Reviews measurement of these properties in the main types of polymers in use today. Numerous techniques are discussed ranging from thermogravimetric analysis, differential scanning calorimetry, infrared and nuclear magnetic resonance based methods to pyrolytic techniques such as those based on pyrolysis, gas chromatography and mass spectrometry.
Understanding the thermal degradation of polymers is of paramount importance for developing a rational technology of polymer processing and higher-temperature applications. Controlling degradation requires understanding of many different phenomena, including chemical mechanisms, the influence of polymer morphology, the complexities of oxidation chemistry, and the effects of stabilisers, fillers and other additives. This book offers a wealth of information for polymer researchers and processors requiring an understanding of the implications of thermal degradation on material and product performance.
This reference guide brings together a wide range of essential data on the effect of long term thermal exposure on plastics and elastomers, enabling engineers to make optimal material choices and design decisions. The data is supported by explanations of how to make use of the data in real-world engineering contexts. High heat environments are common in automotive, oil and gas, household appliances, coatings, space and aeronautics and many more end uses. As a result, thermal stability data are critically important to engineers designing parts particularly that replace metals, work that is common today as they look for ways to reduce weight. The data tables in this book enable engineers and scientists to select the right materials for a given product or application across a wide range of sectors. Several polymer classes are covered, including polyolefins, polyamides, polyesters, elastomers, fluoropolymers, biodegradable plastics and more, saving readers the need to contact suppliers. The book also includes introductory sections to provide background on plastic/polymer chemistry and formulation and plastic testing methods, providing the knowledge required to make best use of the data. Essential data and practical guidance for engineers and scientists working with plastics for use in high temperature environments Includes introductory chapters on polymer chemistry and its effect on thermal stability, providing the underpinning knowledge required to utilize the data Covers a wide range of commercial polymer classes, saving readers the need to contact suppliers
Strong bonds form stronger materials. For this reason, the investigation on thermal degradation of materials is a significantly important area in research and development activities. The analysis of thermal stability can be used to assess the behavior of materials in the aggressive environmental conditions, which in turn provides valuable information about the service life span of the materiel. Unlike other books published so far that have focused on either the fundamentals of thermal analysis or the degradation pattern of the materials, this book is specifically on the mechanism of degradation of materials. The mechanism of rapturing of chemical bonds as a result of exposure to high-temperature environment is difficult to study and resulting mechanistic pathway hard to establish. Limited information is available on this subject in the published literatures and difficult to excavate. Chapters in this book are contributed by the experts working on thermal degradation and analysis of the wide variety of advanced and traditional materials. Each chapter discusses the material, its possible application, behavior of chemical entities when exposed to high-temperature environment and mode and the mechanistic route of its decomposition. Such information is crucial while selecting the chemical ingredients during the synthesis or development of new materials technology.
Presents a solid introduction to thermal analysis, methods, instrumentation, calibration, and application along with the necessary theoretical background. Useful to chemists, physicists, materials scientists, and engineers who are new to thermal analysis techniques, and to existing users of thermal analysis who wish expand their experience to new techniques and applications Topics covered include Differential Scanning Calorimetry and Differential Thermal Analysis (DSC/DTA), Thermogravimetry, Thermomechanical Analysis and Dilatometry, Dynamic Mechanical Analysis, Micro-Thermal Analysis, Hot Stage Microscopy, and Instrumentation. Written by experts in the various areas of thermal analysis Relevant and detailed experiments and examples follow each chapter.
Properties of Polymers: Their Correlation with Chemical Structure; Their Numerical Estimation and Prediction from Additive Group Contributions summarizes the latest developments regarding polymers, their properties in relation to chemical structure, and methods for estimating and predicting numerical properties from chemical structure. In particular, it examines polymer electrical properties, magnetic properties, and mechanical properties, as well as their crystallization and environmental behavior and failure. The rheological properties of polymer melts and polymer solutions are also considered. Organized into seven parts encompassing 27 chapters, this book begins with an overview of polymer science and engineering, including the typology of polymers and their properties. It then turns to a discussion of thermophysical properties, from transition temperatures to volumetric and calorimetric properties, along with the cohesive aspects and conformation statistics. It also introduces the reader to the behavior of polymers in electromagnetic and mechanical fields of force. The book covers the quantities that influence the transport of heat, momentum, and matter, particularly heat conductivity, viscosity, and diffusivity; properties that control the chemical stability and breakdown of polymers; and polymer properties as an integral concept, with emphasis on processing and product properties. Readers will find tables that give valuable (numerical) data on polymers and include a survey of the group contributions (increments) of almost every additive function considered. This book is a valuable resource for anyone working on practical problems in the field of polymers, including organic chemists, chemical engineers, polymer processers, polymer technologists, and both graduate and PhD students.
In recent years, multicomponent polymers have generated much interest due to their excellent properties, unique morphology and high-end applications. Book focusses on thermal, thermo-mechanical and dielectric analysis of polymers and multicomponent polymeric systems like blends, interpenetrating polymeric networks (IPNs), gels, polymer composites, nanocomposites. Through these analyses, it provides an insight into the stability of polymer systems as a function of time, processing and usage. Aimed at polymer chemists, physicists and engineers, it also covers ASTM /ISO and other standards of various measurement techniques for systematic analysis in materials science.
This book is focused primarily on polymer nanocomposites, based on the author's research experience as well as open literature. The environmental health and safety aspects of nanomaterials and polymer nanocomposites, risk assessment and safety standards, and fire toxicity of polymer nanocomposites, are studied. In the final chapter, a brief overview of opportunities, trends, and challenges of polymer nanocomposites are included. Throughout the book, the theme is developed that polymer nanocomposites are a whole family of polymeric materials whose properties are capable of being tailored to meet specific applications. This volume serves as a general introduction to students and researchers just entering the field and to scholars from other subfields seeking information.
Natural Fiber-Reinforced Composites In-depth overview of thermal analysis of natural fiber-reinforced composites In Natural Fiber-Reinforced Composites: Thermal Properties and Applications, a team of distinguished researchers has delivered a comprehensive overview of the thermal properties of natural fiber-reinforced polymer composites. The book brings together information currently dispersed throughout the scientific literature and offers viable and environmentally friendly alternatives to conventional composites. The book highlights the thermal analysis of natural fiber-reinforced composites with techniques such as Thermogravimetric Analysis, Dynamic Mechanical Analysis, Thermomechanical Analysis, Differential Scanning Calorimetry, etc. This book provides: A thorough review of the thermal characterization of natural fiber-based hybrid composites Detailed investigation of the thermal properties of polymer composites reinforced with various natural fibers such as flax fiber, pineapple leaf fiber, sisal, sugar palm, grass fiber and cane fiber Discussions on the thermal properties of hybrid natural fiber-reinforced composites with various thermosetting and thermoplastic polymers Influence of nanofillers on the thermal stability and thermal decomposition characteristics of the natural fiber-based hybrid composites Natural Fiber-Reinforced Composites: Thermal Properties and Applications is a must-read for materials scientists, polymer chemists, and professionals working in the industry. This book is ideal for readers seeking to make an informed decision regarding materials selection for applications involving thermal insulation and elevated temperature. The suitability of natural fiber-reinforced composites in the automotive, mechanical, and civil engineering sectors is highlig
Explore the diverse electrical engineering application of polymer composite materials with this in-depth collection edited by leaders in the field Polymer Composites for Electrical Engineering delivers a comprehensive exploration of the fundamental principles, state-of-the-art research, and future challenges of polymer composites. Written from the perspective of electrical engineering applications, like electrical and thermal energy storage, high temperature applications, fire retardance, power cables, electric stress control, and others, the book covers all major application branches of these widely used materials. Rather than focus on polymer composite materials themselves, the distinguished editors have chosen to collect contributions from industry leaders in the area of real and practical electrical engineering applications of polymer composites. The books relevance will only increase as advanced polymer composites receive more attention and interest in the area of advanced electronic devices and electric power equipment. Unique amongst its peers, Polymer Composites for Electrical Engineering offers readers a collection of practical and insightful materials that will be of great interest to both academic and industrial audiences. Those resources include: A comprehensive discussion of glass fiber reinforced polymer composites for power equipment, including GIS, bushing, transformers, and more) Explorations of polymer composites for capacitors, outdoor insulation, electric stress control, power cable insulation, electrical and thermal energy storage, and high temperature applications A treatment of semi-conductive polymer composites for power cables In-depth analysis of fire-retardant polymer composites for electrical engineering An examination of polymer composite conductors Perfect for postgraduate students and researchers working in the fields of electrical, electronic, and polymer engineering, Polymer Composites for Electrical Engineering will also earn a place in the libraries of those working in the areas of composite materials, energy science and technology, and nanotechnology.
