of the actinide elements, especially of the technologically important elements uranium and plutonium, as well as the transactinide elements. In addition to the comprehensive treatment of the chemical properties of each element, ion, and compound from atomic number 89 (actinium) through to 109 (meitnerium), this multi-volume work has specialized and definitive chapters on electronic theory, optical and laser fluorescence spectroscopy, X-ray absorption spectroscopy, organoactinide chemistry, thermodynamics, magnetic properties, the metals, coordination chemistry, separations, and trace analysis. Several chapters deal with environmental science, safe handling, and biological interactions of the actinide elements. The Editors invited teams of authors, who are active practitioners and recognized experts in their specialty, to write each chapter and have endeavoured to provide a balanced and insightful treatment of these fascinating elements at the frontier of the periodic table. Because the field has expanded with new spectroscopic techniques and environmental focus, the work encompasses five volumes, each of which groups chapters on related topics. All chapters represent the current state of research in the chemistry of these elements and related fields.


Uranium Enrichment and Nuclear Weapon Proliferation

Uranium Enrichment and Nuclear Weapon Proliferation

Author: Allan S. Krass

Publisher: Routledge

Published: 2020-11-20

Total Pages: 325

ISBN-13: 100020054X

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Originally published in 1983, this book presents both the technical and political information necessary to evaluate the emerging threat to world security posed by recent advances in uranium enrichment technology. Uranium enrichment has played a relatively quiet but important role in the history of efforts by a number of nations to acquire nuclear weapons and by a number of others to prevent the proliferation of nuclear weapons. For many years the uranium enrichment industry was dominated by a single method, gaseous diffusion, which was technically complex, extremely capital-intensive, and highly inefficient in its use of energy. As long as this remained true, only the richest and most technically advanced nations could afford to pursue the enrichment route to weapon acquisition. But during the 1970s this situation changed dramatically. Several new and far more accessible enrichment techniques were developed, stimulated largely by the anticipation of a rapidly growing demand for enrichment services by the world-wide nuclear power industry. This proliferation of new techniques, coupled with the subsequent contraction of the commercial market for enriched uranium, has created a situation in which uranium enrichment technology might well become the most important contributor to further nuclear weapon proliferation. Some of the issues addressed in this book are: A technical analysis of the most important enrichment techniques in a form that is relevant to analysis of proliferation risks; A detailed projection of the world demand for uranium enrichment services; A summary and critique of present institutional non-proliferation arrangements in the world enrichment industry, and An identification of the states most likely to pursue the enrichment route to acquisition of nuclear weapons.


Handbook of Nuclear Chemistry

Handbook of Nuclear Chemistry

Author: Attila Vértes

Publisher: Springer Science & Business Media

Published: 2010-12-10

Total Pages: 3762

ISBN-13: 144190719X

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This revised and extended 6 volume handbook set is the most comprehensive and voluminous reference work of its kind in the field of nuclear chemistry. The Handbook set covers all of the chemical aspects of nuclear science starting from the physical basics and including such diverse areas as the chemistry of transactinides and exotic atoms as well as radioactive waste management and radiopharmaceutical chemistry relevant to nuclear medicine. The nuclear methods of the investigation of chemical structure also receive ample space and attention. The international team of authors consists of scores of world-renowned experts - nuclear chemists, radiopharmaceutical chemists and physicists - from Europe, USA, and Asia. The Handbook set is an invaluable reference for nuclear scientists, biologists, chemists, physicists, physicians practicing nuclear medicine, graduate students and teachers - virtually all who are involved in the chemical and radiopharmaceutical aspects of nuclear science. The Handbook set also provides further reading via the rich selection of references.