Based on the Solvay conference, which gathers the leading scientists in the field, this monograph collects review articles from the six topics of the conference, while also including comments, discussions and debates obtained during the conference. The issues discussed at this landmark conference were: * Noncovalent Assemblies: Design and Synthesis * Template Synthesis of Catenanes and Rotaxanes * Molecular Machines Based on Catenanes and Rotaxanes * Molecular Machines Based on Non-Interlocking Molecules * Towards Molecular Logics and Artificial Photosynthesis * From Single Molecules to Practical Devices and the authors add their personal views on the future of each of their own research areas. Novel reading for organic, inorganic and polymer chemists, as well as materials scientists.
The chapters in this volume describe bottom-up strategies and chronicle cutting-edge advances from several of the world’s leading laboratories engaged in the development of molecular machines. The Nobel Prize in Chemistry 2016 was awarded jointly to Jean-Pierre Sauvage, Sir J. Fraser Stoddart and Bernard L. Feringa "for the design and synthesis of molecular machines". Both Jean-Pierre Sauvage and Sir J. Fraser Stoddart have also contributed to this book.
“The story is told by THE inventor-pioneer-master in the field and is accompanied by amazing illustrations… [it] will become an absolute reference and a best seller in chemistry!” Alberto Credi “… the great opus on the mechanical bond. A most impressive undertaking!” Jean-Marie Lehn Congratulations to co-author J. Fraser Stoddart, a 2016 Nobel Laureate in Chemistry. In molecules, the mechanical bond is not shared between atoms—it is a bond that arises when molecular entities become entangled in space. Just as supermolecules are held together by supramolecular interactions, mechanomolecules, such as catenanes and rotaxanes, are maintained by mechanical bonds. This emergent bond endows mechanomolecules with a whole suite of novel properties relating to both form and function. They hold unlimited promise for countless applications, ranging from their presence in molecular devices and electronics to their involvement in remarkably advanced functional materials. The Nature of the Mechanical Bond is a comprehensive review of much of the contemporary literature on the mechanical bond, accessible to newcomers and veterans alike. Topics covered include: Supramolecular, covalent, and statistical approaches to the formation of entanglements that underpin mechanical bonds in molecules and macromolecules Kinetically and thermodynamically controlled strategies for synthesizing mechanomolecules Chemical topology, molecular architectures, polymers, crystals, and materials with mechanical bonds The stereochemistry of the mechanical bond (mechanostereochemistry), including the novel types of dynamic and static isomerism and chirality that emerge in mechanomolecules Artificial molecular switches and machines based on the large-amplitude translational and rotational motions expressed by suitably designed catenanes and rotaxanes. This contemporary and highly interdisciplinary field is summarized in a visually appealing, image-driven format, with more than 800 illustrations covering both fundamental and applied research. The Nature of the Mechanical Bond is a must-read for everyone, from students to experienced researchers, with an interest in chemistry’s latest and most non-canonical bond. Read the Preface
This book commemorates the 25th anniversary of the International Izatt-Christensen Award in Macrocyclic and Supramolecular Chemistry. The award, one of the most prestigious of small awards in chemistry, recognizes excellence in the developing field of macrocyclic and supramolecular chemistry Macrocyclic and Supramolecular Chemistry: How Izatt-Christensen Award Winners Shaped the Field features chapters written by the award recipients who provide unique perspectives on the spectacular growth in these expanding and vibrant fields of chemistry over the past half century, and on the role of these awardees in shaping this growth. During this time there has been an upsurge of interest in the design, synthesis and characterization of increasingly more complex macrocyclic ligands and in the application of this knowledge to understanding molecular recognition processes in host-guest chemistry in ways that were scarcely envisioned decades earlier. In October 2016, Professor Jean-Pierre Sauvage and Sir J. Fraser Stoddart (author for chapter 22 "Contractile and Extensile Molecular Systems: Towards Molecular Muscles" by Jean -Pierre Sauvage, Vincent Duplan, and Frédéric Niess and 20 "Serendipity" by Paul R. McGonigal and J. Fraser Stoddart respectively) were awarded the Nobel Prize in Chemistry alongside fellow Wiley author Bernard Feringa, for the design and synthesis of molecular machines.
A must-have resource that covers everything from out-of-equilibrium chemical systems and materials to dissipative self-assemblies Out-of-Equilibrium Supramolecular Systems and Materials presents a comprehensive overview of the synthetic approaches that use supramolecular bonds in various out-of-thermodynamic equilibrium situations. With contributions from noted experts on the topic, the text contains information on the design of dissipative self-assemblies that maintain their structures when fueled by an external source of energy. The contributors also examine molecules and nanoscale objects and materials that can produce mechanical work based on molecular machines. Additionally, the book explores non-equilibrium supramolecular polymers that can be trapped in kinetically stable states, as well as out-of-equilibrium chemical systems and oscillators that are important to understand the emergence of complex behaviors and, in particular, the origin of life. This important book: Offers comprehensive coverage of fields from design of dissipative self-assemblies to non-equilibrium supramolecular polymers Presents information on a highly emerging and interdisciplinary topic Includes contributions from internationally renowned scientists Written for chemists, physical chemists, biochemists, material scientists, Out-of-Equilibrium Supramolecular Systems and Materials is an indispensable resource written by top scientists in the field.
Advances in Nanostructured Materials and Nanopatterning Technologies: Applications for Healthcare, Environment and Energy demonstrates how to apply micro- and nanofabrication and bioextrusion based systems for cell printing, electrophoretic deposition, antimicrobial applications, and nanoparticles technologies for use in a range of green industry sectors, with an emphasis on emerging applications. - Details strategies to design and realize smart nanostructured/patterned substrates for healthcare and energy and environmental applications - Enables the preparation, characterization and fundamental understanding of nanostructured materials for promising applications in health, environmental and energy related sectors - Provides a broader view of the context around existing projects and techniques, including discussions on potential new routes for fabrication
This book provides a wide-ranging overview of the current state-of-the-art and new trends in photodetector design and research. Written by a team of internationally renowned experts, with contributions from universities, research institutes and industries, this work is suitable for students and professionals interested in studying and dealing with photodetector design and technology, as well as the wide gamut of related applications. Its coverage includes: physics and fundamentals of photodetectors; physical models of photodetector operation; new materials, design, processing and function of photodetectors in related applications; testing, monitoring and calibration; and research progress in photodetector-related areas. Theoretical aspects, design and simulation principles, and important experimental results are thoroughly addressed, embodying a comprehensive account of current activity in this important field of research and industry.
This book is a compilation of research works on electrochemistry in the broadest of its meanings, carried out by Spanish and Portuguese researchers around 2019. It aims to collect the most significant of our research and to show the excellent level that these works have in comparison with the international state of the art. The selection of works, in an extended abstract format, is based on the papers presented as invited plenary conferences and keynote oral communications at the XL Meeting of the Specialized Electrochemistry Group of the Spanish Royal Society of Chemistry and the XX Iberian Electrochemistry Meeting, which took place in the city of Huelva (Spain) between 9th and 12th July 2019. In an attempt to cover the work of Iberian electrochemists in the most complete and representative way possible, several invited chapters have been added to this set of works. On some occasions, the authors have reported on potential legal problems regarding the publication rights of their work, mainly due to the high interest in their results and the fact that they had already been submitted to very high impact journals for publication. In this case, they have been allowed to replace their original work by a mini review of their laboratory's line of research, keeping as much as possible the same research topic.
Este libro es la recopilación de resúmenes de las comunicaciones presentadas en formato Oral o Poster en el Congreso anual del Grupo de Electroquímica de la RSEQ, que este año es adem·s el Congreso Ibérico de Electroquímica al incluir también a la Sociedad Portuguesa de Electroquímica. Su publicación recopila lo mejor y mas reciente de la investigación que, sobre la disciplina electroquímica, se realiza en la penÌnsula ibérica. Tambien incluye los Trabajos Fin de Master de los alumnos del Master Interuniversitario de Electroquímica y los Proyectos de Tesis del programa de Doctorado relacionado, por lo que refleja el futuro más próximo de la electroquímica en nuestros países.
Collating our current knowledge and the latest developments for enabling breakthrough discoveries, this book focuses on the synthesis and applications of materials that are based on supramolecular assemblies of carbon nanostructures, with an emphasis on fullerenes and nanotubes. In so doing, it provides readers with an overview of the different types of supramolecular architectures, accentuating the outstanding geometrical, electronic and photophysical properties of the building blocks and the resulting structures. It makes use of basic concepts and real-life applications -- from simple syntheses to complex architectures, from instructive examples to working experimental procedures, and from photophysics to solar cells. A large part of each chapter is devoted to the methods and possibilities of controlling and tuning these molecular assemblies in order to obtain working devices. Fascinating reading for materials scientists, organic chemists, molecular physicists, and those in the semiconductor industry.
