This textbook concerns thermal properties of bulk matter and is aimed at advanced undergraduate or first-year graduate students in a range of programs in science or engineering. It provides an intermediate level presentation of statistical thermodynamics for students in the physical sciences (chemistry, nanosciences, physics) or related areas of applied science/engineering (chemical engineering, materials science, nanotechnology engineering), as they are areas in which statistical mechanical concepts play important roles. The book enables students to utilize microscopic concepts to achieve a better understanding of macroscopic phenomena and to be able to apply these concepts to the types of sub-macroscopic systems encountered in areas of nanoscience and nanotechnology.
This textbook facilitates students’ ability to apply fundamental principles and concepts in classical thermodynamics to solve challenging problems relevant to industry and everyday life. It also introduces the reader to the fundamentals of statistical mechanics, including understanding how the microscopic properties of atoms and molecules, and their associated intermolecular interactions, can be accounted for to calculate various average properties of macroscopic systems. The author emphasizes application of the fundamental principles outlined above to the calculation of a variety of thermodynamic properties, to the estimation of conversion efficiencies for work production by heat interactions, and to the solution of practical thermodynamic problems related to the behavior of non-ideal pure fluids and fluid mixtures, including phase equilibria and chemical reaction equilibria. The book contains detailed solutions to many challenging sample problems in classical thermodynamics and statistical mechanics that will help the reader crystallize the material taught. Class-tested and perfected over 30 years of use by nine-time Best Teaching Award recipient Professor Daniel Blankschtein of the Department of Chemical Engineering at MIT, the book is ideal for students of Chemical and Mechanical Engineering, Chemistry, and Materials Science, who will benefit greatly from in-depth discussions and pedagogical explanations of key concepts. Distills critical concepts, methods, and applications from leading full-length textbooks, along with the author’s own deep understanding of the material taught, into a concise yet rigorous graduate and advanced undergraduate text; Enriches the standard curriculum with succinct, problem-based learning strategies derived from the content of 50 lectures given over the years in the Department of Chemical Engineering at MIT; Reinforces concepts covered with detailed solutions to illuminating and challenging homework problems.
This 2006 textbook discusses the fundamentals and applications of statistical thermodynamics for beginning graduate students in the physical and engineering sciences. Building on the prototypical Maxwell–Boltzmann method and maintaining a step-by-step development of the subject, this book assumes the reader has no previous exposure to statistics, quantum mechanics or spectroscopy. The book begins with the essentials of statistical thermodynamics, pauses to recover needed knowledge from quantum mechanics and spectroscopy, and then moves on to applications involving ideal gases, the solid state and radiation. A full introduction to kinetic theory is provided, including its applications to transport phenomena and chemical kinetics. A highlight of the textbook is its discussion of modern applications, such as laser-based diagnostics. The book concludes with a thorough presentation of the ensemble method, featuring its use for real gases. Numerous examples and prompted homework problems enrich the text.
The book is devoted to the study of the correlation effects in many-particle systems. It presents the advanced methods of quantum statistical mechanics (equilibrium and nonequilibrium), and shows their effectiveness and operational ability in applications to problems of quantum solid-state theory, quantum theory of magnetism and the kinetic theory. The book includes description of the fundamental concepts and techniques of analysis following the approach of N N Bogoliubov's school, including recent developments. It provides an overview that introduces the main notions of quantum many-particle physics with the emphasis on concepts and models.This book combines the features of textbook and research monograph. For many topics the aim is to start from the beginning and to guide the reader to the threshold of advanced researches. Many chapters include also additional information and discuss many complex research areas which are not often discussed in other places. The book is useful for established researchers to organize and present the advanced material disseminated in the literature. The book contains also an extensive bibliography.The book serves undergraduate, graduate and postgraduate students, as well as researchers who have had prior experience with the subject matter at a more elementary level or have used other many-particle techniques.
"The book will undoubtedly resume its place as a constant guide and reference for chemists using thermodynamics in their research, and as a textbook and reference for classes in the application of thermodynamics to chemistry." -- The Journal of Chemical Education Since its first publication in 1923, this volume has been considered one of the great books in the literature of chemistry. In the early 60s, two well-known chemists revised and updated it, adding substantial material on solution thermodynamics, results in statistical mechanics, surfaces, gravitational and electromagnetic fields, and other areas. The republication of this foundational work will be welcomed by teachers in the field.
The principal message of this book is that thermodynamics and statistical mechanics will benefit from replacing the unfortunate, misleading and mysterious term “entropy” with a more familiar, meaningful and appropriate term such as information, missing information or uncertainty. This replacement would facilitate the interpretation of the “driving force” of many processes in terms of informational changes and dispel the mystery that has always enshrouded entropy.It has been 140 years since Clausius coined the term “entropy”; almost 50 years since Shannon developed the mathematical theory of “information” — subsequently renamed “entropy”. In this book, the author advocates replacing “entropy” by “information”, a term that has become widely used in many branches of science.The author also takes a new and bold approach to thermodynamics and statistical mechanics. Information is used not only as a tool for predicting distributions but as the fundamental cornerstone concept of thermodynamics, held until now by the term “entropy”.The topics covered include the fundamentals of probability and information theory; the general concept of information as well as the particular concept of information as applied in thermodynamics; the re-derivation of the Sackur-Tetrode equation for the entropy of an ideal gas from purely informational arguments; the fundamental formalism of statistical mechanics; and many examples of simple processes the “driving force” for which is analyzed in terms of information.
This text describes how plastics, rubber, and fibers are synthesized, processed into useful materials, characterized, and compounded with fillers and other additives to improve performance for specific applications. Their use in a wide variety of technologies including membrane separations, electronics, and energy production and storage is described. A new chapter in the Third Edition shows how computer correlations and simulations can be used to predict properties of new plastics and to better understand how existing plastics perform.
This text presents statistical mechanics and thermodynamics as a theoretically integrated field of study. It stresses deep coverage of fundamentals, providing a natural foundation for advanced topics. The large problem sets (with solutions for teachers) include many computational problems to advance student understanding.
This unique two-volume set presents the subjects of stochastic processes, information theory, and Lie groups in a unified setting, thereby building bridges between fields that are rarely studied by the same people. Unlike the many excellent formal treatments available for each of these subjects individually, the emphasis in both of these volumes is on the use of stochastic, geometric, and group-theoretic concepts in the modeling of physical phenomena. Stochastic Models, Information Theory, and Lie Groups will be of interest to advanced undergraduate and graduate students, researchers, and practitioners working in applied mathematics, the physical sciences, and engineering. Extensive exercises, motivating examples, and real-world applications make the work suitable as a textbook for use in courses that emphasize applied stochastic processes or differential geometry.
Statistical mechanics: the bane of many a physics student, and traditionally viewed as a long parade of ensembles, partition functions, and partial derivatives. But the subject needn't be arcane. When pared back to its underlying concepts and built from the ground up, statistical mechanics takes on a charm of its own, and sheds light on all manner of physical phenomena. This book presents a straightforward introduction to the key concepts in statistical mechanics, following the popular style of the author's highly successful textbook "Explorations in Mathematical Physics". Offering a clear, conceptual approach to the subject matter, the book presents a treatment that is mathematically complete, while remaining very accessible to undergraduates. It commences by asking: why does an ink drop spread out in a bathtub of water? This showcases the importance of counting configurations, which leads naturally to ideas of microstates, energy, entropy, thermodynamics, and physical chemistry. With this foundation, the Boltzmann distribution writes itself in its fullest form, and this opens the door to the Maxwell distribution and related areas of thermal conductivity and viscosity. Quantum ideas then appear: bosons via Einstein's and Debye's theories of heat capacity, and fermions via electrical conduction and low-temperature heat capacity of metals. The text ends with a detailed derivation of blackbody radiation, and uses this to discuss the greenhouse effect, lasers, and cosmology. Suitable for use with core undergraduate courses in statistical mechanics and thermodynamics, this book concentrates on using solid mathematics, while avoiding cumbersome notation. All the necessary mathematical steps are included in the body of the text and in the worked examples. Reviews of Explorations in Mathematical Physics by Don Koks, 2006 "With enjoyable and sometimes surprising excursions along the way, the journey provides a fresh look at many familiar topics, as it takes us from basic linear mathematics to general relativity... look forward to having your geometric intuition nourished and expanded by the author's intelligent commentaries." (Eugen Merzbacher, University of North Carolina) "... an interesting supplement to standard texts for teaching mathematical methods in physics, as it will add alternative views that could serve as additional material." (S. Marcelja, Australian Journal of Physics) "... a tour through the main ideas forming the language of modern mathematical physics ...it is a difficult task for the author to decide what is a good balance between the topics and their presentation, but in this case it has been achieved. ...for those physicists who would like to be exposed to clear motivation and careful explanation of the basics of the present-day apparatus of mathematical physics." (Ivailo Mladenov, Mathematical Reviews).
