Understanding oxidation resistance of Pt-based alloys through computations of Ellingham diagrams with experimental verifications

Understanding oxidation resistance of Pt-based alloys through computations of Ellingham diagrams with experimental verifications

Author: Xiaoyu Chong

Publisher: OAE Publishing Inc.

Published: 2023-10-12

Total Pages: 18

ISBN-13:

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Thermodynamic calculations of Ellingham diagrams and the forming oxides have been performed relevant to the Pt-based alloys Pt82Al12M6 (M = Cr, Hf, Pt, and Ta). The predicted Ellingham diagrams indicate that the elements Hf and Al are easy to oxidize, followed by Ta and Cr, while Pt is extremely difficult to oxidize. Oxidation experiments characterized by X-ray diffraction (XRD) and electron probe micro-analyzers verify the present thermodynamic predictions, showing that the best alloy with superior oxidation resistance is Pt82Al12Cr6, followed by Pt88Al12 due to the formation of the dense and continuous α-Al2O3 scale on the surface of alloys; while the worse alloy is Pt82Al12Hf6 followed by Pt82Al12Ta6 due to drastic internal oxidation and the formation of deleterious HfO2, AlTaO4, and Ta2O5. The present work, combining computations with experimental verifications, provides a fundamental understanding and knowledgebase to develop Pt-based superalloys with superior oxidation resistance that can be used in ultra-high temperatures.


Computational Thermodynamics of Materials

Computational Thermodynamics of Materials

Author: Zi-Kui Liu

Publisher: Cambridge University Press

Published: 2016-06-30

Total Pages: 261

ISBN-13: 0521198968

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Integrates fundamental concepts with experimental data and practical applications, including worked examples and end-of-chapter problems.


Oxidation of Tungsten

Oxidation of Tungsten

Author: Vincent David Barth

Publisher:

Published: 1961

Total Pages: 192

ISBN-13:

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The report presents a detailed review of available information on the oxidation of W and its alloys. W is relatively inert below 700 C. As the temperature is increased above this level, however, oxidation becomes progressively more rapid, reaching catastrophic rates at temperatures around 1200 C and above. Various theories for the mechanism and rates of W oxidation at different temperatures are reviewed, and the effect of pressure and water vapor on the stability of W oxides is discussed in detail. The elevatedtemperature reactions of W with other materials, such as refractory oxides, and with gases other than oxygen also are covered. Information on the protection of W by alloying and coating is included. (Author).


Research Opportunities in Corrosion Science and Engineering

Research Opportunities in Corrosion Science and Engineering

Author: National Research Council

Publisher: National Academies Press

Published: 2011-01-27

Total Pages: 192

ISBN-13: 0309187680

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The field of corrosion science and engineering is on the threshold of important advances. Advances in lifetime prediction and technological solutions, as enabled by the convergence of experimental and computational length and timescales and powerful new modeling techniques, are allowing the development of rigorous, mechanistically based models from observations and physical laws. Despite considerable progress in the integration of materials by design into engineering development of products, corrosion considerations are typically missing from such constructs. Similarly, condition monitoring and remaining life prediction (prognosis) do not at present incorporate corrosion factors. Great opportunities exist to use the framework of these materials design and engineering tools to stimulate corrosion research and development to achieve quantitative life prediction, to incorporate state-of-the-art sensing approaches into experimentation and materials architectures, and to introduce environmental degradation factors into these capabilities. Research Opportunities in Corrosion Science and Engineering identifies grand challenges for the corrosion research community, highlights research opportunities in corrosion science and engineering, and posits a national strategy for corrosion research. It is a logical and necessary complement to the recently published book, Assessment of Corrosion Education, which emphasized that technical education must be supported by academic, industrial, and government research. Although the present report focuses on the government role, this emphasis does not diminish the role of industry or academia.


Aerospace Alloys

Aerospace Alloys

Author: Stefano Gialanella

Publisher: Springer Nature

Published: 2019-10-30

Total Pages: 583

ISBN-13: 3030244407

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This book presents an up-to-date overview on the main classes of metallic materials currently used in aeronautical structures and propulsion engines and discusses other materials of potential interest for structural aerospace applications. The coverage encompasses light alloys such as aluminum-, magnesium-, and titanium-based alloys, including titanium aluminides; steels; superalloys; oxide dispersion strengthened alloys; refractory alloys; and related systems such as laminate composites. In each chapter, materials properties and relevant technological aspects, including processing, are presented. Individual chapters focus on coatings for gas turbine engines and hot corrosion of alloys and coatings. Readers will also find consideration of applications in aerospace-related fields. The book takes full account of the impact of energy saving and environmental issues on materials development, reflecting the major shifts that have occurred in the motivations guiding research efforts into the development of new materials systems. Aerospace Alloys will be a valuable reference for graduate students on materials science and engineering courses and will also provide useful information for engineers working in the aerospace, metallurgical, and energy production industries.


Introduction to Corrosion Science

Introduction to Corrosion Science

Author: E. McCafferty

Publisher: Springer Science & Business Media

Published: 2010-01-04

Total Pages: 583

ISBN-13: 1441904549

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This textbook is intended for a one-semester course in corrosion science at the graduate or advanced undergraduate level. The approach is that of a physical chemist or materials scientist, and the text is geared toward students of chemistry, materials science, and engineering. This textbook should also be useful to practicing corrosion engineers or materials engineers who wish to enhance their understanding of the fundamental principles of corrosion science. It is assumed that the student or reader does not have a background in electrochemistry. However, the student or reader should have taken at least an undergraduate course in materials science or physical chemistry. More material is presented in the textbook than can be covered in a one-semester course, so the book is intended for both the classroom and as a source book for further use. This book grew out of classroom lectures which the author presented between 1982 and the present while a professorial lecturer at George Washington University, Washington, DC, where he organized and taught a graduate course on “Environmental Effects on Materials.” Additional material has been provided by over 30 years of experience in corrosion research, largely at the Naval Research Laboratory, Washington, DC and also at the Bethlehem Steel Company, Bethlehem, PA and as a Robert A. Welch Postdoctoral Fellow at the University of Texas. The text emphasizes basic principles of corrosion science which underpin extensions to practice.


Applications of Process Engineering Principles in Materials Processing, Energy and Environmental Technologies

Applications of Process Engineering Principles in Materials Processing, Energy and Environmental Technologies

Author: Shijie Wang

Publisher: Springer

Published: 2017-02-07

Total Pages: 549

ISBN-13: 3319510916

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This collection offers new research findings, innovations, and industrial technological developments in extractive metallurgy, energy and environment, and materials processing. Technical topics included in the book are thermodynamics and kinetics of metallurgical reactions, electrochemical processing of materials, plasma processing of materials, composite materials, ionic liquids, thermal energy storage, energy efficient and environmental cleaner technologies and process modeling. These topics are of interest not only to traditional base ferrous and non-ferrous metal industrial processes but also to new and upcoming technologies, and they play important roles in industrial growth and economy worldwide.


Handbook of Corrosion Engineering

Handbook of Corrosion Engineering

Author: Pierre Roberge

Publisher: McGraw-Hill Prof Med/Tech

Published: 1999-09-30

Total Pages: 1154

ISBN-13: 0070765162

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Reduce the enormous economic and environmental impact of corrosion Emphasizing quantitative techniques, this guide provides you with: *Theory essential for understanding aqueous, atmospheric, and high temperature corrosion processes Corrosion resistance data for various materials Management techniques for dealing with corrosion control, including life prediction and cost analysis, information systems, and knowledge re-use Techniques for the detection, analysis, and prevention of corrosion damage, including protective coatings and cathodic protection More


Fundamentals of Metallurgy

Fundamentals of Metallurgy

Author: S Seetharaman

Publisher: Elsevier

Published: 2005-10-10

Total Pages: 589

ISBN-13: 184569094X

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As product specifications become more demanding, manufacturers require steel with ever more specific functional properties. As a result, there has been a wealth of research on how those properties emerge during steelmaking. Fundamentals of metallurgy summarises this research and its implications for manufacturers.The first part of the book reviews the effects of processing on the properties of metals with a range of chapters on such phenomena as phase transformations, types of kinetic reaction, transport and interfacial phenomena. Authors discuss how these processes and the resulting properties of metals can be modelled and predicted. Part two discusses the implications of this research for improving steelmaking and steel properties.With its distinguished editor and international team of contributors, Fundamentals of metallurgy is an invaluable reference for steelmakers and manufacturers requiring high-performance steels in such areas as automotive and aerospace engineering. It will also be useful for those dealing with non-ferrous metals and alloys, material designers for functional materials, environmentalists and above all, high technology industries designing processes towards materials with tailored properties. - Summarises key research and its implications for manufacturers - Essential reading for steelmakers and manufacturers - Written by leading experts from both industry and academia