Structural Chemistry of Silicates

Structural Chemistry of Silicates

Author: F. Liebau

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 484

ISBN-13: 3642500765

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As natural minerals, silica and silicates constitute by far the largest part of the earth's crust and mantle. They are equally important as raw materials and as mass produced items. For this reason they have been the subject of scientific research by geoscientists as well as by applied scientists in cement, ceramic, glass, and other industries. Moreover, intensive fun damental research on silicates has been carried out for many years because silicates are, due to their enormous variability, ideally suited for the study of general chemical and crystallographic principles. Several excellent books on mineralogy and cement, ceramics, glass, etc. give brief, usually descriptive synopses of the structure of silicates, but do not contain detailed discussions of their structural chemistry. A number of monographs on special groups of silicates, such as the micas and clay min erals, amphiboles, feldspars, and zeolites have been published which con tain more crystal chemical information. However, no modern text has been published which is devoted to the structural chemistry of silicates as a whole. Within the last 2 decades experimental and theoretical methods have been so much improved to the extent that not only have a large number of silicate structures been accurately determined, but also a better under standing has been obtained of the correlation between the chemical composition of a silicate and its structure. Therefore, the time has been reached when a modern review of the structural chemistry of silicates has become necessary.


Physical Geology

Physical Geology

Author: Steven Earle

Publisher:

Published: 2016-08-12

Total Pages: 628

ISBN-13: 9781537068824

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This is a discount Black and white version. Some images may be unclear, please see BCCampus website for the digital version.This book was born out of a 2014 meeting of earth science educators representing most of the universities and colleges in British Columbia, and nurtured by a widely shared frustration that many students are not thriving in courses because textbooks have become too expensive for them to buy. But the real inspiration comes from a fascination for the spectacular geology of western Canada and the many decades that the author spent exploring this region along with colleagues, students, family, and friends. My goal has been to provide an accessible and comprehensive guide to the important topics of geology, richly illustrated with examples from western Canada. Although this text is intended to complement a typical first-year course in physical geology, its contents could be applied to numerous other related courses.


Differential Thermal Analysis

Differential Thermal Analysis

Author: W. Smykatz-Kloss

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 259

ISBN-13: 3642659519

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At first glance it may seem presumptuous to want to add yet another to the numerous books on Differential Thermal Analysis (DT A). Thermoanalytical methods have been in use for some time, as shown by the more than five thousand publications containing DT A or TG curves listed by SMOTHERS and CHIANG in the bibliography to their handbook and abstracted in the several volumes of Thermal Analysis Abstracts (TAA), edited by J. P. REDFERN for the International Con federation for Thermal Analysis (ICT A). Every three years the proceed ings of ICT A meetings are published, bringing the latest results of thermoanalytic research. There is also the Scifax DT A Data Index, edited by R. C. MACKENZIE (1962) and modeled on the ASTM pattern card index (used for X-ray investigations), a compilation of the DT A data for several hundred minerals, and inorganic and organic materials. The theoretical foundations of thermogravimetry and DT A have been described in detail by LEHMANN, DAS and PAETSCH (1953), R. C. MACKENZIE (1957, 1970), DUVAL (1963), WENDLANDT (1964), GARN (1965), F. PAULIK et al. (1966), SMOTHERS and CHIANG (1966), and KEATTCH (1969). Thermoanalytical results are strongly influenced by various factors relative to preparation and equipment (see 1-2. 4 of this study). This is the reason why we frequently find, in these books as well as in the Scifax-Card catalog, contradictory data on the same substance.


Structure and Chemistry of Crystalline Solids

Structure and Chemistry of Crystalline Solids

Author: Bodie Douglas

Publisher: Springer Science & Business Media

Published: 2007-03-20

Total Pages: 356

ISBN-13: 0387366873

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Understandable by anyone concerned with crystals or solid state properties dependent on structure Presents a general system using simple notation to reveal similarities and differences among crystal structures More than 300 selected and prepared figures illustrate structures found in thousands of compounds


Silicate Glasses and Melts

Silicate Glasses and Melts

Author: Bjorn Mysen

Publisher: Elsevier

Published: 2018-11-27

Total Pages: 722

ISBN-13: 0444637095

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Silicate Glasses and Melts, Second Edition describes the structure-property-composition relationships for silicate glasses and melts from a geological and industrial perspective. Updated sections include (i) characterization of silicate melt and COHN fluid structure (with and without dissolved silicate components) with pressure, temperature, and redox conditions and responses of structural variables to chemical composition, (ii) determination of solubility and solution mechanisms of COHN volatiles in silicate melts and minerals and of solubility and solution mechanisms of silicate components in COHN fluids, and (iii) effects of very high pressure on structure and properties of melts and glasses. This new book is an essential resource for researchers in a number of fields, including geology, geophysics, geoscience, volcanology, material science, glass science, petrology and mineralogy. - Brings together multidisciplinary research scattered across the scientific literature into one reference, with a focus on silicate melts and their application to natural systems - Emphasizes linking melt properties to melt structure - Includes a discussion of the pros and cons of the use of glass as a proxy for melt structure and properties - Written by highly regarded experts in the field who, among other honors, were the 2006 recipients of the prestigious G.W. Morey award of the American Ceramic Society


Structure and Properties of Silicate Melts

Structure and Properties of Silicate Melts

Author: Bjorn O. Mysen

Publisher: Elsevier Publishing Company

Published: 1988

Total Pages: 376

ISBN-13:

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Characterization of the relationships between structure and properties of materials is based on the fundamental principle that the structure of the material be determined first, followed by assessments of which structural properties may govern their properties as a function of composition, pressure, temperature and other variables. Whereas this methodology has been successfully applied to further our understanding of crystalline materials, studies of silicate melt structure are often conducted on a somewhat different basis. Rather than from direct structural determination, structure models have been developed from assumed relationships between a specific melt property and its structure. As a result, a multitude of models has evolved - many of which are mutually exclusive. The overall scope of this book is to address properties and processes of magmatic systems from the vantage point of melt structure. To this end available data in chemically increasingly complex systems are reviewed and discussed with the ultimate goal being integration of the simple system data into a model that describes complex systems such as natural magmatic liquids. Thus the book evolves from the simplest possible system, SiO 2 , to complex systems such as natural magmatic liquids. From a petrologic point of view, sufficient data have been obtained so that a general framework of the structure of magmatic liquids is in place. This framework is based on the same principles as those of crystal chemistry, modulated by the absence of long range order in amorphous material, and systematic relationships between structure and properties can be discerned at least at atmospheric pressure.


Silicate Glasses and Melts

Silicate Glasses and Melts

Author: Bjorn Mysen

Publisher: Elsevier

Published: 2005-06-16

Total Pages: 561

ISBN-13: 0080457711

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This book describes the structure-property-composition relationships for silicate glasses and melts of industrial and geological interest. From Antiquity to the 20th century, an introductory chapter presents this subject in a historical perspective. Basic concepts are then discussed in three chapters where attention is paid to the glass transition and its various consequences on melt and glass properties, to the structural and physical differences between amorphous and crystalline silicates, and to the mutual relationships between local order, energetics and physical properties. With pure SiO2 as a starting point, compositions of increasing chemical complexity are successively dealt with in a dozen chapters. The effects of network-modifying cations on structure and properties are first exemplified by alkali and alkaline earth elements. The specific influence of aluminum, iron, titanium, and phosphorus are then reviewed. With water, volatiles in the system COHS, noble gases, and halogens, the effects of volatile components are also described. The last chapter explains how the results obtained on simpler melts can be applied to chemically complex systems. In each chapter, physical and chemical properties are described first and followed by a review of glass and melt structure. When possible, pressure effects are also considered.*From SiO2 to complex silicate compositions, the physical and chemical properties of melts and glasses of geological and industrial interest*Structural characterization of melts and glasses, from ambient to high pressure and temperature*From basic concepts to an advanced level, a consistent description of the structure-property-composition relationships in glasses and melts


Silicate Melts

Silicate Melts

Author: Sharon Webb

Publisher: Springer

Published: 1997-07-17

Total Pages: 88

ISBN-13:

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This book focuses on the experimental determination of the physical properties of silicate melts and magmas close to glass transition. Abundant new data are presented. The same type of measurement is performed on a range of melts to test the effect of composition on physical properties; and a range of different techniques are used to determine the same physical properties to illustrate the relationships between the relaxation of the melt structure and the relaxation of its physical properties. This book is of interest to experimental researchers in the discussion of data obtained from both a materials science and a geoscientific point of view.


Mineralogy

Mineralogy

Author: Dexter Perkins

Publisher: Pearson

Published: 2013-08-26

Total Pages: 562

ISBN-13: 9781292039114

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This student-oriented text is written in a casual, jargon-free style to present a modern introduction to mineralogy. It emphasizes real-world applications and the history and human side of mineralogy. This book approaches the subject by explaining the larger, understandable topics first, and then explaining why the little things are important for understanding the larger picture.