The Molybdenum Isotopic Composition of Carbonate Rocks
Author: Andrea Voegelin
Publisher:
Published: 2009
Total Pages: 105
ISBN-13:
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Molybdenum Isotopic Composition of Modern and Carboniferous Carbonates
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DOWNLOAD EBOOKStable Isotope Geochemistry
Author: Jochen Hoefs
Publisher: Springer Nature
Published: 2021-10-08
Total Pages: 528
ISBN-13: 3030776921
DOWNLOAD EBOOKThis classic textbook is an introduction to the systematics and the use of stable isotopes in geosciences. It is subdivided into three parts: i) theoretical and experimental principles, ii) fractionation processes of light and heavy elements, iii) the natural variations of geologically important reservoirs. Since the publication of the previous edition improvements in multi-collector ICP mass-spectrometry have increased the ability to measure isotope ratios with very high precision for many elements of the periodic table. The amount of published data has increased tremendously in the last years; thus, conclusions based on a limited database are now better constrained. In this new edition, therefore, 47 elements with resolvable natural variations in isotope composition are discussed. This increase of elements, together with advances in the calculation of equilibrium isotope fractionation using ab initio methods, has led to an unbelievable rise of publications, making substantial major revisions and extensions of the last edition necessary. Many new references have been added, which enable quick access to recent literature.
Incorporation and Preservation of Molybdenum and Uranium Isotope Variations in Modern Marine Sediments
Author: Stephen J. Romaniello
Publisher:
Published: 2012
Total Pages: 143
ISBN-13:
DOWNLOAD EBOOKMolybdenum and uranium isotope variations are potentially powerful tools for reconstructing the paleoredox history of seawater. Reliable application and interpretation of these proxies requires not only detailed knowledge about the fractionation factors that control the distribution of molybdenum and uranium isotopes in the marine system, but also a thorough understanding of the diagenetic processes that may affect molybdenum and uranium isotopes entering the rock record. Using samples from the Black Sea water column, the first water column profile of 238U/235U variations from a modern euxinic basin has been measured. This profile allows the direct determination of the 238U/235U fractionation factor in a euxinic marine setting. More importantly however, these data demonstrate the extent of Rayleigh fractionation of U isotopes that can occur in euxinic restricted basins. Because of this effect, the offset of 238U/235U between global average seawater and coeval black shales deposited in restricted basins is expected to depend on the degree of local uranium drawdown from the water column, potentially complicating the interpretation 238U/235U paleorecords. As an alternative to the black shales typically used for paleoredox reconstructions, molybdenum and uranium isotope variations in bulk carbonate sediments from the Bahamas are examined. The focus of this work was to determine what processes, if any, fractionate molybdenum and uranium isotopes during incorporation into bulk carbonate sediments and their subsequent diagenesis. The results demonstrate that authigenic accumulation of molybdenum and uranium from anoxic and sulfidic pore waters is a dominant process controlling the concentration and isotopic composition of these sediments during early diagenesis. Examination of ODP drill core samples from the Bahamas reveals similar behavior for sediments during the first ~780ka of burial, but provides important examples where isolated cores and samples occasionally demonstrate additional fractionation, the cause of which remains poorly understood.
Sulfidic Sediments and Sedimentary Rocks
Author: David Rickard
Publisher: Newnes
Published: 2012-12-31
Total Pages: 813
ISBN-13: 0080931839
DOWNLOAD EBOOKThis book deals with sedimentary sulfides which are the most abundant authigenic minerals in sediments. Special emphasis is given to the biogeochemistry that plays such a central role in the formation of sedimentary sulfides. It will be of interest to scientists in a number of disciplines, including geology, microbiology, chemistry and environmental science. The sulfur system is important to environmental scientists considering the present and future effects of pollution and anoxia. The development of the sulfur system – particularly the characteristics of ocean anoxia over the last 200 Ma – is useful in predicting the future fate of the Earth surface system as well as in understanding the past. The biochemistry and microbiology of the sulfur system are key to understanding microbial ecology and the evolution of life. First monograph on sedimentary sulfides, covering the ancient and modern sedimentary sulfide systems Comprehensive, integrating chemistry, microbiology, geology and environmental science All key references are included and discussed
Isotope Geochemistry
Author: William M. White
Publisher: John Wiley & Sons
Published: 2015-01-27
Total Pages: 502
ISBN-13: 0470656700
DOWNLOAD EBOOKThis book provides a comprehensive introduction to radiogenic and stable isotope geochemistry. Beginning with a brief overview of nuclear physics and nuclear origins, it then reviews radioactive decay schemes and their use in geochronology. A following chapter covers the closely related techniques such as fission-track and carbon-14 dating. Subsequent chapters cover nucleosynthetic anomalies in meteorites and early solar system chronology and the use of radiogenic isotopes in understanding the evolution of the Earth’s mantle, crust, and oceans. Attention then turns to stable isotopes and after reviewing the basic principles involved, the book explores their use in topics as diverse as mantle evolution, archeology and paleontology, ore formation, and, particularly, paleoclimatology. A following chapter explores recent developments including unconventional stable isotopes, mass-independent fractionation, and isotopic ‘clumping’. The final chapter reviews the isotopic variation in the noble gases, which result from both radioactive decay and chemical fractionations.
Non-Traditional Stable Isotopes
Author: Fang-Zhen Teng
Publisher: Walter de Gruyter GmbH & Co KG
Published: 2017-03-06
Total Pages: 902
ISBN-13: 3110545632
DOWNLOAD EBOOKThe development of multi-collector inductively coupled plasma mass spectrometry (MC-ICPMS) makes it possible to precisely measure non-traditional stable isotopes. This volume reviews the current status of non-traditional isotope geochemistry from analytical, theoretical, and experimental approaches to analysis of natural samples. In particular, important applications to cosmochemistry, high-temperature geochemistry, low-temperature geochemistry, and geobiology are discussed. This volume provides the most comprehensive review on non-traditional isotope geochemistry for students and researchers who are interested in both the theory and applications of non-traditional stable isotope geochemistry.
Molybdenum as a Paleoredox Proxy
Author: Stephan R. Hlohowskyj
Publisher: Cambridge University Press
Published: 2021-09-09
Total Pages: 57
ISBN-13: 1009002260
DOWNLOAD EBOOKMolybdenum (Mo) is a widely used trace metal for investigating redox conditions. However, unanswered questions remain that concentration and bulk isotopic analysis cannot specially answer. Improvements can be made by combining new geochemical techniques to traditional methods of Mo analysis. In this Element, we propose a refinement of Mo geochemistry within aquatic systems, ancient rocks, and modern sediments through molecular geochemistry (systematically combining concentration, isotope ratio, elemental mapping, and speciation analyses). Specifically, to intermediate sulfide concentrations governing Mo behavior below the 'switch-point' and dominant sequestration pathways in low oxygen conditions. The aim of this work is to 1) aid and improve the breadth of Mo paleoproxy interpretations by considering Mo speciation and 2) address outstanding research gaps concerning Mo systematics (cycling, partitioning, sequestration, etc.). The Mo paleoproxy has potential to solve ever complex research questions. By using molecular geochemical recommendations, improved Mo paleoproxy interpretations and reconstruction can be achieved.
Large Igneous Provinces
Author: Richard E. Ernst
Publisher: Cambridge University Press
Published: 2014-09-25
Total Pages: 667
ISBN-13: 1316060519
DOWNLOAD EBOOKLarge igneous provinces (LIPs) are intraplate magmatic events, involving volumes of mainly mafic magma upwards of 100,000 km3, and often above 1 million km3. They are linked to continental break-up, global environmental catastrophes, regional uplift and a variety of ore deposit types. In this up-to-date, fascinating book, leading expert Richard E. Ernst explores all aspects of LIPs, beginning by introducing their definition and essential characteristics. Topics covered include continental and oceanic LIPs; their origins, structures, and geochemistry; geological and environmental effects; association with silicic, carbonatite and kimberlite magmatism; and analogues of LIPs in the Archean, and on other planets. The book concludes with an assessment of LIPs' influence on natural resources such as mineral deposits, petroleum and aquifers. This is a one-stop resource for researchers and graduate students in a wide range of disciplines, including tectonics, igneous petrology, geochemistry, geophysics, Earth history, and planetary geology, and for mining industry professionals.
Carbon Isotope Stratigraphy
Author: Michael Montenari
Publisher: Academic Press
Published: 2020-10-30
Total Pages: 780
ISBN-13: 0128209925
DOWNLOAD EBOOKCarbon Isotope Stratigraphy, Volume Five in the Advances in Sequence Stratigraphy series, covers research in stratigraphic disciplines, including the most recent developments in the geosciences. This fully commissioned review publication aims to foster and convey progress in stratigraphy with its inclusion of a variety of topics, including Carbon isotope stratigraphy - principles and applications, Interpreting Phanerozoic d13C patterns as periodic glacio-eustatic sequences, Stable carbon isotopes in archaeological plant remains, Review of the Upper Ediacaran-Lower Cambrian Detrital Series in Central and North Iberia: NE Africa as possible Source Area, Calibrating d13C and d18O chemostratigraphic correlations across Cambrian strata of SW, and much more. Contains contributions from leading authorities in the field Informs and updates on all the latest developments in the field Aims to foster and convey progress in stratigraphy, including geochronology, magnetostratigraphy, lithostratigraphy, event-stratigraphy, and more
