Transition Metals-Based Metal-Organic Frameworks, Synthesis, and Environmental Applications
Transition Metals-Based Metal-Organic Frameworks, Synthesis, and Environmental Applications

Author: José María María Rivera

Publisher:

Published: 2018

Total Pages: 0

ISBN-13:

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This work illustrates examples of metal-organic frameworks (MOFs) derived from transition metals and their environmental applications in areas of catalysis, sorption, and hydrogen evolution. Explanation of some of the techniques employed for their synthesis has been discussed. On the other hand, the advantages of the use of hybrid materials such as the metal-organic frameworks are exposed in this book as well a detailed description of the different linkers and metals used for the synthesis of this kind of porous materials going through the methodologies and techniques utilized by different authors to obtain good-quality crystalline applicable materials. Adjustments of linker geometry, length, ratio, and the functional group can tune the size, shape, and internal surface property of an MOF for a targeted application. The uses of MOFs are exploring new different areas of chemistry such as catalysis, adsorption, carrier systems, hydrogen evolution, photocatalysis, and more. Different examples of MOFs from Scandium to Zinc are well described in this book, and finally, a brief description of some common environmental applications such as metals and azo dyes sorption, hydrogen evolution, and catalyst in the transesterification process of vegetable oils to produce biodiesel is explored and commented.

Metal-Organic Frameworks (MOFs) for Environmental Applications
Metal-Organic Frameworks (MOFs) for Environmental Applications

Author: Sujit K. Ghosh

Publisher: Elsevier

Published: 2019-06-07

Total Pages: 464

ISBN-13: 0128146346

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Metal-Organic Frameworks for Environmental Applications examines this important topic, looking at potential materials and methods for the remediation of pressing pollution issues, such as heavy-metal contaminants in water streams, radioactive waste disposal, marine oil-spillage, the treatment of textile and dye industry effluents, the clean-up of trace amounts of explosives in land and water, and many other topics. This survey of the cutting-edge research and technology of MOFs is an invaluable resource for researchers working in inorganic chemistry and materials science, but it is also ideal for graduate students studying MOFs and their applications. Examines the applications of metal-organic frameworks for the remediation of environmental pollutants Features leading experts who research the applications of MOFs from around the world, including contributions from the United States, India and China Explores possible solutions to some of today’s most pressing environmental challenges, such as heavy-metal contamination in bodies of water, oil spills and clean-up of explosives hidden in land and water Provides an excellent reference for researchers and graduate students studying in the areas of inorganic chemistry, materials chemistry and environmental science

Synthesis of Metal-Organic Frameworks via Water-Based Routes
Synthesis of Metal-Organic Frameworks via Water-Based Routes

Author: Yasser Azim

Publisher: Elsevier

Published: 2023-10-20

Total Pages: 334

ISBN-13: 0323959407

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Synthesis of Metal-Organic Frameworks via Water-Based Routes: A Green and Sustainable Approach describes a sustainable approach for the synthesis of metal-organic frameworks. Bringing together chapters on the aqueous synthesis and stability of metal-organic frameworks, as well as the applications of water stable metal-organic frameworks, this timely book shows how green processing technology utilizing water as a main solvent for the synthesis of metal-organic frameworks can eliminate solvent consumption, lower investment costs and reduce energy requirements. Providing quantitative descriptions and reliable guidelines, the book summarizes the fundamental approaches and principles to prepare metal-organic frame works, highlighting the most exciting preparations and applications. Includes the role of water in metal organic synthesis Describes various methods of metal-organic framework preparation Covers the industrial aspects of water-based metal-organic frameworks and potential applications

Metal-Organic Frameworks for Chemical Reactions
Metal-Organic Frameworks for Chemical Reactions

Author: Anish Khan

Publisher: Elsevier

Published: 2021-01-19

Total Pages: 501

ISBN-13: 0128232625

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Metal-Organic Frameworks for Chemical Reactions: From Organic Transformations to Energy Applications brings together the latest information on MOFs materials, covering recent technology in the field of manufacturing and design. The book covers different aspects of reactions from energy storage and catalysts, including preparation, design and characterization techniques of MOFs material and applications. This comprehensive resource is ideal for researchers and advanced students studying metal-organic frameworks in academia and industry. Metal-organic frameworks (MOFs) are nanoporous polymers made up of inorganic metal focuses connected by natural ligands. These entities have become a hot area of research because of their exceptional physical and chemical properties that make them useful in di?erent ?elds, including medicine, energy and the environment. Since combination conditions strongly a?ect the properties of these compounds, it is especially important to choose an appropriate synthetic technique that produces a product with homogenous morphology, small size dispersion, and high thermal stability. Covers the synthetic advantages and versatile applications of metal-organic frameworks (MOFs) due to their organic-inorganic hybrid nature and unique porous structure Includes energy applications such as batteries, fuel storage, fuel cells, hydrogen evaluation reactions and super capacitors Features information on using MOFs as a replacement to conventional engineering materials because they are lightweight, less costly, environmentally-friendly and sustainable

Fabrication of Metal–Organic Framework Derived Nanomaterials and Their Electrochemical Applications
Fabrication of Metal–Organic Framework Derived Nanomaterials and Their Electrochemical Applications

Author: Wei Xia

Publisher: Springer

Published: 2018-04-03

Total Pages: 148

ISBN-13: 9811068119

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This thesis systematically introduces readers to a new metal-organic framework approach to fabricating nanostructured materials for electrochemical applications. Based on the metal-organic framework (MOF) approach, it also demonstrates the latest ideas on how to create optimal MOF and MOF-derived nanomaterials for electrochemical reactions under controlled conditions. The thesis offers a valuable resource for researchers who want to understand electrochemical reactions at nanoscale and optimize materials from rational design to achieve enhanced electrochemical performance. It also serves as a useful reference guide to fundamental research on advanced electrochemical energy storage materials and the synthesis of nanostructured materials.

Introduction to Reticular Chemistry
Introduction to Reticular Chemistry

Author: Omar M. Yaghi

Publisher: John Wiley & Sons

Published: 2019-03-22

Total Pages: 684

ISBN-13: 3527821104

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A concise introduction to the chemistry and design principles behind important metal-organic frameworks and related porous materials Reticular chemistry has been applied to synthesize new classes of porous materials that are successfully used for myraid applications in areas such as gas separation, catalysis, energy, and electronics. Introduction to Reticular Chemistry gives an unique overview of the principles of the chemistry behind metal-organic frameworks (MOFs), covalent organic frameworks (COFs), and zeolitic imidazolate frameworks (ZIFs). Written by one of the pioneers in the field, this book covers all important aspects of reticular chemistry, including design and synthesis, properties and characterization, as well as current and future applications Designed to be an accessible resource, the book is written in an easy-to-understand style. It includes an extensive bibliography, and offers figures and videos of crystal structures that are available as an electronic supplement. Introduction to Reticular Chemistry: -Describes the underlying principles and design elements for the synthesis of important metal-organic frameworks (MOFs) and related materials -Discusses both real-life and future applications in various fields, such as clean energy and water adsorption -Offers all graphic material on a companion website -Provides first-hand knowledge by Omar Yaghi, one of the pioneers in the field, and his team. Aimed at graduate students in chemistry, structural chemists, inorganic chemists, organic chemists, catalytic chemists, and others, Introduction to Reticular Chemistry is a groundbreaking book that explores the chemistry principles and applications of MOFs, COFs, and ZIFs.

Metal, Metal-Oxides and Metal-Organic Frameworks for Environmental Remediation
Metal, Metal-Oxides and Metal-Organic Frameworks for Environmental Remediation

Author: Saravanan Rajendran

Publisher: Springer Nature

Published: 2021-05-05

Total Pages: 285

ISBN-13: 303068976X

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This book reviews principles, techniques and applications of metal, metal oxides, metal sulfides and metal-organic frameworks for removal and degradation of pollutants. Natural materials are often much more advanced than synthetic materials in terms of circularity and are functional, often biodegradable, recyclable and generate little waste. They are, therefore, a source of inspiration for new synthetic materials. In particular, recent research has focused on various types of functional materials such as organic, inorganic, nanostructured and composites for the remediation of environmental pollution.

Metal-Organic Framework Materials
Metal-Organic Framework Materials

Author: Leonard R. MacGillivray

Publisher: John Wiley & Sons

Published: 2014-09-19

Total Pages: 1210

ISBN-13: 1118931580

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Metal-Organic Frameworks (MOFs) are crystalline compounds consisting of rigid organic molecules held together and organized by metal ions or clusters. Special interests in these materials arise from the fact that many are highly porous and can be used for storage of small molecules, for example H2 or CO2. Consequently, the materials are ideal candidates for a wide range of applications including gas storage, separation technologies and catalysis. Potential applications include the storage of hydrogen for fuel-cell cars, and the removal and storage of carbon dioxide in sustainable technical processes. MOFs offer the inorganic chemist and materials scientist a wide range of new synthetic possibilities and open the doors to new and exciting basic research. Metal-Organic Frameworks Materials provides a solid basis for the understanding of MOFs and insights into new inorganic materials structures and properties. The volume also reflects progress that has been made in recent years, presenting a wide range of new applications including state-of-the art developments in the promising technology for alternative fuels. The comprehensive volume investigates structures, symmetry, supramolecular chemistry, surface engineering, recognition, properties, and reactions. The content from this book will be added online to the Encyclopedia of Inorganic and Bioinorganic Chemistry: http://www.wileyonlinelibrary.com/ref/eibc

Biocompatible Hybrid Oxide Nanoparticles for Human Health
Biocompatible Hybrid Oxide Nanoparticles for Human Health

Author: Inna V. Melnyk

Publisher: Elsevier

Published: 2019-06-30

Total Pages: 288

ISBN-13: 0128161884

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Biocompatible Hybrid Oxide Nanoparticles for Human Health: From Synthesis to Applications explores the synthesis, structure, properties and applications of functionalized oxide nanoparticles. The books shows the applications of materials depending on their composition and structure, with a focus on silicon, titanium and iron oxides, each of which was chosen because of their unique features, including silica because it is chemically resistant to most organic solvents, harmless to living organisms, can thicken flowable formulations, and increase the strength of materials, titania for its unique chemical, optical, electrophysical and bactericidal properties, and iron-containing materials because they possess important magnetic properties. Shows how oxide nanoparticles are being used to solve current problems in the fields of environmental protection, medicine, and in the creation of "smart" materials Includes case studies that explore the major characteristics and applications of silica, titania and iron oxide nanomaterials Discusses the use of biocompatible oxide nanostructures in the development of new sensing technology