Analytical methods used in the Geologic Division laboratories of the U.S. Geological Survey for the inorganic chemical analysis of rock and mineral samples.
The founders of geology at the beginning of the last century were suspicious oflaboratories. Hutton's well-known dictum illustrates the point: "There are also superficial reasoning men . . . they judge of the great oper ations of the mineral kingdom from having kindled a fire, and looked into the bottom of a little crucible. " The idea was not unreasonable; the earth is so large and its changes are so slow and so complicated that labo ratory tests and experiments were of little help. The earth had to be studied in its own terms and geology grew up as a separate science and not as a branch of physics or chemistry. Its practitioners were, for the most part, experts in structure, stratigraphy, or paleontology, not in silicate chemistry or mechanics. The chemists broke into this closed circle before the physicists did. The problems of the classification of rocks, particularly igneous rocks, and of the nature and genesis of ores are obviously chemical and, by the mid- 19th century, chemistry was in a state where rocks could be effectively analyzed, and a classification built up depending partly on chemistry and partly on the optical study of thin specimens. Gradually the chemical study of rocks became one of the central themes of earth science.
Written for the practicing analyst, Analytical Methods for Geochemical Exploration offers thoroughly tested chemical analysis methods for determining what base or precious metals are in geochemical exploration samples, such as rocks, soil, or sediment. Theory is kept to a minimum and complete procedures are provided so that no additional sources are needed to conduct analyses.
All sub disciplines in Organic Geochemistry (Petroleum Geochemistry, Environmental Geochemistry etc.) are linked by the basic analytical approaches used for identification and quantitation of individual organic substances. Hence, a fundamental prerequisite for organic geochemists is the knowledge not only about the individual analytical techniques but more about their potential as well as their limitations. In this issues basic analytical procedures and techniques are introduced comprising fundamental steps like sampling and sample storage, aspects of sample treatment like extraction and fractionation procedures and finally the specific techniques used for organic analyses on partially very low concentration levels such as mass spectrometry or infrared spectroscopy. Beside the technical aspects also application on organic-geochemical problems and the standard data evaluation practice is introduced. Finally, special chapters point to analytical pitfalls and to principal standard operation procedures. The intention of this issue is to get the readers familiar with analytical Organic Geochemistry and to enable them to assess the quality and suitability of specific analytical approaches, in particular with respect to the organic-geochemical problems.
Handbook of Exploration Geochemistry, Volume I: Analytical Methods in Geochemical Prospecting focuses on the principles, methodologies, approaches, and techniques employed in geochemical prospecting. The book first underscores quality control in the laboratory, sample preparation, sample decomposition-solution techniques, and colorimetry and related techniques. Discussions focus on colorimetry, turbidimetric methods, strong decompositions, partial extractions, preparation of rock samples, random and systematic errors, and quality control program. The publication then takes a look at atomic absorption spectrophotometry, emission spectroscopy, and X-ray fluorescence. Concerns cover instrumentation, operation of the X-ray fluorescence spectrometer, flame emission spectroscopy, semi-quantitative DC-arc spectroscopy, and plasma sources. The text examines electrochemical methods, including determination of pH and specific ion electrodes. The publication is a dependable reference for researchers interested in the analytical methods in geochemical prospecting.
Environmental Geochemistry: Site Characterization, Data Analysis and Case Histories, Second Edition, reviews the role of geochemistry in the environment and details state-of-the-art applications of these principles in the field, specifically in pollution and remediation situations. Chapters cover both philosophy and procedures, as well as applications, in an array of issues in environmental geochemistry including health problems related to environment pollution, waste disposal and data base management. This updated edition also includes illustrations of specific case histories of site characterization and remediation of brownfield sites. - Covers numerous global case studies allowing readers to see principles in action - Explores the environmental impacts on soils, water and air in terms of both inorganic and organic geochemistry - Written by a well-respected author team, with over 100 years of experience combined - Includes updated content on: urban geochemical mapping, chemical speciation, characterizing a brownsfield site and the relationship between heavy metal distributions and cancer mortality
Following the collection of a sample, every analytical chemist will agree that its subsequent preservation and processing are of paramount importance. The availability of high performance analytical instrumentation has not diminished this need for careful selection of appropriate pretreatment methodologies, intelligently designed to synergistically elicit optimum function from these powerful measurement tools. Sample Preparation for Trace Element Analysis is a modern, comprehensive treatise, providing an account of the state-of-the art on the subject matter. The book has been conceived and designed to satisfy the varied needs of the practicing analytical chemist. It is a multi-author work, reflecting the diverse expertise arising from its highly qualified contributors. The first five chapters deal with general issues related to the determination of trace metals in varied matrices, such as sampling, contamination control, reference materials, calibration and detection techniques. The second part of the book deals with extraction and sampling technologies (totaling 15 chapters), providing theoretical and practical hints for the users on how to perform specific extractions. Subsequent chapters overview seven major representative matrices and the sample preparation involved in their characterization. This portion of the book is heavily based on the preceding chapters dealing with extraction technologies. The last ten chapters are dedicated to sample preparation for trace element speciation.- First title to provide comprehensive sample preparation information, dealing specifically with the analysis of samples for trace elements. - The 39 chapters are authored by international leaders of their fields.
This textbook is a complete rewrite, and expansion of Hugh Rollinson's highly successful 1993 book Using Geochemical Data: Evaluation, Presentation, Interpretation. Rollinson and Pease's new book covers the explosion in geochemical thinking over the past three decades, as new instruments and techniques have come online. It provides a comprehensive overview of how modern geochemical data are used in the understanding of geological and petrological processes. It covers major element, trace element, and radiogenic and stable isotope geochemistry. It explains the potential of many geochemical techniques, provides examples of their application, and emphasizes how to interpret the resulting data. Additional topics covered include the critical statistical analysis of geochemical data, current geochemical techniques, effective display of geochemical data, and the application of data in problem solving and identifying petrogenetic processes within a geological context. It will be invaluable for all graduate students, researchers, and professionals using geochemical techniques.
Geochemical Anomaly and Mineral Prospectivity Mapping in GIS documents and explains, in three parts, geochemical anomaly and mineral prospectivity mapping by using a geographic information system (GIS). Part I reviews and couples the concepts of (a) mapping geochemical anomalies and mineral prospectivity and (b) spatial data models, management and operations in a GIS. Part II demonstrates GIS-aided and GIS-based techniques for analysis of robust thresholds in mapping of geochemical anomalies. Part III explains GIS-aided and GIS-based techniques for spatial data analysis and geo-information sybthesis for conceptual and predictive modeling of mineral prospectivity. Because methods of geochemical anomaly mapping and mineral potential mapping are highly specialized yet diverse, the book explains only methods in which GIS plays an important role. The book avoids using language and functional organization of particular commercial GIS software, but explains, where necessary, GIS functionality and spatial data structures appropriate to problems in geochemical anomaly mapping and mineral potential mapping. Because GIS-based methods of spatial data analysis and spatial data integration are quantitative, which can be complicated to non-numerate readers, the book simplifies explanations of mathematical concepts and their applications so that the methods demonstrated would be useful to professional geoscientists, to mineral explorationists and to research students in fields that involve analysis and integration of maps or spatial datasets. The book provides adequate illustrations for more thorough explanation of the various concepts. - Explains GIS functionality and spatial data structures appropriate regardless of the particular GIS software in use - Simplifies explanation of mathematical concepts and application - Illustrated for more thorough explanation of concepts
Handbook of Exploration Geochemistry, Volume 2: Statistics and Data Analysis in Geochemical Prospecting aims to survey the techniques available for the quality control of laboratory data, storage and retrieval of field and laboratory information, statistical analysis of single- and multi-element data, and presentation of geochemical data as maps. The selection first elaborates on data storage and retrieval, control procedures in geochemical analysis, and univariate analysis. Discussions focus on analysis of variance, density distribution, probability graphs, statistical basis of analytical quality control, laboratory control procedures, data storage media, data organization, programming considerations, and generalized data systems. The book then takes a look at sampling methodology, mapping, and multivariate analysis. Concerns cover correlation, cluster analysis, regression, partial correlation, class selection techniques, map filtering techniques, cross-correlation maps, strategies for optimum sampling design, and search techniques. The manuscript elaborates on examples of geochemical data processing in Africa, mathematical and statistical activity in North America, statistical models for geochemical anomalies, geochemical characterization of tin granites in northern Thailand, and use of pattern classification methods in till geochemistry. The selection is highly recommended for researchers interested in statistics and data analysis in geochemical prospecting.