Insights into the electrochemical performance of metal fluoride cathodes for lithium batteries
Insights into the electrochemical performance of metal fluoride cathodes for lithium batteries

Author: Delong Ma

Publisher: OAE Publishing Inc.

Published: 2022-07-28

Total Pages: 31

ISBN-13:

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In recent years, energy storage and conversion have become key areas of research to address social and environmental issues, as well as practical applications, such as increasing the storage capacity of portable electronic storage devices. However, current commercial lithium-ion batteries suffer from low specific energy and high cost and toxicity. Conversion-type cathode materials are promising candidates for next-generation Li metal and Li-ion batteries (LIBs). Metal fluoride materials have shown tremendous chemical tailorability and exhibit excellent energy density in LIBs. Batteries based on such electrodes can compete with other envisaged alternatives, such as Li-air and Li-S systems. However, conversion reactions are typically multiphase redox reactions with mass transport phenomena and nucleation and growth processes of new phases along with interfacial reactions. Therefore, these reactions involve nonequilibrium reaction pathways and significant overpotentials during the charge-discharge process. In this review, we summarize the key challenges facing metal fluoride cathode materials and general strategies to overcome them in cells. Different synthesis methods of metal fluorides are also presented and discussed in the context of their application as cathode materials in Li and LIBs. Finally, the current challenges and future opportunities of metal fluorides as electrode materials are emphasized. With continuous rapid improvements in the electrochemical performance of metal fluorides, it is believed that these materials will be used extensively for energy storage in Li batteries in the future.

High Energy Density Lithium Batteries
High Energy Density Lithium Batteries

Author: Katerina E. Aifantis

Publisher: John Wiley & Sons

Published: 2010-03-30

Total Pages: 296

ISBN-13: 9783527630028

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Materials Engineering for High Density Energy Storage provides first-hand knowledge about the design of safe and powerful batteries and the methods and approaches for enhancing the performance of next-generation batteries. The book explores how the innovative approaches currently employed, including thin films, nanoparticles and nanocomposites, are paving new ways to performance improvement. The topic's tremendous application potential will appeal to a broad audience, including materials scientists, physicists, electrochemists, libraries, and graduate students.

Annual Review of Nano Research
Annual Review of Nano Research

Author: Guozhong Cao

Publisher: World Scientific

Published: 2006

Total Pages: 650

ISBN-13: 9812705643

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The first volume in an exciting new series, Annual Review of Nano Research, this formidable collection of review articles sees renowned contributors from eight different countries tackle the most recent advances in nanofabrication, nanomaterials and nanostructures.The broad coverage of topics in nanotechnology and nanoscience also includes a special focus on the hot topic of biomedical applications of nanomaterials. The important names contributing to the volume include: M R Bockstaller (USA), L Duclaux (France), S Forster (Germany), W Fritzsche (Germany), L Jiang (China), C Lopez (Spain), W J Parak (Germany), B Samori (Italy), U S Schubert (The Netherlands), S Shinkai (Japan), A Stein (USA), S M Hou (China), and Y N Xia (USA).The volume serves both as a handy reference for experts active in the field and as an excellent introduction to scientists whose expertise lies elsewhere but who are interested in learning about this cutting-edge research area.

Encyclopedia of Electrochemical Power Sources
Encyclopedia of Electrochemical Power Sources

Author:

Publisher: Elsevier

Published: 2024-09-16

Total Pages: 5674

ISBN-13: 0323958222

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The Encyclopedia of Electrochemical Power Sources, Second Edition, is a comprehensive seven-volume set that serves as a vital interdisciplinary reference for those working with batteries, fuel cells, electrolyzers, supercapacitors, and photo-electrochemical cells. With an increased focus on the environmental and economic impacts of electrochemical power sources, this work not only consolidates extensive coverage of the field but also serves as a gateway to the latest literature for professionals and students alike. The field of electrochemical power sources has experienced significant growth and development since the first edition was published in 2009. This is reflected in the exponential growth of the battery market, the improvement of many conventional systems, and the introduction of new systems and technologies. This completely revised second edition captures these advancements, providing updates on all scientific, technical, and economic developments over the past decade. Thematically arranged, this edition delves into crucial areas such as batteries, fuel cells, electrolyzers, supercapacitors, and photo-electrochemical cells. It explores challenges and advancements in electrode and electrolyte materials, structural design, optimization, application of novel materials, and performance analysis. This comprehensive resource, with its focus on the future of electrochemical power sources, is an essential tool for navigating this rapidly evolving field. - Covers the main types of power sources, including their operating principles, systems, materials, and applications - Serves as a primary source of information for electrochemists, materials scientists, energy technologists, and engineers - Incorporates 365 articles, with timely coverage of environmental and sustainability aspects - Arranged thematically to facilitate easy navigation of topics and easy exploration of the field across its key branches - Follows a consistent structure and features elements such as key objective boxes, summaries, figures, references, and cross-references etc., to help students, faculty, and professionals alike

Electrodes for Li-ion Batteries
Electrodes for Li-ion Batteries

Author: Laure Monconduit

Publisher: John Wiley & Sons

Published: 2015-06-29

Total Pages: 100

ISBN-13: 1848217218

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The electrochemical energy storage is a means to conserve electrical energy in chemical form. This form of storage benefits from the fact that these two energies share the same vector, the electron. This advantage allows us to limit the losses related to the conversion of energy from one form to another. The RS2E focuses its research on rechargeable electrochemical devices (or electrochemical storage) batteries and supercapacitors. The materials used in the electrodes are key components of lithium-ion batteries. Their nature depend battery performance in terms of mass and volume capacity, energy density, power, durability, safety, etc. This book deals with current and future positive and negative electrode materials covering aspects related to research new and better materials for future applications (related to renewable energy storage and transportation in particular), bringing light on the mechanisms of operation, aging and failure.

Materials for Lithium-Ion Batteries
Materials for Lithium-Ion Batteries

Author: Christian Julien

Publisher: Springer Science & Business Media

Published: 2000-10-31

Total Pages: 658

ISBN-13: 9780792366508

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A lithium-ion battery comprises essentially three components: two intercalation compounds as positive and negative electrodes, separated by an ionic-electronic electrolyte. Each component is discussed in sufficient detail to give the practising engineer an understanding of the subject, providing guidance on the selection of suitable materials in actual applications. Each topic covered is written by an expert, reflecting many years of experience in research and applications. Each topic is provided with an extensive list of references, allowing easy access to further information. Readership: Research students and engineers seeking an expert review. Graduate courses in electrical drives can also be designed around the book by selecting sections for discussion. The coverage and treatment make the book indispensable for the lithium battery community.

Printed Batteries
Printed Batteries

Author: Senentxu Lanceros-Méndez

Publisher: John Wiley & Sons

Published: 2018-04-23

Total Pages: 270

ISBN-13: 1119287421

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Offers the first comprehensive account of this interesting and growing research field Printed Batteries: Materials, Technologies and Applications reviews the current state of the art for printed batteries, discussing the different types and materials, and describing the printing techniques. It addresses the main applications that are being developed for printed batteries as well as the major advantages and remaining challenges that exist in this rapidly evolving area of research. It is the first book on printed batteries that seeks to promote a deeper understanding of this increasingly relevant research and application area. It is written in a way so as to interest and motivate readers to tackle the many challenges that lie ahead so that the entire research community can provide the world with a bright, innovative future in the area of printed batteries. Topics covered in Printed Batteries include, Printed Batteries: Definition, Types and Advantages; Printing Techniques for Batteries, Including 3D Printing; Inks Formulation and Properties for Printing Techniques; Rheological Properties for Electrode Slurry; Solid Polymer Electrolytes for Printed Batteries; Printed Battery Design; and Printed Battery Applications. Covers everything readers need to know about the materials and techniques required for printed batteries Informs on the applications for printed batteries and what the benefits are Discusses the challenges that lie ahead as innovators continue with their research Printed Batteries: Materials, Technologies and Applications is a unique and informative book that will appeal to academic researchers, industrial scientists, and engineers working in the areas of sensors, actuators, energy storage, and printed electronics.

Lithium-ion Batteries
Lithium-ion Batteries

Author: Perla B. Balbuena

Publisher: World Scientific

Published: 2004

Total Pages: 424

ISBN-13: 1860943624

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This invaluable book focuses on the mechanisms of formation of a solid-electrolyte interphase (SEI) on the electrode surfaces of lithium-ion batteries. The SEI film is due to electromechanical reduction of species present in the electrolyte. It is widely recognized that the presence of the film plays an essential role in the battery performance, and its very nature can determine an extended (or shorter) life for the battery. In spite of the numerous related research efforts, details on the stability of the SEI composition and its influence on the battery capacity are still controversial. This book carefully analyzes and discusses the most recent findings and advances on this topic.

Na-ion Batteries
Na-ion Batteries

Author:

Publisher: John Wiley & Sons

Published: 2021-05-11

Total Pages: 386

ISBN-13: 1789450136

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This book covers both the fundamental and applied aspects of advanced Na-ion batteries (NIB) which have proven to be a potential challenger to Li-ion batteries. Both the chemistry and design of positive and negative electrode materials are examined. In NIB, the electrolyte is also a crucial part of the batteries and the recent research, showing a possible alternative to classical electrolytes – with the development of ionic liquid-based electrolytes – is also explored. Cycling performance in NIB is also strongly associated with the quality of the electrode-electrolyte interface, where electrolyte degradation takes place; thus, Na-ion Batteries details the recent achievements in furthering knowledge of this interface. Finally, as the ultimate goal is commercialization of this new electrical storage technology, the last chapters are dedicated to the industrial point of view, given by two startup companies, who developed two different NIB chemistries for complementary applications and markets.

Sodium-Ion Capacitors
Sodium-Ion Capacitors

Author: Guoqiang Zou

Publisher: John Wiley & Sons

Published: 2024-01-03

Total Pages: 277

ISBN-13: 3527350373

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Sodium-Ion Capacitors Enables readers to quickly understand core issues and field development of sodium-ion capacitors Sodium-Ion Capacitors summarizes and outlines the dynamics and development of sodium-ion capacitors, covering key aspects of the technology including background, classification and configuration, key technologies, and more, allowing readers to gain an understanding of sodium-ion capacitors from the perspective of both industrial technology and electrochemistry. Sodium-Ion Capacitors includes information on: EDLC-type mechanism of SCs and battery-type mechanism of SIBs, definition and types of pseudocapacitance, and energy storage mechanism of pseudocapacitors Cathode materials for sodium-ion capacitors, covering EDLC cathode materials, carbon nanotubes, reduced graphene oxide, and hollow carbon microspheres Flexible battery-type anode and capacitive cathode SICs cell configurations, including flexible electrodes based on carbon nanofiber, graphene substrates, carbon cloth, MXenes, and metal foil Pre-sodiation technologies, covering operation with Li metal, usage of Li-based alternatives, and the sacrificial additives method Summarizing the development, directions, potential, and core issues of sodium-ion capacitors, Sodium-Ion Capacitors is an essential resource on the subject for materials scientists, solid-state chemists and electrochemists, and semiconductor physicists in both industry and academia.