Polyoxometalate-Based Hybrids and their Applications
Polyoxometalate-Based Hybrids and their Applications

Author: Majid M. Heravi

Publisher: Elsevier

Published: 2023-03-14

Total Pages: 462

ISBN-13: 0323983464

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Polyoxometalate-Based Hybrids and their Applications focuses on recent progress in polyoxometalate-based hybrids materials. Chapters present the structure, composition, classification and properties of POMs such as isopolyaions, heteropolyanions, giant and lacunary polyoxometalates and then cover polyoxometalate-based open-frameworks (POM-OFs), include a historical introduction to these compounds, and present their synthetic strategies. The structural diversity and relative applications of POM-OFs is also covered. Other sections delve into synthetic strategies, structural diversity and relative applications of porous polyoxometalate-based metal-organic frameworks. Polyoxometalate-based coordination polymers (POMCPs) and polyoxometalate-based host-guest framework materials are highlighted in final sections. This book is an essential reference for inorganic chemists, biochemists, and material scientists working in academia and industry. - Discusses polyoxometalate-based host-guest framework materials - Includes coverage of polyoxometalates and their environmental applications - Reviews transition metal substituted lacunary polyoxometalates

Polyoxometalate Molecular Science
Polyoxometalate Molecular Science

Author: Juan J. Borrás-Almenar

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 473

ISBN-13: 9401000913

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Polyoxometalates (POMs) form a large, distinctive class of molecular inorganic compounds of unrivaled electronic versatility and structural variation, with impacts ranging from chemistry, catalysis, and materials science to biology, and medicine. This book covers the basic principles governing the structure, bonding and reactivity of these metal-oxygen cluster anions and the major developments in their molecular science. The book comprises three sections. The first covers areas ranging from topological principles via synthesis and stability to reactivity in solution. It also focuses on the physical methods currently used to extract information on the molecular and electronic structures as well as the physical properties of these clusters. The second part reviews different types of POMs, focusing on those systems that currently impact other areas of interest, such as supramolecular chemistry, nanochemistry and molecular magnetism. The third section is devoted to POM-based materials and their applications and prospects in catalysis and materials science.

Trends in Polyoxometalates Research
Trends in Polyoxometalates Research

Author: Laurent Ruhlmann

Publisher: Nova Science Publishers

Published: 2015

Total Pages: 0

ISBN-13: 9781634826563

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The book attempts to make available the recent developments in polyoxometalate (POM) synthesis. The focus centralises on the functionalisation of POMs with covalently organic moiety (for instance, the use of exogenous ligands such as carboxylate or bisphosphonate). It also delves into the development of lanthanide POMs, or the formation of blackberry-like assemblies. Likewise, the properties (redox properties, magnetism, etc...), and its applications (homogeneous and heterogeneous catalysis, photocatalysis, photoelectrocatalysis and photovoltaic cell development, etc.) are also analysed. This application concerns also the catalysis of H2O oxidation, photodegradation of pollutants, and reduction of cationic metal to form original nanoparticles. The use of polyoxometalates as catalysts for biologically relevant reactions is also considered. One of the other aims of the book is to highlight some recent developments and perspectives in the domain of materials and their applications. For instance, the use of POM-organic photosensitiser hybrids can also be achieved for application in the generation of photocurrent and the development of new types of solar cells. By combining POMs with electrically active materials, a variety of applications have been explored and several examples of POM-based electronic materials are presented in this book.

Polyoxometalate-Based Assemblies and Functional Materials
Polyoxometalate-Based Assemblies and Functional Materials

Author: Yu-Fei Song

Publisher: Springer

Published: 2018-03-24

Total Pages: 168

ISBN-13: 3319759043

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The authors of this volume concentrate on the recent progress of novel polyoxometalate (POM) syntheses, as well as advances made in catalytic, electrochemical, and sensing systems. The state-of-the-art techniques such as flow system and gel-electrophoresis for the discovery of POMs are covered with a detailed discussion. Of particular importance, the application of POM-based materials in photo-sensing, heterogeneous catalysis, energy conservation and storage, and gas separation is reviewed. Over the past few years, POM chemistry has witnessed a remarkable progress with more than 1500 papers published each year. Due to their intrinsic structural features, POMs are considered as versatile building blocks for the construction of sophisticated complex assemblies and advanced multi-functional materials. Various strategies, methods, and techniques have been adopted to develop POM-based materials with intriguing properties and excellent performance. All the contributors to this volume are young, vibrant chemists in this research field and all the works are carefully collected from the authors’ years of experience. This volume serves as an essential reference for every POM chemist and is of great interest to new researchers who wish to learn more about this area.

Metal Oxides in Supercapacitors
Metal Oxides in Supercapacitors

Author: Deepak P. Dubal

Publisher: Elsevier

Published: 2017-07-10

Total Pages: 294

ISBN-13: 0128104651

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Metal Oxides in Supercapacitors addresses the fundamentals of metal oxide-based supercapacitors and provides an overview of recent advancements in this area. Metal oxides attract most of the materials scientists use due to their excellent physico-chemical properties and stability in electrochemical systems. This justification for the usage of metal oxides as electrode materials in supercapacitors is their potential to attain high capacitance at low cost. After providing the principles, the heart of the book discusses recent advances, including: binary metal oxides-based supercapacitors, nanotechnology, ternary metal oxides, polyoxometalates and hybrids. Moreover, the factors affecting the charge storage mechanism of metal oxides are explored in detail. The electrolytes, which are the soul of supercapacitors and a mostly ignored character of investigations, are also exposed in depth, as is the fabrication and design of supercapacitors and their merits and demerits. Lastly, the market status of supercapacitors and a discussion pointing out the future scope and directions of next generation metal oxides based supercapacitors is explored, making this a comprehensive book on the latest, cutting-edge research in the field. - Explores the most recent advances made in metal oxides in supercapacitors - Discusses cutting-edge nanotechnology for supercapacitors - Includes fundamental properties of metal oxides in supercapacitors that can be used to guide and promote technology development - Contains contributions from leading international scientists active in supercapacitor research and manufacturing

Materials-Chirality
Materials-Chirality

Author: Mark M. Green

Publisher: John Wiley & Sons

Published: 2004-05-07

Total Pages: 625

ISBN-13: 0471471909

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Dieser Sonderband der Reihe "Topics in Stereochemistry" beschäftigt sich mit der Chiralität von Werkstoffen und der Bedeutung der Stereochemie für bestimmte Polymere, Flüssigkristalle und andere spezielle Materialien. Die Grundlage dafür bilden die ausführlich dargestellten Prinzipien der organischen Stereochemie. Das aktuellste derzeit erhältliche Buch zur Chiralität!

Homogeneous Photocatalysis
Homogeneous Photocatalysis

Author: M. Chanon

Publisher: John Wiley & Sons

Published: 1997-03-06

Total Pages: 440

ISBN-13:

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Photocatalysis and related processes occupy a strategic position for the future of photochemistry. This volume provides an introduction to basic concepts and explains how applications work at the molecular level.

Heterogeneous Catalytic Materials
Heterogeneous Catalytic Materials

Author: Guido Busca

Publisher: Newnes

Published: 2014-05-23

Total Pages: 479

ISBN-13: 044459521X

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Heterogeneous Catalytic Materials discusses experimental methods and the latest developments in three areas of research: heterogeneous catalysis; surface chemistry; and the chemistry of catalysts. Catalytic materials are those solids that allow the chemical reaction to occur efficiently and cost-effectively. This book provides you with all necessary information to synthesize, characterize, and relate the properties of a catalyst to its behavior, enabling you to select the appropriate catalyst for the process and reactor system. Oxides (used both as catalysts and as supports for catalysts), mixed and complex oxides and salts, halides, sulfides, carbides, and unsupported and supported metals are all considered. The book encompasses applications in industrial chemistry, refinery, petrochemistry, biomass conversion, energy production, and environmental protection technologies. - Provides a systematic and clear approach of the synthesis, solid state chemistry and surface chemistry of all solid state catalysts - Covers widely used instrumental techniques for catalyst characterization, such as x-ray photoelectron spectroscopy, scanning electron microscopy, and more - Includes characterization methods and lists all catalytic behavior of the solid state catalysts - Discusses new developments in nanocatalysts and their advantages over conventional catalysts

Cluster Assembled Materials
Cluster Assembled Materials

Author: Klaus Sattler

Publisher: CRC Press

Published: 1996

Total Pages: 318

ISBN-13: 9780878497478

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It is now some 15 years since atomic clusters were first produced and investigated in laboratories. Since then, knowledge concerning clusters has enjoyed rapid and sustained growth, and cluster research has become a new branch of science.

Applied Polyoxometalate-Based Electrocatalysis
Applied Polyoxometalate-Based Electrocatalysis

Author: Diana M. Fernandes

Publisher: John Wiley & Sons

Published: 2024-10-11

Total Pages: 386

ISBN-13: 3527842705

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Well-researched reference on stable alternative electrocatalysts and electrode materials with the potential to transform chemistry and processes in sensor- and energy-related technologies Applied Polyoxometalate-based Electrocatalysis delivers an overview of the variety of efficient applications of free POM and POM-based (nano)composites as exciting materials in the field of electrocatalysis. With a variety of sizes, shapes, composition, and physical and chemical properties, these composites have important properties, such as the ability to undergo reversible multivalence reductions/oxidations, leading to the formation of mixed-valence species, which brings about favorable electrocatalytic properties with regard to several electrochemical processes. Edited by a highly qualified independent researcher internationally recognized for her contributions to materials for electrochemical energy-related reactions, Applied Polyoxometalate-based Electrocatalysis includes information on: General methodologies used in the preparation of free POMs and POM-based nanocomposites and different strategies employed in electrode modification Role of POM-modified electrodes in oxidative and reductive electrocatalysis, including the detection/sensing of several (bio)molecules of interest and carbon dioxide electroreduction Application of POM-based (nano)composites, including the oxygen reduction reaction relevant to fuel cells, the oxygen and hydrogen evolution reactions, and batteries and supercapacitors Applied Polyoxometalate-based Electrocatalysis is an essential reference on the subject for chemists, material scientists, chemical engineers, and institutions involved in work related to free POM and POM-based (nano)composites.