The only text to cover both thermodynamic and statistical mechanics--allowing students to fully master thermodynamics at the macroscopic level. Presents essential ideas on critical phenomena developed over the last decade in simple, qualitative terms. This new edition maintains the simple structure of the first and puts new emphasis on pedagogical considerations. Thermostatistics is incorporated into the text without eclipsing macroscopic thermodynamics, and is integrated into the conceptual framework of physical theory.
This textbook explains the meaning of heat and work and the definition of energy and energy systems. It describes the constructive role of entropy growth and makes the case that energy matters, but entropy growth matters more. Readers will learn that heat can be transferred, produced, and extracted, and that the understanding of generalized heat extraction will revolutionize the design of future buildings as thermal systems for managing low grade heat and greatly contribute to enhanced efficiency of tomorrow’s energy systems and energy ecosystems. Professor Wang presents a coherent theory-structure of thermodynamics and clarifies the meaning of heat and the definition of energy in a manner that is both scientifically rigorous and engaging, and explains contemporary understanding of engineering thermodynamics in continuum of its historical evolution. The textbook reinforces students’ grasp of concepts with end-of-chapter problems and provides a historical background of pioneering work by Black, Laplace, Carnot, Joule, Thomson, Clausius, Maxwell, Planck, Gibbs, Poincare and Prigogine. Developed primarily as a core text for graduate students in engineering programs, and as reference for professional engineers, this book maximizes readers’ understanding and shines a light on new horizons for our energy future.
Designed as an undergraduate-level textbook in Chemical Engineering, this student-friendly, thoroughly class-room tested book, now in its second edition, continues to provide an in-depth analysis of chemical engineering thermodynamics. The book has been so organized that it gives comprehensive coverage of basic concepts and applications of the laws of thermodynamics in the initial chapters, while the later chapters focus at length on important areas of study falling under the realm of chemical thermodynamics. The reader is thus introduced to a thorough analysis of the fundamental laws of thermodynamics as well as their applications to practical situations. This is followed by a detailed discussion on relationships among thermodynamic properties and an exhaustive treatment on the thermodynamic properties of solutions. The role of phase equilibrium thermodynamics in design, analysis, and operation of chemical separation methods is also deftly dealt with. Finally, the chemical reaction equilibria are skillfully explained. Besides numerous illustrations, the book contains over 200 worked examples, over 400 exercise problems (all with answers) and several objective-type questions, which enable students to gain an in-depth understanding of the concepts and theory discussed. The book will also be a useful text for students pursuing courses in chemical engineering-related branches such as polymer engineering, petroleum engineering, and safety and environmental engineering. New to This Edition • More Example Problems and Exercise Questions in each chapter • Updated section on Vapour–Liquid Equilibrium in Chapter 8 to highlight the significance of equations of state approach • GATE Questions up to 2012 with answers
Four-part treatment covers principles of quantum statistical mechanics, systems composed of independent molecules or other independent subsystems, and systems of interacting molecules, concluding with a consideration of quantum statistics.
Heat and Thermodynamics is written for General Physics courses that emphasise temperature dependent phenomena. New ideas are introduced with accompanying appropriate experiments.
A thorough understanding of statistical mechanics depends strongly on the insights and manipulative skills that are acquired through the solving of problems. Problems on Statistical Mechanics provides over 120 problems with model solutions, illustrating both basic principles and applications that range from solid-state physics to cosmology. An introductory chapter provides a summary of the basic concepts and results that are needed to tackle the problems, and also serves to establish the notation that is used throughout the book. The problems themselves occupy five chapters, progressing from the simpler aspects of thermodynamics and equilibrium statistical ensembles to the more challenging ideas associated with strongly interacting systems and nonequilibrium processes. Comprehensive solutions to all of the problems are designed to illustrate efficient and elegant problem-solving techniques. Where appropriate, the authors incorporate extended discussions of the points of principle that arise in the course of the solutions. The appendix provides useful mathematical formulae.
Essentials of Thermodynamics offers a fresh perspective on classical thermodynamics and its explanation of natural phenomena. It combines fundamental principles with applications to offer an integrated resource for students, teachers and experts alike. The essence of classic texts has been distilled to give a balanced and in-depth treatment, including a detailed history of ideas which explains how thermodynamics evolved without knowledge of the underlying atomic structure of matter. The principles are illustrated by a vast range of applications, such as osmotic pressure, how solids melt and liquids boil, the incredible race to reach absolute zero, and the modern theme of the renormalization group. Topics are handled using a variety of techniques, which helps readers see how concepts such as entropy and free energy can be applied to many situations, and in diverse ways. The book has a large number of solved examples and problems in each chapter, as well as a carefully selected guide to further reading. The treatment of traditional topics like the three laws of thermodynamics, Carnot cycles, Clapeyron equation, phase equilibria, and dilute solutions is considerably more detailed than usual. For example, the chapter on Carnot cycles discusses exotic cases like the photon cycle along with more practical ones like the Otto, Diesel and Rankine cycles. There is a chapter on critical phenomena that is modern and yet highly pedagogical and contains a first principles calculation of the critical exponents of Van der Waals systems. Topics like entropy constants, surface thermodynamics, and superconducting phase transitions are explained in depth while maintaining accessibility for different readers.
The canonical ensemble - Other ensembles and fluctuations - Boltzmann statistics, fermi-dirac statistics, and bose-einstein statistics - Ideal monatomic gas - Ideal diatomic - Classical statistical mechanics - Ideal polyatomic - Chemical equilibrium - Quantum statistics - Crystals - Imperfect gases - Distribution functions in classical monatomic liquids - Perturbation theories of liquids - Solutions of strong electrolytes - Kinetic theory of gases and molecular collisions - Continuum mechanics - Kinetic theory of-gases and the boltzmann equation - Transport processes in dilute gases - Theory of brownian motion - The time-correlation function formalism.
This book focuses on nonextensive statistical mechanics, a current generalization of Boltzmann-Gibbs (BG) statistical mechanics. Conceived nearly 150 years ago by Maxwell, Boltzmann and Gibbs, the BG theory, one of the greatest monuments of contemporary physics, exhibits many impressive successes in physics, chemistry, mathematics, and computational sciences. Presently, several thousands of publications by scientists around the world have been dedicated to its nonextensive generalization. A variety of applications have emerged in complex systems and its mathematical grounding is by now well advanced. Since the first edition release thirteen years ago, there has been a vast amount of new results in the field, all of which have been incorporated in this comprehensive second edition. Heavily revised and updated with new sections and figures, the second edition remains the go-to text on the subject. A pedagogical introduction to the BG theory concepts and their generalizations – nonlinear dynamics, extensivity of the nonadditive entropy, global correlations, generalization of the standard CLT’s, complex networks, among others – is presented in this book, as well as a selection of paradigmatic applications in various sciences together with diversified experimental verifications of some of its predictions. Introduction to Nonextensive Statistical Mechanics is suitable for students and researchers with an interest in complex systems and statistical physics.
