The Biogeochemistry of Iron, Zinc and Cobalt in the Atlantic Ocean
Author: Neil Wyatt
Publisher:
Published: 2014
Total Pages:
ISBN-13:
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Author: Neil Wyatt
Publisher:
Published: 2014
Total Pages:
ISBN-13:
DOWNLOAD EBOOKAuthor: Mak A. Saito
Publisher:
Published: 2001
Total Pages: 832
ISBN-13:
DOWNLOAD EBOOKProcesses that enable marine phytoplankton to acquire trace metals are fundamental to our understanding of primary productivity and global carbon cycling. This thesis explored the biogeochemistry of cobalt using analytical chemistry and physiological experiments with the dominant phytoplankton species, Prochlorococcus. A high sensitivity method for Co speciation was developed using hanging mercury drop cathodic stripping voltammetry. Dissolved Co at the Bermuda Atlantic Time Series station (BATS) in the Sargasso Sea was bound by strong organic complexes with a conditional stability constant of logK=16.3 +/- 0.9. Biweekly time series measurements of total cobalt near Bermuda from the MITESS sampler were 0-47pM throughout 1999, and averaged 20 +/- 10pM in 1999. A transect of total cobalt from BATS to American coastal waters ranged from 19-133pM and correlated negatively with salinity (r(sup 2)=0.93). Prochlorococcus strains MED4-Ax and SS120 showed an absolute requirement for Co, despite replete Zn. Co-57 uptake rates and growth rates were enhanced by additions of filtered low Co cultures, suggesting that a ligand is present that facilitates Co uptake. Co-limited Prochlorococcus cultures exhibited an increase in the fraction of cells in G2 relative to other cell cycle stages during exponential growth, and the durations of this stage increased with decreasing cobalt concentrations.
Author: David R. Turner
Publisher: John Wiley & Sons
Published: 2001-11-28
Total Pages: 426
ISBN-13:
DOWNLOAD EBOOKIntensive research carried out during the 1990's (known as the "Iron Age of Oceanography") provided a wealth of new information and this title, written by acknowledged experts and reviewed by international specialists, provides the authoritative and comprehensive review of the subject area. A joint venture between SCOR and IUPAC, it expertly addresses the current state of knowledge of the biogeochemistry of iron in seawater and covers: * Chemical speciation * Analytical techniques * Transformation of iron * It includes evidence for iron limitation of primary production of High Nutrient Low Chlorophyll (HNLC) areas in the ocean * Structured into a series of chapters it has been reviewed by international specialists- SCOR (Scientific Committee for Ocean Research) and IUPAC (International Union for Pure and Applied Chemistry) * The final chapter summarises the conclusions of the book and discusses the priorities for future research * Ideal for scientists studying the environmental impact of metals and their role in marine ecosystems; Marine Scientists and Oceanographers; Environmental Analytical Chemists
Author: Abigail Emery Noble
Publisher:
Published: 2012
Total Pages: 296
ISBN-13:
DOWNLOAD EBOOKTrace metal cycling is one of many processes that influence ocean ecosystem dynamics. Cobalt, iron, and manganese are redox active trace metal micro-nutrients with oceanic distributions that are influenced by both biological and abiotic sources and sinks. Their open ocean concentrations range from picomolar to nanomolar, and their bioavailabilities can impact primary production. Understanding the biogeochemical cycling of these hybrid-type metals with an emphasis on cobalt was the focus of this thesis. This was accomplished by determining the dissolved distributions of these metals in oceanic regions that were characterized by different dominant biogeochemistries. A large subsurface plume of dissolved cobalt, iron, and manganese was found in the Eastern South Atlantic. The cause of this plume is a combination of reductive dissolution in coastal sediments, wind-driven upwelling, advection, biological uptake, and remineralization. Additional processes that are discussed as sources of metals to the regions studied during this thesis include isopycnal uplift within cold-core eddies (Hawaii), ice melt (McMurdo Sound, Antarctica), riverine input (Arctic Ocean), and winter mixing (McMurdo Sound). The biological influence on surface ocean distributions of cobalt was apparent by the observation of linear relationships between cobalt and phosphate in mid to low latitudes. The cobalt:phosphate ratios derived from these correlations changed over orders of magnitude, revealing dynamic variability in the utilization, demand, and sources of this micronutrient. Speciation studies suggest that there may be two classes of cobalt binding ligands, and that organic complexation plays an important role in preventing scavenging of cobalt in the ocean. These datasets provided a basis for comparing the biogeochemical cycles of cobalt, iron, and manganese in three oceanic regimes (Hawaii, South Atlantic, McMurdo Sound). The relative rates of scavenging for these metals show environmental variability: in the South Atlantic, cobalt, iron, and manganese were scavenged at very different rates, but in the Ross Sea, mixing and circulation over the shallow sea was fast, scavenging played a minor role, and the cycles of all three metals were coupled. Studying the distributions of these metals in biogeochemically distinct regions is a step toward a better understanding of their oceanic cycles.
Author: Rachel Ursula Shelley
Publisher:
Published: 2011
Total Pages:
ISBN-13:
DOWNLOAD EBOOKAuthor: Christel Hassler
Publisher: Frontiers E-books
Published: 2013-07-05
Total Pages: 207
ISBN-13: 2889191303
DOWNLOAD EBOOKThe Environmental Bioinorganic Chemistry of Aquatic Microbial Organisms describes the interactions between metals and aquatic prokaryotic and eukaryotic microorganisms in their environment. Metals influence microbial growth in the aquatic environment as they can be either toxic to aquatic microbes, if present at too high concentrations in the environment, or limiting, if bio-essential and present at very low concentrations. In turn, microorganisms influence the biogeochemical cycling of metals as they affect trace metal concentrations, distributions between particulate and dissolved phase, and chemical speciation. At the sub cellular level, metalloproteins are the catalysts driving many steps in the biogeochemical cycles of major elements such as carbon, nitrogen and sulfur. Metals thus provide a link between the abundance and activity of enzymes, the growth of microorganisms, and the biogeochemical cycles of major climate influencing elements. Furthermore, the evolution of the chemistry of aquatic environments and atmosphere has left its mark on the microbial proteome as a direct result of changes in the solubility of metals. The aquatic microbial metallome thus has the potential to reveal information about key biogeochemical processes, their spatial and seasonal occurrence, and also to reveal how the geochemical environment is shaping the microbial population itself. The aim of this Research Topic is to highlight recent advances in our understanding of how metals influence the activity of aquatic microbes, and how microbes influence the biogeochemical cycling of metals. Applications of techniques in proteomics, spectroscopy, mass spectrometry and genomics are all leading to a greater understanding of the interactions between the microbial metallome and the “aquatic metallome” and thus the influence of metals on the biogeochemical cycles of climatically important elements such as carbon, nitrogen and sulfur. Both reviews and original research on the occurrence and abundance of microbial metal proteins and peptides, the utilisation of metals by aquatic microbes, the influence of microbially produced exudates on metal speciation and the biogeochemical cycling, and the toxicity of metals to microbial organisms are welcome.
Author: Lars-Göran Danielsson
Publisher:
Published: 1979
Total Pages: 194
ISBN-13:
DOWNLOAD EBOOKAuthor: Liudmila L. Demina
Publisher: Springer
Published: 2016-07-26
Total Pages: 219
ISBN-13: 3319413406
DOWNLOAD EBOOKThis volume synthesizes the relevant data that is fundamental to our understanding of trace metal biogeochemistry and the ecology of biological communities of deep-sea vent systems. It presents the combined results of biological and geochemical research and analyzes the microdistribution of animals and the spatial structure of vent communities. Careful consideration is given to the export of iron and other trace metals from hydrothermal vents. The environmental conditions to be found in deep-sea hydrothermal community habitats, along with the trace metal behavior in biotope water are characterized and the sources and forms of trace metals taken up by dominant hydrothermal vent animals are discussed. Special attention is paid to the poorly investigated deep biosphere of the sub-seafloor igneous crust. The book is illustrated with a wealth of exceptional deep-sea photos taken by the manned submersible “Mir”, and a dedicated chapter focuses on the role of deep manned submersibles in ocean research. The book will be of interest to researchers and students in the fields of oceanography, geochemistry, biology, the environmental sciences and marine ecology.
Author: H. Elderfield
Publisher: Elsevier
Published: 2006-06-20
Total Pages: 668
ISBN-13: 9780080451015
DOWNLOAD EBOOKThe Treatise on Geochemistry is the first work providing a comprehensive, integrated summary of the present state of geochemistry. It deals with all the major subjects in the field, ranging from the chemistry of the solar system to environmental geochemistry. The Treatise on Geochemistry has drawn on the expertise of outstanding scientists throughout the world, creating the reference work in geochemistry for the next decade. Each volume consists of fifteen to twenty-five chapters written by recognized authorities in their fields, and chosen by the Volume Editors in consultation with the Executive Editors. Particular emphasis has been placed on integrating the subject matter of the individual chapters and volumes. Elsevier also offers the Treatise on Geochemistry in electronic format via the online platform ScienceDirect, the most comprehensive database of academic research on the Internet today, enhanced by a suite of sophisticated linking, searching and retrieval tools.
Author: Maria Josefina Olascoaga
Publisher: Frontiers Media SA
Published: 2023-12-11
Total Pages: 259
ISBN-13: 2832540287
DOWNLOAD EBOOKIn response to the Deepwater Horizon oil spill in the Gulf of Mexico (GoM), and given the increased activities of the offshore oil industry, an international multidisciplinary consortium - the CIGOM Consortium - was funded by Mexico's Energy Secretariat (SENER) and its National Council for Science and Technology (CONACyT). Spanning 2015-2022, CIGOM's goals were to establish an environmental baseline to characterize the southern GOM’s natural variability and contribute to the understanding of ecosystem function, use cutting-edge technologies to observe the ocean, couple physical circulation and biogeochemical models to gain understating of oceanographic processes, generate oil spill scenarios using model ensembles and statistical techniques and conducting vulnerability assessments. Over 300 researchers participated in the CIGOM consortium's efforts.