Inorganic Electronic Spectroscopy
Author: Alfred Beverley Philip Lever
Publisher: Elsevier Science & Technology
Published: 1984
Total Pages: 888
ISBN-13:
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Author: Alfred Beverley Philip Lever
Publisher: Elsevier Science & Technology
Published: 1984
Total Pages: 888
ISBN-13:
DOWNLOAD EBOOKAuthor: A. B. P. Lever
Publisher:
Published: 1997
Total Pages: 0
ISBN-13: 9780444416995
DOWNLOAD EBOOKAuthor: Alfred Beverly Philip Lever
Publisher:
Published: 1997
Total Pages: 863
ISBN-13: 9780444416995
DOWNLOAD EBOOKAuthor: Edward I. Solomon
Publisher: Wiley-Interscience
Published: 1999-06-23
Total Pages: 682
ISBN-13:
DOWNLOAD EBOOKSpectroscopy is an analytical method used to detect and identify samples, and analyze the electronic structure and behavior of a compound. Electronic structure is the bonding of inorganic compounds that give rise to a compounds' physical properties and reactivity. The two volume set covers current development in inorganic electronic spectroscopy. Because the field is inextricably linked to the more general area of electronic structure, the volumes will cover both inorganic spectroscopy and electronic structure. This second volume includes a series of case studies demonstrating how various methods and procedures in Volume 1 can be applied to important and topical areas of inorganic spectroscopy and electronic structure
Author: Chintamani Nagesa Ramachandra Rao
Publisher:
Published: 1971
Total Pages: 311
ISBN-13:
DOWNLOAD EBOOKAuthor: Edward I. Solomon
Publisher: Wiley-Interscience
Published: 1999-06-23
Total Pages: 754
ISBN-13:
DOWNLOAD EBOOKIncludes information on modern, state-of-the-art & widely applied techniques. * Covers fundamental concepts & timely applications of the methodology in the field. * Illustrates modern procedures for collecting & processing electronic spectroscopic & structural data. * Includes case studies written by key people in the field showing application in important & topical areas of inorganic spectroscopy & electronic structure.
Author: Mandeep Dalal
Publisher: Dalal Institute
Published: 2017-01-01
Total Pages: 480
ISBN-13: 8193872002
DOWNLOAD EBOOKAn advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory, dπ -pπ bonds, Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions, Trends in stepwise constants, Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand, Chelate effect and its thermodynamic origin, Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes, Mechanisms for ligand replacement reactions, Formation of complexes from aquo ions, Ligand displacement reactions in octahedral complexes- acid hydrolysis, Base hydrolysis, Racemization of tris chelate complexes, Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes, The trans effect, Theories of trans effect, Mechanism of electron transfer reactions – types; Outer sphere electron transfer mechanism and inner sphere electron transfer mechanism, Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory, Molecular orbital theory, octahedral, tetrahedral or square planar complexes, π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals, Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states), Calculation of Dq, B and β parameters, Effect of distortion on the d-orbital energy levels, Structural evidence from electronic spectrum, John-Tellar effect, Spectrochemical and nephalauxetic series, Charge transfer spectra, Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry, Guoy’s method for determination of magnetic susceptibility, Calculation of magnetic moments, Magnetic properties of free ions, Orbital contribution, effect of ligand-field, Application of magneto-chemistry in structure determination, Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes, Wade’s rules, Carboranes, Metal Carbonyl Clusters - Low Nuclearity Carbonyl Clusters, Total Electron Count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls, structure and bonding, Vibrational spectra of metal carbonyls for bonding and structure elucidation, Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Author: C.N.R. Rao
Publisher: Elsevier
Published: 2012-12-02
Total Pages: 328
ISBN-13: 0323155790
DOWNLOAD EBOOKSpectroscopy in Inorganic Chemistry, Volume II is a collection of research studies on some of the spectroscopic methods and areas of inorganic chemistry in which spectroscopy has been used effectively. This book is divided into seven chapters that present the status reports and potentialities in the fields of study. Each chapter outlines the theoretical and experimental aspects, as well as the application to a specific field of the analytical method. The first three chapters deal with the molecular structure determination by neutron and X-ray diffraction, high-pressure vibrational spectroscopy, and electronic Raman transitions of rare earth ions. Other chapters explore the potential of electron spin resonance spectroscopy for inorganic radical and radical ion determination, as well as the application of electron spin resonance for coordination compound analysis. The remaining chapters examine the use of electronic spectroscopy for organometalloid study and the fluorescence and laser action in rare earth chelates. This book is intended primarily for analytical and inorganic chemists and spectroscopists who are interested in inorganic systems.
Author: C. R. Brundle
Publisher: Mittal Publications
Published: 2002
Total Pages: 274
ISBN-13: 9788170998259
DOWNLOAD EBOOKAuthor: H. C. Baldry
Publisher:
Published: 1968
Total Pages:
ISBN-13:
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