Heterocyclic Derivatives of Phosphorous, Arsenic, Antimony and Bismuth, Volume 1
Heterocyclic Derivatives of Phosphorous, Arsenic, Antimony and Bismuth, Volume 1

Author: Frederick G. Mann

Publisher: John Wiley & Sons

Published: 2009-09-15

Total Pages: 743

ISBN-13: 0470188006

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The Chemistry of Heterocyclic Compounds, since its inception, has been recognized as a cornerstone of heterocyclic chemistry. Each volume attempts to discuss all aspects – properties, synthesis, reactions, physiological and industrial significance – of a specific ring system. To keep the series up-to-date, supplementary volumes covering the recent literature on each individual ring system have been published. Many ring systems (such as pyridines and oxazoles) are treated in distinct books, each consisting of separate volumes or parts dealing with different individual topics. With all authors are recognized authorities, the Chemistry of Heterocyclic Chemistry is considered worldwide as the indispensable resource for organic, bioorganic, and medicinal chemists.

The Chemistry of Arsenic, Antimony and Bismuth
The Chemistry of Arsenic, Antimony and Bismuth

Author: J. D. Smith

Publisher: Elsevier

Published: 2016-06-06

Total Pages: 155

ISBN-13: 1483140067

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Pergamon Texts in Inorganic Chemistry, Volume 2: The Chemistry of Arsenic, Antimony and Bismuth focuses on the physical and chemical properties of arsenic, antimony, and bismuth. This book discusses the alloys and intermetallic compounds; general aspects of the chemistry of arsenic; salts of antimony and bismuth; and organometallic compounds. The complexes of Arsenic(V), Antimony(V), and Bismuth(V), and mixed valency compounds and mechanisms of redox reactions are also elaborated. This text describes the chemical and physical properties of compounds, such as hydrides EH3, halides EX3, oxides E2O3, halides EX5, sulfides E2S5, oxides E2O5, and related oxyacids. This publication is intended for chemical engineering students and chemists researching on the characteristics of arsenic, antimony, and bismuth.

Topics in Stereochemistry
Topics in Stereochemistry

Author: Norman L. Allinger

Publisher: John Wiley & Sons

Published: 2009-09-17

Total Pages: 358

ISBN-13: 0470147423

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This seminal series, first edited by Ernest Eliel, responsible for some of the major advances in stereochemistry and the winner of the ACS Priestley Medal in 1996, provides coverage of the major developments of the field of stereochemistry. The scope of this series is broadly defined to encompass all fields of chemical and biological sciences that are founded on molecular and supramolecular interactions. Insofar as chemical, physical, and biological properties are determined by molecular shape and structure, the importance of stereochemistry is fundamental to and consequential for all natural sciences. Topics in Stereochemistry serves as a multidisciplinary series that enriches all of chemistry. Aimed at advanced students, university professors and teachers as well as researchers in pharmaceutical, agricultural, biotechnological, polymer, materials, and fine chemical industries, Topics in Stereochemistry publishes definitive and scholarly reviews in stereochemistry and has long been recognized as the gold standard reference work in this field. Covering the effect of chirality on all aspects of molecular interaction from the fundamental physical chemical properties of molecules and their molecular physics to the application of chirality in new areas such as its applications in materials science, Topics in Stereochemistry explores a wide variety of properties, both physical and chemical of isomers with a view to their applications in a number of disciplines from biochemistry to materials science.

Organometallic Compounds
Organometallic Compounds

Author: B. J. Aylett

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 532

ISBN-13: 9400957297

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A very large number of organo derivatives is formed by the Group IV ele ments silicon, germanium, tin, and lead. In comparing the general properties of these elements, Table 1. 1 shows that the first ionization energies decrease (though not in a regular way) with increase in size and atomic number, con sistent with the general increase in metallic character of the elements. Electro negativity values (which have been the subject of considerable controversy) show no clear trend. Although purely inorganic compounds of tin(n) and leaden) are well known, almost all organo Group IV derivatives show an oxidation state of IV. Bonds to carbon become weaker on passing from silicon to lead, as do the element-element bonds themselves. With any particular element M (M = Si, Ge, Sn, or Pb), there is a small decrease in bond energy in the order: M-Ph > M - Me > M - Et. Although accurate data for organo derivatives are lacking, strengths of bonds to other elements probably decrease in the order: M-F> M-O > M-CI > M-H ~ M-N ~ M-S ~ M-Br > M-I, while for a particular element X, the order is: Si-X > Ge-X > Sn-X > Pb-X. It is therefore understandable that reactions leading to Si-F, Si-O, or Si-CI bonds are especially favoured in a thermodynamic sense.

Organometallic Syntheses
Organometallic Syntheses

Author: R. Bruce King

Publisher: Elsevier

Published: 2013-10-22

Total Pages: 686

ISBN-13: 1483289931

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Organometallic Syntheses, Volume 3 focuses on the synthesis of compounds containing carbon-metal bonds, including ligands, compounds, chlorides, and derivatives. The selection first elaborates on bis(cyclopentadienyl) organolanthanide and organoyttrium chloride, methyl, and hydride complexes and base stabilized alkali metal halide adducts of bis (pentamethylcyclopentadienyl) lanthanide chlorides. The text then examines cyclopentadienyl metal carbonyl and nitrosyl derivatives, ferrocenylamine, cobalticinium and rhodicinium salts, and alkyl transition metal derivatives. The publication takes a look at transition metal complexes containing organophosphorus ligands, transition metal derivatives containing chalcogen ligands, and coinage metal derivatives. The text also reviews transition metal organometallic compounds, including compounds of group IA, IIA, IIB, and IVA. The selection is a vital reference for researchers interested in the synthesis of compounds containing carbon-metal bonds.

A Guide to Organophosphorus Chemistry
A Guide to Organophosphorus Chemistry

Author: Louis D. Quin

Publisher: John Wiley & Sons

Published: 2000-02-04

Total Pages: 416

ISBN-13: 9780471318248

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Die organische Chemie des Phosphors - ein großes, äußerst lebendiges Forschungsfeld - umfaßt sowohl Verbindungen mit Kohlenstoff-Phosphor-Bindungen als auch organische Ester anorganischer Phosphorsäuren. Dieser Band behandelt die meisten phosphorhaltigen funktionellen Gruppen und daneben aktuelle Fragen wie z.B. ungewöhnliche Koordinationszustände, Heterocyclen, Anwendungen der 31P-NMR und andere spektroskopische Verfahren. Soweit bekannt, werden auch elektronische Reaktionsmechanismen und reaktive Intermediate diskutiert. Mit zahlreichen Literaturhinweisen! (03/00)