A comprehensive introduction to inorganic chemistry and, specifically, the science of metal-based drugs, Essentials of Inorganic Chemistry describes the basics of inorganic chemistry, including organometallic chemistry and radiochemistry, from a pharmaceutical perspective. Written for students of pharmacy and pharmacology, pharmaceutical sciences, medicinal chemistry and other health-care related subjects, this accessible text introduces chemical principles with relevant pharmaceutical examples rather than as stand-alone concepts, allowing students to see the relevance of this subject for their future professions. It includes exercises and case studies.
The last two decades have seen a renaissance in interest in the chemistry of the main group elements. In particular research on the metals of group 13 (aluminium, gallium, indium and thallium) has led to the synthesis and isolation of some very novel and unusual molecules, with implications for organometallic synthesis, new materials development, and with biological, medical and, environmental relevance. The Group 13 Metals Aluminium, Gallium, Indium and Thallium aims to cover new facts, developments and applications in the context of more general patterns of physical and chemical behaviour. Particular attention is paid to the main growth areas, including the chemistry of lower formal oxidation states, cluster chemistry, the investigation of solid oxides and hydroxides, advances in the formation of III-V and related compounds, the biological significance of Group 13 metal complexes, and the growing importance of the metals and their compounds in the mediation of organic reactions. Chapters cover: general features of the group 13 elements group 13 metals in the +3 oxidation state: simple inorganic compounds formal oxidation state +3: organometallic chemistry formal oxidation state +2: metal-metal bonded vs. mononuclear derivatives group 13 metals in the +1 oxidation state mixed or intermediate valence group 13 metal compounds aluminium and gallium clusters: metalloid clusters and their relation to the bulk phases, to naked clusters, and to nanoscaled materials simple and mixed metal oxides and hydroxides: solids with extended structures of different dimensionalities and porosities coordination and solution chemistry of the metals: biological, medical and, environmental relevance III-V and related semiconductor materials group 13 metal-mediated organic reactions The Group 13 Metals Aluminium, Gallium, Indium and Thallium provides a detailed, wide-ranging, and up-to-date review of the chemistry of this important group of metals. It will find a place on the bookshelves of practitioners, researchers and students working in inorganic, organometallic, and materials chemistry.
Emphasises on contemporary applications and an intuitive problem-solving approach that helps students discover the exciting potential of chemical science. This book incorporates fresh applications from the three major areas of modern research: materials, environmental chemistry, and biological science.
Boron has all the best tunes. That may well be the first impression of the Group 13 elements. The chemical literature fosters the impression not only in the primary journals, but also in asteady outflowofbooks focussing more or less closely on boron and its compounds. The same preoccupation with boron is apparent in the coverage received by the Group 13 elements in the comprehensive and regularly updated volume of the Gmelin Handbook. Yet such an imbalance cannot be explained by any inherent lack ofvariety, interest or consequence in the 'heavier elements. Aluminium is the most abundant metal in the earth's crust; in the industrialised world the metal is second only to iron in its usage, and its compounds can justifiably be said to touch our lives daily - to the potential detriment of those and other lives, some would argue. From being chemical curios, gallium and indium have now gained considerably prominence as sources of compound semiconductors like gallium arsenide and indium antimonide. Nor is there any want ofincident in the chemistriesofthe heavier Group 13 elements. In their redox, coordination and structural properties, there is to be found music indeed, notable not always for its harmony but invariably for its richness and variety. Thisbook seeks to redress the balance with a definitive, wide-rangingand up-to-date review of the chemistry of the Group 13 metals aluminium, gallium, indium and thallium.
The main group elements represent the most prevalent elements in the Earth's crust, as well as most of the key elements of life, and have enormous industrial, economic, and environmental importance. In this regard an understanding of the chemistry of the main group elements is vital for students within science, engineering, and medicine; however, it is hoped that those who make political and economic decisions would make better ones (or at least more responsible ones) if they had a fraction of the knowledge of the world around them.
Group 13 Chemistry: From Fundamentals to Applications contains research reports and review articles in both the fundamental and applied aspects of group 13 chemistry. Topics covered illustrate the widespread influence of group 13 chemistry in modern science and technology. This volume addresses recent research and technological achievements involving group 13 chemistry and provides important background information for both experienced practitioners and novices. New developments in group 13 compounds, the stabilization of compounds of the lighter group 13 elements in their +1 oxidation state, and electron-deficient group 13 clusters, are presented. Because of the unusual geometries of newly developed electron-deficient group 13 clusters, chemists have had to reexamine and refine their models of structure and bonding. Furthermore, the stabilization of compounds of the lighter group 13 elements in their +1 oxidation state has produced some unique molecular structures and reactivity. Group 13 compounds are well known as reagents for organic synthesis and as both catalysts and cocatalysts for asymmetric organic transformations and alkene and ring-opening polymerization. Now, the design of multidentate Lewis acids is expected to exhibit enhanced activity via the cooperation of multiple electrophilic sites. Finally, a special section devoted to aluminum chemistry examines the environmental sources and biological effects of this most abundant metal. Research implicating aluminum in the etiology of neurological diseases is examined as well as potentially useful biochemical applications for aluminum in the form of Al4-.
'This is an an absolutely wonderful book that is full of gems about the elements and the periodic table … All in all, the book is highly recommended to philosophers of chemistry. As philosophers we have a natural tendency to concentrate on generalities and not to get too involved in the specifics and the details. Above all else, this new book reminds us that such an approach needs to be tempered by a detailed knowledge of the exceptions and features that go against the simplified generalities which we so cherish.' [Read Full Review]Eric ScerriFoundations of Chemistry'Many questions are dealt with in a clearly written way in this stimulating and innovative book. The reader will quickly become interested in the subject and will be taken on tour through this Periodic Table in a very readable way, both for students and teachers … The number of illustrations is good, and clear. This book is indeed unique and quite thought-provoking … This book is highly recommended for students, teachers, researchers and not only chemists! Geologists, biochemist and also physicists will find it very interesting to read.' [Read Full Review]Chemistry InternationalThat fossilized chart on every classroom wall — isn't that The Periodic Table? Isn't that what Mendeléev devised about a century ago? No and No. There are many ways of organizing the chemical elements, some of which are thought-provoking, and which reveal philosophical challenges. Where does hydrogen 'belong'? Can an element occupy more than one location on the chart? Which are the Group 3 elements? Is aluminum in the wrong place? Why is silver(I) like thallium(I)? Why is vanadium like molybdenum? Why does gold form an auride ion like a halide ion? Does an atom 'know' if it is a non-metal or metal? Which elements are the 'metalloids'? Which are the triels? So many questions! In this stimulating and innovative book, the Reader will be taken on a voyage from the past to the present to the future of the Periodic Table. This book is unique. This book is readable. This book is thought-provoking. It is a multi-dimensional examination of patterns and trends among the chemical elements. Every reader will discover something about the chemical elements which will provoke thought and a new appreciation as to how the elements relate together.
With more than 20 contributions from leading research groups, this book provides essential information for chemists and materials scientists working with molecular clusters. It treats both homonuclear and heteronuclear clusters, including: the theory and concepts in main-group cluster chemistry, * novel boranes and heteroboranes, * silicon/germanium/tin clusters, * alkali metal suboxides, * clusters in alloys with mercury, * chalkogen clusters * and numerous other compound classes. The whole is illustrated by examples of the great potential for technical applications such as electron storage, cancer therapy and in optoelectronic devices. Its systematic coverage of all relevant main group elements makes this the prime reference source in the field.
Over the last decade our view of chemistry has evolved substantially. Whereas individual researchers previously focused on specific areas of chemistry, such as inorganic, organic, etc. we now take a more holistic approach. Effective and efficient research projects now incorporate whatever aspects of the chemistry subdisciplines that are needed to complete the intended work. The main group elements have always been used in this manner. Depending on the use of the elements, the resulting work can be described under any heading of chemistry. The group 13 elements have been special in this regard due to the very unique characters of the constituent elements. Thus, there is a dramatic change in the properties of the elements when proceeding through the series, B, A1, Ga, In, T1. This difference is one of the main reasons why these elements have seen, and continue to see, such widespread usage in such disparate applications as organic synthesis, electronic and structural materials, and catalysis, to name but a few.
Involved as it is with 95% of the periodic table, inorganic chemistry is one of the foundational subjects of scientific study. Inorganic catalysts are used in crucial industrial processes and the field, to a significant extent, also forms the basis of nanotechnology. Unfortunately, the subject is not a popular one for undergraduates. This book aims to take a step to change this state of affairs by presenting a mechanistic, logical introduction to the subject. Organic teaching places heavy emphasis on reaction mechanisms - "arrow-pushing" - and the authors of this book have found that a mechanistic approach works just as well for elementary inorganic chemistry. As opposed to listening to formal lectures or learning the material by heart, by teaching students to recognize common inorganic species as electrophiles and nucleophiles, coupled with organic-style arrow-pushing, this book serves as a gentle and stimulating introduction to inorganic chemistry, providing students with the knowledge and opportunity to solve inorganic reaction mechanisms. • The first book to apply the arrow-pushing method to inorganic chemistry teaching • With the reaction mechanisms approach ("arrow-pushing"), students will no longer have to rely on memorization as a device for learning this subject, but will instead have a logical foundation for this area of study • Teaches students to recognize common inorganic species as electrophiles and nucleophiles, coupled with organic-style arrow-pushing • Provides a degree of integration with what students learn in organic chemistry, facilitating learning of this subject • Serves as an invaluable companion to any introductory inorganic chemistry textbook
