Functional Metal-Organic Frameworks: Gas Storage, Separation and Catalysis
Functional Metal-Organic Frameworks: Gas Storage, Separation and Catalysis

Author: Martin Schröder

Publisher: Springer Science & Business Media

Published: 2010-09-07

Total Pages: 270

ISBN-13: 3642146120

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- Microporous Organic Polymers: Design, Synthesis, and Function By J.-X. Jiang and A. I. Cooper - Hydrogen, Methane and Carbon Dioxide Adsorption in Metal-Organic Framework Materials By X. Lin, N. R. Champness, and M. Schröder -Doping of Metal-Organic Frameworks with Functional Guest Molecules and Nanoparticles By F. Schröder and R. A. Fischer -Chiral Metal-Organic Porous Materials: Synthetic Strategies and Applications in Chiral Separation and Catalysis By K. Kim, M. Banerjee, M. Yoon, and S. Das -Controlled Polymerization by Incarceration of Monomers in Nanochannels By T. Uemura and S. Kitagawa -Designing Metal-Organic Frameworks for Catalytic Applications L. Ma and W. Lin -Magnetic and Porous Molecule-Based Materials By N. Roques, V. Mugnaini, and J. Veciana

Metal-Organic Frameworks
Metal-Organic Frameworks

Author: David Farrusseng

Publisher: John Wiley & Sons

Published: 2011-09-19

Total Pages: 415

ISBN-13: 3527635866

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An international and interdisciplinary team of leading experts from both academia and industry report on the wide range of hot applications for MOFs, discussing both the advantages and limits of the material. The resulting overview covers everything from catalysis, H2 and CH4 storage and gas purification to drug delivery and sensors. From the Contents: - Design of Porous Coordination Polymers/Metal-Organic Frameworks: Past, Present and Future - Design of Functional Metal-Organic Frameworks by Post-Synthetic Modification - Thermodynamic Methods for Prediction of Gas Separation in Flexible Frameworks - Separation and purification of gases by MOFs - Opportunities for MOFs in CO2 capture from flue gases, natural gas and syngas by adsorption - Manufacture of MOF thin films on structured supports for separation and catalysis - Research status of Metal-Organic Frameworks for on-board cryo-adsorptive hydrogen storage applications - Separation of xylene isomers - Metal-Organic Frameworks as Catalysts for Organic Reactions - Biomedical applications of Metal Organic Frameworks - Metal Organic Frameworks for Biomedical Imaging - Luminescent Metal-Organic Frameworks - Deposition of thin films for sensor applications - Industrial MOF Synthesis - MOF shaping and immobilisation A must-have for every scientist in the field.

Metal-Organic Framework Materials
Metal-Organic Framework Materials

Author: Leonard R. MacGillivray

Publisher: John Wiley & Sons

Published: 2014-09-19

Total Pages: 1210

ISBN-13: 1118931580

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Metal-Organic Frameworks (MOFs) are crystalline compounds consisting of rigid organic molecules held together and organized by metal ions or clusters. Special interests in these materials arise from the fact that many are highly porous and can be used for storage of small molecules, for example H2 or CO2. Consequently, the materials are ideal candidates for a wide range of applications including gas storage, separation technologies and catalysis. Potential applications include the storage of hydrogen for fuel-cell cars, and the removal and storage of carbon dioxide in sustainable technical processes. MOFs offer the inorganic chemist and materials scientist a wide range of new synthetic possibilities and open the doors to new and exciting basic research. Metal-Organic Frameworks Materials provides a solid basis for the understanding of MOFs and insights into new inorganic materials structures and properties. The volume also reflects progress that has been made in recent years, presenting a wide range of new applications including state-of-the art developments in the promising technology for alternative fuels. The comprehensive volume investigates structures, symmetry, supramolecular chemistry, surface engineering, recognition, properties, and reactions. The content from this book will be added online to the Encyclopedia of Inorganic and Bioinorganic Chemistry: http://www.wileyonlinelibrary.com/ref/eibc

Metal-Organic Frameworks with Heterogeneous Structures
Metal-Organic Frameworks with Heterogeneous Structures

Author: Ali Morsali

Publisher: John Wiley & Sons

Published: 2021-10-12

Total Pages: 226

ISBN-13: 1119792045

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METAL-ORGANIC FRAMEWORKS WITH HETEROGENEOUS STRUCTURES A unique book that sheds light on Metal-Organic Frameworks complex systems that often display behaviors that surprise and cannot be easily described. In this book, MOF-based heterostructures technology with key characteristics is completely analyzed and the current state-of-the-art is discussed. The authors focus on the complex heterostructures promoted by MOFs with advantage of their recent new advances for various applications with particular emphasis on their design. As an extension of the design and synthesis, the shaping technology of heterostructure MOFs is also of great significance to the future practical applications in industry (adsorption/desorption, gas storage, catalysis, conductivity, optical activity) of this class of complex porous materials. As this unique book covers all of the aspects of complexity in MOFs with heterogeneous structures, it serves as an essential reference to the concepts of introducing complexity to designing the future new platforms of materials with advanced and superior properties. This important compact book provides the reader with: The principal aspects of heterogeneity that produce complexity in MOFs, their effects in the structure chemistry, performance and applications The effects of complexities on the structure of metal-organic frameworks The roles of complexities on metal-organic frameworks applications Explanation of synthesis strategies of the complex heterostructure MOFs. Audience This book will be beneficial for chemists, materials engineers, advanced postgraduate and graduate students, researchers and specialists who are working in the area of materials design and their chemistry, porous crystalline materials, coordination polymers, hybrid and functional materials, as well as industry professionals, such as those working on selective catalysis and adsorption-separation, optics, gas capture, processes of biological and pharmaceutical.

Functional Metal-organic Frameworks
Functional Metal-organic Frameworks

Author: Ali Morsali

Publisher:

Published: 2021

Total Pages:

ISBN-13: 9781119640998

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In this book, application of functional metal-organic frameworks in environmental and energy science especially separation of pollutant gases, storage of explosive and energy gases, detection and purification of hazardous chemicals, designing ion/electro conductive and heterogeneous catalysis is discussed repeatedly. So, the content of this book can be useful in industry for designing novel MOF-based adsorbents, catalysts and conductive materials.

Advanced Functional Metal-Organic Frameworks
Advanced Functional Metal-Organic Frameworks

Author: Jay Singh

Publisher: CRC Press

Published: 2023-05-01

Total Pages: 335

ISBN-13: 1000862798

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Due to the structural flexibility, large surface area, tailorable pore size and functional tenability, metal-organic frameworks (MOFs) can lead to materials with unique properties. This book covers the fundamental aspects of MOFs, their synthesis and modification, including their potential applications in different domains. The major focus is on applications including chemical, biosensors, catalysis, drug delivery, supercapacitors, energy storage, magnetics and their future perspectives. The volume: Covers all aspects related to metal-organic frameworks (MOFs), including characterization, modification, applications and associated challenges Illustrates designing and synthetic strategies for MOFs Describes MOFs for gas adsorption, separation and purification, and their role in heterogeneous catalysis Covers sensing of different types of noxious substances in the aqueous environment Includes concepts of molecular magnetism, tunable magnetic properties and future aspects This book is aimed at graduate students, and researchers in material science, coordination and industrial chemistry, chemical and environmental engineering and clean technologies.

Metal-Organic Frameworks
Metal-Organic Frameworks

Author: Hermenegildo García

Publisher: John Wiley & Sons

Published: 2018-02-22

Total Pages: 534

ISBN-13: 3527809120

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Focusing on applications in separation, adsorption and catalysis, this handbook underlines the importance of this hot and exciting topic. It provides an excellent insight into the synthesis and modification of MOFs, their synthesis on an industrial scale, their use as CO2 and chemical warfare adsorbers, and the role of defects in catalysis. In addition, the authors treat such new aspects as biocatalysis and applications in photocatalysis and optoelectronic devices.

Functionalized Metal-organic Frameworks for Applications in Gas Storage and Catalysis
Functionalized Metal-organic Frameworks for Applications in Gas Storage and Catalysis

Author: Phuong Viet Dau

Publisher:

Published: 2014

Total Pages: 201

ISBN-13: 9781321516371

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Metal-organic frameworks (MOFs) are 3-dimensional (3D) inorganic-organic hybrid materials. Due to their hybrid structures, MOFs have been increasingly become attractive materials for energy related applications. In recent years, many methods have been investigated and utilized to functionalize MOFs with a variety of chemical groups to enhance its properties. Among these methods, prefunctionalization and postsynthetic modification methods (PSM) have been proven to be versatile and accessible pathways to incorporate functional groups into MOFs. In this dissertation, the use of prefunctionalization and PSM methods to decorate MOFs with functionalities, and an overview of functionalized MOFs for applications in gas storage and catalysis will be highlighted and investigated. In the first part of the dissertation, a series of free phenylpyridine functionalized MOFs are synthesized and characterized. These MOFs are further decorated with Ir(I) and Rh(I) via cyclometalation reactions using PSM method. Amazingly, a selective PSM on an interpenetrated MOF is unprecedentedly observed. The selective outcome of the PSM is the result of the spatial difference between of chemically modifiable sites within the interpenetrated framework. In the second haft of this dissertation, Ir(I)phenylpyrdine functionalized MOFs are showed to be effective, stable, and reusable heterogeneous catalysts for allylic N-alkylation of amines. Furthermore, the use of prefunctionalization and PSM methods are utilized for the rational synthesis of a bifunctional, site-isolated MOF that has both organocatalytic -NH2 and organometallic Ir(I)phenylpyridine. The bifunctional MOF is further investigated as a tandem catalyst for one-pot condensation and alkylation reactions. Lastly, the synthesis of the first pair of isomeric MOFs is realized via prefunctionalization and PSM methods. More importantly, these cubic isoreticular MOFs with disordered ordered phenyl amide substituents displayed drastic differences in their sorption toward both N2 and H2. This observed differences suggest a new strategy to modulate H2 sorption of MOFs and to potentially produce MOFs with ideal behaviors for application in H2 storage.

Metal-Organic Framework Composites
Metal-Organic Framework Composites

Author: Anish Khan

Publisher: Materials Research Forum LLC

Published: 2019-10-25

Total Pages: 426

ISBN-13: 1644900424

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Because of their nanoporous structures and ultra-high surface areas Metal-Organic Framework Composites (MOFs) are very interesting materials. The book focusses on the following applications: gas capture and storage, especially molecular hydrogen storage; performance enhancement of Li-ion batteries; gas separation, nano-filtration, ionic sieving, water treatment, and catalysis; sustainable renewable energy resources, electrochemical capacitors, including supercapacitors, asymmetric supercapacitors and hybrid supercapacitors; biomedical disciplines including drug delivery, theranostics; biological detection and imaging; nanoparticle photosensitizers for photodynamic therapy (PDT) and photothermal therapy (PTT). Keywords: MOF Materials, Hydrogen Storage, Renewable Energy Applications, Lithium Batteries, MOF-Quantum Dots, Clean Energy, Nanoporous MOFs, Supercapacitors, Therapeutic Applications, Biosensing, Bioimaging, Phototherapy of Cancer, Gas Separation, Nano-filtration, Ionic Sieving, Water Treatment, Drug Delivery, Theranostics; Nanoparticle Photosensitizers, Photodynamic Therapy (PDT), Photothermal Therapy (PTT).

Pillared Metal-Organic Frameworks
Pillared Metal-Organic Frameworks

Author: Lida Hashemi

Publisher: John Wiley & Sons

Published: 2019-04-30

Total Pages: 378

ISBN-13: 1119460247

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In the last two decades, metal-organic frameworks (MOFs) have provoked considerable interest due to their potential applications in different fields such as catalysis, gas storage and sensing. The most important advantages of MOFs over other porous materials is the ability of tailoring their pore size, functionality and even the topology of the framework by rational selection of the molecular building blocks. Therefore, many chemists have tried to engineer the structure of MOFs to achieve specific functions. Pillared metal organic frameworks are a class of MOFs composed of inorganic secondary building units (SBUs) and two sets of organic linkers, generally oxygen- and nitrogen-donor ligands. Typically, in the structure of pillared MOFs, the oxygen-donor struts link the metal clusters into a two-dimensional (2D) sheet and the N-donor struts pillar the sheets to generate a three-dimensional (3D) framework. Thus, the construction of MOFs by utilizing two sets of organic linkers could provide an extra possibility for further tuning of MOF’s pore walls. A variety of functional groups including imine, amide and heterocycles were successfully incorporated into bidentate pillar ligand skeleton. Interestingly, by using pillaring linkers with different length, a wide diversity of metal-organic frameworks with tunable pore dimensions and topologies can be obtained. In this book, we introduce pillared metal organic frameworks with their properties and applications.