Liquids and Liquid Mixtures

Liquids and Liquid Mixtures

Author: J S Rowlinson

Publisher: Butterworth-Heinemann

Published: 2013-09-03

Total Pages: 337

ISBN-13: 1483140679

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Liquids and Liquid Mixtures, Third Edition explores the equilibrium properties of liquids and liquid mixtures and relates them to the properties of the constituent molecules using the methods of statistical thermodynamics. Topics covered include the critical state, fluid mixtures at high pressures, and the statistical thermodynamics of fluids and mixtures. This book consists of eight chapters and begins with an overview of the liquid state and the thermodynamic properties of liquids and liquid mixtures, including vapor pressure and heat capacities. The discussion then turns to the thermodynamics of and inequalities at the critical point; measurement of thermodynamic functions in the critical region; experimental values of the critical exponents; and scaling of the free energy. The change of thermodynamic functions with composition is the subject of the next two chapters, followed by an analysis of fluid mixtures at high pressures. The final chapter is devoted to the statistical thermodynamics of fluids and mixtures, paying particular attention to the thermodynamic properties in terms of the forces between the molecules; the balance of intermolecular potentials between like and unlike molecules; and phase behavior. This monograph will be of interest to students and researchers in the fields of chemistry and chemical engineering.


Molecular Thermodynamics of Nonideal Fluids

Molecular Thermodynamics of Nonideal Fluids

Author: Lloyd L. Lee

Publisher: Butterworth-Heinemann

Published: 1988

Total Pages: 520

ISBN-13:

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The statistical ensembles - The ideal gas - The structure of liquids - Microthermodynamics - Integral equation theories - Theories for polar fluids - Hard spheres and hard-core fluids - The lennard-jones fluid - Solution thermodynamics - The perturbation theories - Electrolyte solutions - Molecular dynamics - Interaction site models for polyatomics - Adsorption : the solid-fluid interface.


Thermodynamics

Thermodynamics

Author: Jean Vidal

Publisher: Editions OPHRYS

Published: 1980

Total Pages: 522

ISBN-13: 9782710811183

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The simulation and optimization of processes assumes that the thermodynamic properties and phase equilibria of the mixtures concerned are well known. This knowledge is still based upon experimentation, but it is also the result of calculation methods based on the principles of thermodynamics that govern them, insure their coherence, and confer upon them a wide range of application. This text is concerned primarily with the description of these methods and their evolution. It devotes extensive space to fundamental concepts and places particular emphasis on the models that, although based on simplified concepts of the subject matter at the molecular level, have predictive character. Computational examples are used to explain the application of these concepts and models. Contents: 1. Principles. Thermodynamic functions. The ideal gas. 2. Properties of pure substances. 3. Predicting thermodynamic properties of pure substances. General principles. Corresponding states. Group contributions. 4. Equations of state. 5. Characterization of mixtures. 6. Mixtures: liquid-vapor equilibria. 7. Deviations from ideality in the liquid phase. 8. Application of equations of state to mixtures. Calculation of liquid-vapor equilibria under pressure. 9. Liquid-liquid and liquid-liquid-vapor equilibria. 10. Fluid-solid equilibria. Crystallization. Hydrates. 11. Polymer solutions and alloys. 12. Multicomponent mixtures. 13. Chemical reactions. Appendixes. Index. Bibliography.


Thermodynamics

Thermodynamics

Author: William C. Reynolds

Publisher: Cambridge University Press

Published: 2018-09-20

Total Pages: 425

ISBN-13: 1108546730

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This concise text provides an essential treatment of thermodynamics and a discussion of the basic principles built on an intuitive description of the microscopic behavior of matter. Aimed at a range of courses in mechanical and aerospace engineering, the presentation explains the foundations valid at the macroscopic level in relation to what happens at the microscopic level, relying on intuitive and visual explanations which are presented with engaging cases. With ad hoc, real-word examples related also to current and future renewable energy conversion technologies and two well-known programs used for thermodynamic calculations, FluidProp and StanJan, this text provides students with a rich and engaging learning experience.


An Introduction to Physical Chemistry

An Introduction to Physical Chemistry

Author: Ishwar Das

Publisher: New Age International

Published: 2012

Total Pages: 368

ISBN-13: 9788122415605

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In This Broad Introduction To Physical Chemistry, The Authors Have Included The Essential Elements Of Physical Chemistry, Paying Careful Attention To The Presentation Of Material. It Also Includes Some Chapters Of New Thrusts And Frontiers Viz. Reaction Dynamics, Oscillatory Chemical Reactions, Fast Reactions Kinetics, Polymer Chemistry, Environmental Chemistry And Statistical Thermodynamics, Glossary And Latest Examination Questions Are Given At The End Of Most Chapters To Provide Practice In The Subject. The Book Can Therefore Be Used To Meet The Demands Of A Large Number Of Undergraduate Chemistry Students Of Indian Universities. It May Also Be Used As A Reference Book For Postgraduate Students.


Integrated Design and Simulation of Chemical Processes

Integrated Design and Simulation of Chemical Processes

Author: Alexandre C. Dimian

Publisher: Elsevier

Published: 2003-05-13

Total Pages: 715

ISBN-13: 0080534805

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This title aims to teach how to invent optimal and sustainable chemical processes by making use of systematic conceptual methods and computer simulation techniques. The material covers five sections: process simulation; thermodynamic methods; process synthesis; process integration; and design project including case studies. It is primarily intended as a teaching support for undergraduate and postgraduate students following various process design courses and projects, but will also be of great value to professional engineers interested in the newest design methods.Provides an introduction to the newest design methods.Of great value to undergraduate and postgraduate students as well as professional engineers.Numerous examples illustrate theoretical priciples and design issues.