Inorganic Stereochemistry

Inorganic Stereochemistry

Author: D. L. Kepert

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 239

ISBN-13: 3642680461

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Molecular stereochemistry is a fundamental aspect of all areas of chemistry. It is especially important in inorganic chemistry where the coordination numbers are variable and occasionally quite high. The present book evolved naturally from a series of articles written by Professor Kepert for Progre88 in Inorganic Ohemi8try, elucida ting aspects of the stereochemistry of inorganic compounds of co ordination numbers 4-12. In the present volume, Professor Kepert has added new sections and synthesized these individual chapters into a unified treatment, updating his references when necessary to the most recent contributions in the literature, and inter weaving the various themes as deemed appropriate. The result is a major contribution, describing the stereochemistry of coordi nation compounds having both unidentate and multidentate ligands. The viability of the repulsion approach to stereochemistry is tested to the limit in this treatise and shown to be an extremely good way of rationalizing a diverse body of data.


Topics in Inorganic and Organometallic Stereochemistry

Topics in Inorganic and Organometallic Stereochemistry

Author: Gregory L. Geoffroy

Publisher: John Wiley & Sons

Published: 2009-09-17

Total Pages: 366

ISBN-13: 0470147431

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This volume is devoted entirely to inorganic and organometallic stereochemical subjects. Discusses the systematic notations that have been developed to satisfy the needs for a rational and systematic stereochemical nomenclature. Reviews the stereochemical aspects of the changes of bonding at carbon centers induced by metals, either catalytically or stoiciometrically. Also reviews the major achievements in current stereochemical research—the synthesis of asymmetric compounds mediated by transition metals. Discusses the structures of transition metal carbonyl clusters, summarizing recent progress in this expanding area and providing a semiquantitative rationalization of the structures for these clusters.


Introduction to Stereochemistry

Introduction to Stereochemistry

Author: Andrew Clark

Publisher: Royal Society of Chemistry

Published: 2023-01-17

Total Pages: 201

ISBN-13: 1839164131

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CHEMISTRY STUDENT GUIDES. GUIDED BY STUDENTS Why did the drug thalidomide cause birth defects? What is the chemical difference between sucrose and lactose in your food? Stereochemistry holds the answer and is essential to the understanding of the chemistry of life. Stereochemistry is an important concept that often causes confusion amongst students when they learn it for the first time. Unlike most other areas of chemistry, it requires the chemist to visualise molecules in 3D, which can be difficult. In this book we deal with tricky concepts like conformation and configuration, how to represent them accurately and how to use the correct terms to describe them in both organic and inorganic chemistry. We involved students in the writing process to ensure we deal with areas that you find difficult, in an understandable language. With problems designed to focus on common errors and misconceptions, real life examples, and practical hands-on exercises coupled with visualisation tips, our intention is to give you the tools to become confident in stererochemistry. Complementing mainstream organic textbooks, or self-study, this book is for anyone who has struggled with describing alkenes as E or Z, assigning R and S absolute configurations, drawing Newman projections or chair representations of cyclohexanes, axial chirality, understanding the stereochemistry of octahedral metal complexes and indeed explaining complexities observed in NMR spectra. Chemistry Student Guides are written with current students involved at every stage, guiding the books towards the most challenging aspects of the topic. Student co-authors for Introduction to Stereochemistry are Caroline Akamune, Michael Lloyd and Matthew Taylor.


Basic Concepts in Organic Stereochemistry

Basic Concepts in Organic Stereochemistry

Author: Sunil Kumar Talapatra

Publisher: Springer Nature

Published: 2023-01-01

Total Pages: 266

ISBN-13: 3030959902

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This book discusses essential stereochemical concepts associated with organic molecules (natural or synthetic), as reflected in the course of their many reactions, their mechanisms, their asymmetric synthesis, biosynthesis, and biological activities. This treatise provides useful insights and understanding of the chiral/achiral designations (nomenclatures), the stereochemical features, and related properties of the natural and synthetic products. Without having an adequate knowledge of stereochemical concepts, it will not be possible to understand and appreciate the stereochemistry of natural or synthetic products. Thus, essential static and dynamic aspects of stereochemistry with sufficient illustrative examples along with discussions are presented. The structure of the monograph allows for easy selection of separate topics for reading and teaching. This book will also provide an idea of basic stereochemical concepts, as applied to organic molecules in general as well as to organic ligands in coordination complexes, and will, therefore, be valuable resources to teachers and students of advanced undergraduates and post-graduates, researchers, and professionals.


Stereochemistry of Coordination Compounds

Stereochemistry of Coordination Compounds

Author: Alexander von Zelewsky

Publisher: John Wiley & Sons

Published: 1996-06-03

Total Pages: 272

ISBN-13: 9780471955993

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This well-illustrated and well-referenced book provides a systematic introduction to the modern aspects of the topographical stereochemistry of coordination compounds, which are made up of metal ions surrounded by other non-metal atoms, ions and molecules.


Principles and Applications of Stereochemistry

Principles and Applications of Stereochemistry

Author: Michael North

Publisher: Routledge

Published: 2017-10-19

Total Pages: 276

ISBN-13: 1351422057

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A thorough understanding of stereochemistry is essential for the comprehension of almost all aspects of modern organic chemistry. It is also of great significance in many biochemical and medicinal disciplines, since the stereoisomers of a compound can have dramatically different biological properties. This text explains how the different properties of stereoisomers of a compound arise, and what processes can be used to prepare and analyze stereoisomerically pure compounds. It also presents prominent coverage of the stereochemistry of inorganic and organometallic compounds, which is likely to increase in importance, as these compounds are used as symmetric catalysts in asymmetric synthesis. Modern stereochemical terminology is used throughout, although reference is also made to older terms which are still widely used. A set of problems at the end of each chapter aims to further the reader's understanding of how the content can be applied. The book is designed mainly as a textbook for undergraduate students and as a reference source for more advanced levels, but is also intended for academic and professional organic chemists.


Organic Stereochemistry

Organic Stereochemistry

Author: Michael J. T. Robinson

Publisher: Oxford University Press on Demand

Published: 2000

Total Pages: 89

ISBN-13: 9780198792758

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This book is an account for students of how the three-dimensional shapes of molecules influence their chemical and physical properties. It begins with the structures of molecules and then describes how such structures can be changed.


Stereochemistry of Organic Compounds

Stereochemistry of Organic Compounds

Author: Ernest L. Eliel

Publisher: John Wiley & Sons

Published: 1994-09-28

Total Pages: 1296

ISBN-13: 0471016705

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Stereochemistry of Organic Compounds The first fully referenced, comprehensive book on this subject in more than thirty years, Stereochemistry of Organic Compounds contains up-to-date coverage and insightful exposition of all important new concepts, developments, and tools in the rapidly advancing field of stereochemistry, including: * Asymmetric and diastereoselective synthesis * Conformational analysis * Properties of enantiomers and racemates * Separation and analysis of enantiomers and diastereoisomers * Developments in spectroscopy (including NMR), chromatography, and molecular mechanics as applied to stereochemistry * Prostereoisomerism * Conceptual foundations of stereochemistry, including terminology and symmetry concepts * Chiroptical properties Written by the leading authorities in the field, the text includes more than 4,000 references, 1,000 illustrations, and a glossary of stereochemical terms.