Characterization of Solutes in Nonaqueous Solvents
Characterization of Solutes in Nonaqueous Solvents

Author: Mamantov

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 322

ISBN-13: 1461339820

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This book consists of contributions by participants in the Symposium "Spectroscopic and Electrochemical Characterizat.ion of Solute Species in Non~Aqueous Solvents" which took place at the American Chemical Society Meeting, Division of Analytical Chemistry, August 31 and September I, 1976, San Francisco, California. The manuscripts were submitted to the editor during the first half of 1977 and, in most cases, represent reviews of selected research topics in the broad area of characterization of solute species in non~aqueous solvents. In organizing this Symposium, I attempted to bring together a significantly large group of research workers involved in spectro scopic and electrochemical studies in the three large classes of non-aqueous solvents ~ organic solvents, covalent inorganic sol vents and molten salts. The experimental apprcaches and problems, such as avoidance of traces of moisture and oxygen, are frequently similar for all types of non-aqueous solvents. It is hoped that this volume will be useful to all concerned with chemistry in non-aqueous solvents. Gleb l>lamantov , Contents 1. IDENTIFICATION AND SYSTEMIZATION OF SOLVENT PROPERTIES INVOLVED IN THE LIGAND SUBSTITUTION KINETICS OF LABILE COMPLEXES OF NICKEL(II) J. F. Coetzee, D. Frollini, C. G. Karakatsanis, E. J.

Solvation, Ionic and Complex Formation Reactions in Non-Aqeuous Solvents
Solvation, Ionic and Complex Formation Reactions in Non-Aqeuous Solvents

Author: K. Burger

Publisher: Elsevier

Published: 2012-12-02

Total Pages: 269

ISBN-13: 0444597514

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Solvation, Ionic and Complex Formation Reactions in Non-Aqueous Solvents: Experimental Methods for their Investigation presents the available methods and their particular value in investigating solutions composed of non-aqueous solvents. This book is composed of 10 chapters and begins with a brief description of the complexity of the interactions possible n solutions. The subsequent chapters deal with a classification of the solvents and empirical solvent strength scales based on various experimental parameters, together with various correlations empirically describing the solvent effect. Other chapters present the methods for the purification of solvents and ways of checking their purity, as well as the individual results achieved during investigations of the solvent effect, particularly the general regularities recognized. The remaining chapters provide a review of the coordination chemistry of non-aqueous solutions. This book will prove useful to analytical and inorganic chemists.

Solvent-Solute Interactions: A Spectroscopic Study
Solvent-Solute Interactions: A Spectroscopic Study

Author: Thomas R. Stengle

Publisher:

Published: 1971

Total Pages: 22

ISBN-13:

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The primary object of the research was the elucidation of the solvation of halide ions in mixtures of water with dipolar aprotic solvents. Preliminary results on chloride ion had indicated that there was no preferential solvation of the ion DMSO-H2O mixtures, however, the contact solvation shell of the ion did contain an excess concentration of water in CH3CN-H2) mixtures. The presence of excess solvating water in the CH3CN-H2O system was found to be due to the large activity coefficient of water in that solvent mixture. The reasons for the lack of an intrinsic preference of the halide ion for water have been explored. (Author).

The Chemical Physics of Solvation
The Chemical Physics of Solvation

Author: Revaz R. Dogonadze

Publisher: Elsevier Science & Technology

Published: 1985

Total Pages: 834

ISBN-13:

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The importance of solvation as a concept which covers quite generally the interactions between a molecular solute particle and a macroscopic body of surrounding solvent is well recognized. Solvation plays a major role in the distribution of elements in the geo- and hydrosphere, and most chemical and biological processes involve solvated reactants and products, the electronic and molecular structure of which are strongly determined by solvation. This three-volume monograph has been written collectively by 50 authors from 14 countries who are specialists in different areas of solvation science. Part A deals with the theory of solvation; Part B is entirely devoted to spectroscopy of solvation; and Part C covers solvation phenomena in specific physical, chemical and biological systems. The volumes will be an invaluable reference source for physicists, physical chemists and biophysicists undertaking investigations into the diversified and fascinating areas of the physics and chemical physics of solvation at postgraduate and professional research levels.