Effect of Pulsations on Black Liquor Gasification. Progress Report, July--September 1995

Effect of Pulsations on Black Liquor Gasification. Progress Report, July--September 1995

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Published: 1995

Total Pages: 3

ISBN-13:

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The objective of this study is to investigate the use of pulse combustion to provide the energy required for the endothermic gasification of black liquor in a fluidized bed. In this process it is critical that the temperature remain in the small window above the gasification temperature but below the smelting temperature of the inorganic salts in the black liquor. Pulse combustors have been shown to have high heat transfer rates between the hot combustion products and the combustor tailpipe. Similarly, fluidized beds have high heat transfer rates within the bed itself, promoting temperature uniformity throughout. Typical analysis of the gasified black liquor shows there is a large percentage of combustible gases in the products of the gasification process (approximately 70%). The potential exists, therefore, for using this fuel mixture to fire the pulse combustor. This makes the entire process more efficient and may be necessary to make it economically feasible. The overall goals of this study are to determine (1) which is the limiting heat transfer rate in the process of transferring the heat from the hot combustion products to the pipe, through the pipe, from the tailpipe to the bed and then throughout the bed; i.e., whether increased heat transfer within the pulse combustor will significantly increase the overall heat transfer rate; (2) whether the temperature distribution in the bed can be maintained within the narrow temperature range required by the process without generating hot spots in the bed even if the heat transfer from the pulse combustor is significantly increased; and (3) whether the fuel gas produced during the gasification process can be used to efficiently fire the pulse combustor.


Effect of Pulsation on Black Liquor Gasification. Final Report

Effect of Pulsation on Black Liquor Gasification. Final Report

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Published: 1998

Total Pages: 51

ISBN-13:

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Pyrolysis is an endothermic process. The heat of reaction is provided either by partial combustion of the waste or by heat transfer from an external combustion process. In one proposed system black liquor is pyrolized in a fluidized bed to which heat is added through a series of pulse combustor tail pipes submerged in the bed material. This system appears promising because of the relatively high heat transfer in pulse combustors and in fluidized beds. Other advantages of pulse combustors are discussed elsewhere. The process is, however, only economically viable if a part of the pyrolysis products can be used to fire the pulse combustors. The overall goals of this study were to determine: (1) which is the limiting heat transfer rate in the process of transferring heat from the hot combustion products to the pipe, through the pipe, from the tail pipe to the bed and through the bed; i.e., whether increased heat transfer within the pulse combustor will significantly increase the overall heat transfer rate; (2) whether the heat transfer benefits of the pulse combustor can be utilized while maintaining the temperature in the bed within the narrow temperature range required by the process without generating hot spots in the bed; and (3) whether the fuel gas produced during the gasification process can be used to efficiently fire the pulse combustor.


Fundamental Study of Black Liquor Gasification Kinetics Using a Pressurized Entrained-flow Reactor (PEFR). Quarterly Progress Report for the Period July 1999 to September 1999

Fundamental Study of Black Liquor Gasification Kinetics Using a Pressurized Entrained-flow Reactor (PEFR). Quarterly Progress Report for the Period July 1999 to September 1999

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Published: 1999

Total Pages: 2

ISBN-13:

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The goal of the program is to identify the optimal operating window for black liquor gasification. The goals during this year are to prepare the PEFR for operation, conduct a series of preliminary screening tests to bracket BLG operating conditions, and develop a process model that can guide identification of the optimal operating window.


Fundamental Study of Black Liquor Gasification Kinetics. Quarterly Progress Report for the Period October 1999 to December 1999

Fundamental Study of Black Liquor Gasification Kinetics. Quarterly Progress Report for the Period October 1999 to December 1999

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Published: 2000

Total Pages: 14

ISBN-13:

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The overall objective of this research is to evaluate the kinetics of gasification of kraft black liquor under laboratory conditions simulating pressurized, oxygen-blown gasification. The significant independent variables are gasifier temperature, black liquor composition particle size, and particle residence time. The authors will quantify their impact on the concentration of major and trace gas phase species, as well as the composition of condensed phase inorganic products, including specification of the Na- and S-containing compounds and overall carbon conversion.


Black Liquor Gasification

Black Liquor Gasification

Author: Pratima Bajpai

Publisher: Elsevier

Published: 2014-03-06

Total Pages: 103

ISBN-13: 0081000154

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Black Liquor Gasification (BLG) is a first of its kind to guide chemical engineers, students, operators of paper plants, technocrats, and entrepreneurs on practical guidelines and a holistic techno-enviro-economic perspective applicable to their future or existing projects based on the treatment of black liquor for energy production. BLG describes the gasification process as a more efficient alternative to current processes for the conversion of black liquor biomass into energy. BLG operates largely in sync with other methods to improve pulp-making efficiency. This book explains how BLG offers a way to generate electricity and to reclaim pulping chemicals from black liquor, and why BLG would replace the Tomlinson recovery boiler for the recovery of spent chemicals and energy. Describes the utilization of black liquor as a source of energy Provides a detailed account of black liquor gasification processes for the production of energy and chemicals from black liquor Provides guidelines to chemical engineers for the treatment of black liquor