The Chemistry of Nitrogen-rich Functional Groups

The Chemistry of Nitrogen-rich Functional Groups

Author: Alexander Greer

Publisher: John Wiley & Sons

Published: 2019-12-31

Total Pages: 436

ISBN-13: 1119311780

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Nitrogen is unique among the non-carbon atoms in its ability to form single, double, and triple bonds with itself, giving rise to a wide range of organic-chemical groups containing several nitrogen atoms in different states and geometries. The present volume surveys the properties and chemical behaviour of all important nitrogen-rich organic-chemical groups, including azides, azimines, aziridines, diazo compounds, nitramines, nitrenes, nitrosamines, polyazine N-oxides, tetrazoles, triazanes, triazenes, and triazoles. A special focus lies on commercially important species which are used, e. g., as powerful explosives. PATAI's Chemistry of Functional Groups publishes comprehensive reviews on all aspects of specific functional groups. Each volume contains outstanding surveys on theoretical and computational aspects, NMR, MS, other spectroscopic methods and analytical chemistry, structural aspects, thermochemistry, photochemistry, synthetic approaches and strategies, synthetic uses and applications in chemical and pharmaceutical industries, biological, biochemical and environmental aspects. To date, almost 150 volumes have been published in the series.


The Kjeldahl Method for Organic Nitrogen

The Kjeldahl Method for Organic Nitrogen

Author: R. B. Bradstreet

Publisher: Elsevier

Published: 2013-10-22

Total Pages: 248

ISBN-13: 1483258599

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The Kjeldahl Method for Organic Nitrogen volume presents a broad and comprehensive survey of the method as applied to natural products and organic nitrogen compounds. The quantitative determination of an element as widely distributed as nitrogen is of great importance, and the truth of this is borne out by the tremendous amount of literature published throughout the years. The analysis of nitrogen can be divided into two classes: inorganic and organic. This book is concerned only with organic nitrogen compounds, and specifically their determination by the Kjeldahl method. The book opens with a chapter on the historical background and the work leading to the evolution of the method. This is followed by separate chapters that discuss each of the several divisions of the method, e.g., salt addition, reduction, oxidation, catalysts, distillation.


Infrared Spectral Interpretation

Infrared Spectral Interpretation

Author: Brian C. Smith

Publisher: CRC Press

Published: 1998-12-10

Total Pages: 286

ISBN-13: 9780849324635

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This author's second volume introduces basic principles of interpreting infrared spectral data, teaching its readers to make sense of the data coming from an infrared spectrometer. Contents include spectra and diagnostic bands for the more common functional groups as well as chapters on polyester spectra and interpretation aids. Discussions include: Science of infrared interpretation Light and molecular vibrations How and why molecules absorb infrared radiation Peak heights, intensities, and widths Hydrocarbons, carbonyl groups, and molecules with C-N bonds Polymers and inorganic molecules The use of atlases, library searching, spectral subtraction, and the Internet in augmenting interpretation Each chapter presents an introduction to the nomenclature and structure of a specific functional group and proceeds with the important diagnostic bands for each group. Infrared Spectral Interpretation serves both novices and experienced practitioners in this field. The author maintains a website and blog with supplemental material. His training course schedule is also available online.


Chalcogen-nitrogen Chemistry: From Fundamentals To Applications In Biological, Physical And Materials Sciences (Updated Edition)

Chalcogen-nitrogen Chemistry: From Fundamentals To Applications In Biological, Physical And Materials Sciences (Updated Edition)

Author: Tristram Chivers

Publisher: World Scientific

Published: 2021-10-12

Total Pages: 464

ISBN-13: 981124135X

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Chalcogen-nitrogen chemistry involves the study of compounds that exhibit a linkage between nitrogen and sulfur, selenium or tellurium atoms. Since the publication of A Guide to Chalcogen-Nitrogen Chemistry in 2005, the emphasis of investigations of chalcogen-nitrogen compounds has advanced from a focus on fundamental studies to the development of practical applications, as indicated by the title of this new edition. Pharmaceutical applications of organic sulfur-nitrogen compounds include drugs for the treatment of various diseases, as well as probes for locating tumour cells. From a materials perspective, carbon-containing chalcogen-nitrogen heterocycles have applications in everyday devices such as LEDs and solar cells. A new technology based on binary sulfur nitrides is being used for fingerprint detection in forensic science. As a result, this book includes seven new chapters and updates the others with extensive literature coverage of developments since 2005 while retaining earlier seminal results. This comprehensive text is essential for anyone working in the field, and the four introductory chapters emphasise general concepts that will be helpful to the non-specialist. The treatment is unique in providing a comparison of sulfur, selenium and tellurium compounds. Each chapter is designed to be self-contained, and there are extensive cross-references between chapters.


Nitrogen in the Marine Environment

Nitrogen in the Marine Environment

Author: Edward J. Carpenter

Publisher: Elsevier

Published: 2013-10-22

Total Pages: 919

ISBN-13: 1483288293

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Nitrogen in the Marine Environment provides information pertinent to the many aspects of the nitrogen cycle. This book presents the advances in ocean productivity research, with emphasis on the role of microbes in nitrogen transformations with excursions to higher trophic levels. Organized into 24 chapters, this book begins with an overview of the abundance and distribution of the various forms of nitrogen in a number of estuaries. This text then provides a comparison of the nitrogen cycling of various ecosystems within the marine environment. Other chapters consider chemical distributions and methodology as an aid to those entering the field. This book discusses as well the enzymology of the initial steps of inorganic nitrogen assimilation. The final chapter deals with the philosophy and application of modeling as an investigative method in basic research on nitrogen dynamics in coastal and open-ocean marine environments. This book is a valuable resource for plant biochemists, microbiologists, aquatic ecologists, and bacteriologists.


Nitrogen, Oxygen, and Sulfur Ylide Chemistry

Nitrogen, Oxygen, and Sulfur Ylide Chemistry

Author: J. Stephen Clark

Publisher: Practical Approach in Chemistr

Published: 2002

Total Pages: 328

ISBN-13: 9780198500179

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Chemists from Europe, North America, Japan, and India not only describe the chemistry of the three reactive intermediates relevant to their use in synthesizing complex organic compounds, they also provide detailed protocols of methods for generating and using them in reactions. About a third of the book is devoted to nitrogen, oxygen, and sulfur ylides. The rest ammonium, oxonium, and sulfonium; azomethine, carbonyl, and thiocarbonyl; and nitrile flavors. Annotation (c)2003 Book News, Inc., Portland, OR (booknews.com).


Asymmetric Synthesis of Nitrogen Heterocycles

Asymmetric Synthesis of Nitrogen Heterocycles

Author: Jacques Royer

Publisher: John Wiley & Sons

Published: 2009-08-04

Total Pages: 425

ISBN-13: 3527625518

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Here, all aspects of the topic are presented in a compact manner. The book is clearly structured, and divided into two sections -- asymmetric synthesis of heterocycles containing only one nitrogen and that of those with more than one nitrogen as a heteroatom -- such that the necessary information may be found at a glance. The international team of authors provides important experimental procedures, including industrial applications. Essential for synthetic chemists in pharmaceutical and agrochemical chemistry.


Basic Principles of Organic Chemistry

Basic Principles of Organic Chemistry

Author: John D. Roberts

Publisher:

Published: 1977

Total Pages: 1596

ISBN-13: 9780805383218

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Introduction what is organic chemistry all about?; Structural organic chemistry the shapes of molecules functional groups; Organic nomenclature; Alkanes; Stereoisomerism of organic molecules; Bonding in organic molecules atomic-orbital models; More on nomenclature compounds other than hydrocarbons; Nucleophilic substitution and elimination reactions; Separation and purification identification of organic compounds by spectroscopic techniques; Alkenes and alkynes. Ionic and radical addition reactions; Alkenes and alkynes; Oxidation and reduction reactions; Acidity or alkynes.


The Chemistry and Biochemistry of Nitrogen Fixation

The Chemistry and Biochemistry of Nitrogen Fixation

Author: J. Postgate

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 339

ISBN-13: 1468418181

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Understanding of biological nitrogen fixation has advanced with impressive rapidity during the last decade. As befits a developing area of Science, these advances have uncovered information and raised questions which will have, and indeed have had, repercussions in numerous other branches of science and its applications. This 'information explosion', to use one of to-day's cant idioms, was initiated by the discovery, by a group of scientists working in the Central Research laboratories of Dupont de Nemours, U. S. A. , of a reproducibly active, cell-free enzyme preparation from a nitrogen fixing bacterium. Full credit is due to them. But subsequent developments, albeit sometimes quite as impressive, have too often been marked by that familiar disorder of a developing field of research-the scramble to publish. It is a scramble which, at its best, may represent a laudable desire to inform colleagues of the latest developments; yet which too easily develops into an undignified rush for priority, wherewith to impress one's Board of Directors or Grant-giving Institution. This, in miniature, is the tragedy of scientific research to-day: desire for credit causes research to be published in little bulletins, notes and preliminary communications, so that only those intimately involved in the field really know what is happening (and even they may well not see the forest for the trees). Those outside the field, or working in peripheral areas, may glean something of what is going on from reviews and fragments presented at meetings, but the broad pattern of development is often elusive.