Synthesis of Chiral Rare Earth and Alkaline Earth Compounds

Synthesis of Chiral Rare Earth and Alkaline Earth Compounds

Author: Meng He

Publisher: Cuvillier Verlag

Published: 2016-08-16

Total Pages: 134

ISBN-13: 3736983301

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The first chiral amidinate borohydride rare earth compounds and compounds based on (S)-HPEBA ((S,S)-N,N-bis-(1-phenylethyl)benzamidine) ligand were reported by Roesky et al. To continuing this work, the new chiral ligand (S)-HNEBA ((S,S)-N,N-bis-(1-naphthylethyl)benzamidine) were synthesized. The corresponding amidinate metal complexes were successfully obtained by amine elimination. The luminescent and magnetic properties of rare earth compounds were studied. Alkaline earth metal compounds have been extensively studied as catalysts in synthetic chemistry. However, chiral amidinate alkaline earth metal complexes have never been reported. Chiral amidinate ligand (S)-HPEBA was introduced into the coordination chemistry of the alkaline earth metal as well as divalent lanthanides, their catalytic activities in hydrophosphination have been investigated. The Ba compound showed high catalytic activities in the hydrophosphination reaction. Moreover, since rare earth metal COT complexes exhibit excellent SMM behavior, it is of great interest to study the magnetic behavior of COT amidinate complexes. Thus, amidine ligand (S)-HPEBA and (S)-HPETA are introduced into the corresponding COT amidinate complexes for magnetic properties studies. The Er Compound exhibited typical field-induced SMM behavior. Furthermore, inspired by the promising application of lanthanide SMMs and the research of SMMs based on sandwich type lanthanide complexes, a series of novel sandwich type complexes comprising of Pc and COT ligand were designed and synthesized.


Alkaline-Earth Metal Compounds

Alkaline-Earth Metal Compounds

Author: Sjoerd Harder

Publisher: Springer

Published: 2013-07-20

Total Pages: 282

ISBN-13: 3642362702

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The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.


Reactivity of Low-Valent Group 14 Species Toward Main Group Element, Transition Metal and Lanthanide Compounds

Reactivity of Low-Valent Group 14 Species Toward Main Group Element, Transition Metal and Lanthanide Compounds

Author: Xiaofei Sun

Publisher: Cuvillier Verlag

Published: 2022-08-22

Total Pages: 259

ISBN-13: 3736966628

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Die Dissertation befasst sich mit der Anwendung von niedervalenten Gruppe-14-Verbindungen in metallorganischer Chemie und Hauptgruppenchemie. Ausgehend von mono- und divalenten Siliziumverbindungen wurde die analoge Siliziumverbindung des 2π-Hückel-aromatischen Verbindung dargestellt (Kapitel 3.1). Ein chirales Silen wurde synthetisiert und weitere Reaktivität mit unterschiedlichen kleinen Molekülen untersucht (Kapitel 3.2). Außerdem wurden bidentate Silylene als Liganden zur Stabilisierung von Seldenerdelementen, Erdalkalielementen und Gruppe-12-Metallen eingesetzt (Kapitel 3.3-3.4). Verschiedene Polyphosphide wurden aus reduzierenden Silylenen oder Plumbolen generiert (Kapitel 3.5-3.6). Die dianionischen Gruppe-14-Metallole, Silol, Germol und Plumbol wurden als Liganden für sandwichartige Lanthanidkomplexe eingesetzt und die magnetischen Eigenschaften der Er-Verbindung wurden untersucht (Kapitel 3.7-3.8).


Catalytic Amination for N-Alkyl Amine Synthesis

Catalytic Amination for N-Alkyl Amine Synthesis

Author: Feng Shi

Publisher: Academic Press

Published: 2018-03-14

Total Pages: 208

ISBN-13: 0128122854

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Catalytic Amination for N-Alkyl Amine Synthesis provides a useful survey of this key type of reaction for chemistry researchers in academia and industry. Beginning with an introduction to amination and the development of the field, the book focuses on useful and high potential methods, such as the catalytic amination of alcohol with homogeneous and heterogeneous catalysts, the coupling reaction of olefin and amine, and the reductive amination of carbon dioxide with different reducing agents. The work also discusses two key examples of one-pot synthesis, the oxidative amination of alkane and amine and synthesis of N-alkyl amine with nitrobenzene and nitrile as starting materials. Valuable for chemists, materials scientists, chemical engineers and others, the book offers a unique overview of this growing area and its future possibilities. - Describes the catalytic amination of alcohol with homogeneous and heterogeneous catalysts - Discusses the one-pot oxidative amination of alkane and amine - Explores the application of ammonia as the N-source in amination reaction to avoid primary or secondary amine synthesis


The Rare Earth Elements

The Rare Earth Elements

Author: David A. Atwood

Publisher: John Wiley & Sons

Published: 2013-02-19

Total Pages: 994

ISBN-13: 111863263X

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Lanthanides are of great importance for the electronic industries, this new book (from the EIBC Book Series) provides a comprehensive coverage of the basic chemistry, particularly inorganic chemistry, of the lanthanoid elements, those having a 4f shell of electrons. A chapter is describing the similarity of the Group 3 elements, Sc, Y, La, the group from which the lanthanoids originate and the group 13 elements, particularly aluminum, having similar properties. Inclusion of the group 3 and 13 elements demonstrates how the lanthanoid elements relate to other, more common, elements in the Periodic Table. Beginning chapters describe the occurrence and mineralogy of the elements, with a focus on structural features observed in compounds described in later chapters. The majority of the chapters is organized by the oxidation state of the elements, Ln(0), Ln(II), Ln(III), and Ln(IV). Within this organization the chapters are further distinguished by type of compound, inorganic (oxides and hydroxides, aqueous speciation, halides, alkoxides, amides and thiolates, and chelates) and organometallic. Concluding chapters deal with diverse and critically important applications of the lanthanoids in electronic and magnetic materials, and medical imaging.