Characterization of Solutes in Nonaqueous Solvents
Characterization of Solutes in Nonaqueous Solvents

Author: Mamantov

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 322

ISBN-13: 1461339820

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This book consists of contributions by participants in the Symposium "Spectroscopic and Electrochemical Characterizat.ion of Solute Species in Non~Aqueous Solvents" which took place at the American Chemical Society Meeting, Division of Analytical Chemistry, August 31 and September I, 1976, San Francisco, California. The manuscripts were submitted to the editor during the first half of 1977 and, in most cases, represent reviews of selected research topics in the broad area of characterization of solute species in non~aqueous solvents. In organizing this Symposium, I attempted to bring together a significantly large group of research workers involved in spectro scopic and electrochemical studies in the three large classes of non-aqueous solvents ~ organic solvents, covalent inorganic sol vents and molten salts. The experimental apprcaches and problems, such as avoidance of traces of moisture and oxygen, are frequently similar for all types of non-aqueous solvents. It is hoped that this volume will be useful to all concerned with chemistry in non-aqueous solvents. Gleb l>lamantov , Contents 1. IDENTIFICATION AND SYSTEMIZATION OF SOLVENT PROPERTIES INVOLVED IN THE LIGAND SUBSTITUTION KINETICS OF LABILE COMPLEXES OF NICKEL(II) J. F. Coetzee, D. Frollini, C. G. Karakatsanis, E. J.

Non-Aqueous Solutions – 5
Non-Aqueous Solutions – 5

Author: J. B. Gill

Publisher: Elsevier

Published: 2013-10-22

Total Pages: 131

ISBN-13: 1483155714

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Non-Aqueous Solutions — 5 is a collection of lectures presented at the Fifth International Conference on Non-Aqueous Solutions held in Leeds, England, on July 5-9, 1976. The papers explore reactions in non-aqueous solutions as well as the thermodynamic and kinetic properties of non-aqueous solutions. Examples of the use of spectroscopic techniques are presented, and solutions in molten salts are given. Metals in solution and liquid metal solutions are also considered. This book is comprised of 12 chapters and begins with a review of a general scheme which considers the species formed by cation-electron and electron-electron interactions at dilute to moderate concentrations, along with the influence of the solvent and the metal on these interactions. The discussion then shifts to the application of electron spin resonance spectroscopy to the study of solvation; the influence of solvent properties on ligand substitution mechanisms of labile complexes; and the effect of acidity on chemical reactions in molten salts. Subsequent chapters deal with the chemistry of solutions of salts in liquid alkali metals; preferential solvation in kinetics; and the use of non-aqueous solvents for preparation and reactions of nitrogen halogen compounds. Results of Raman spectroscopic studies of non-aqueous solutions and spectroscopic studies of coordination compounds formed in molten salts are also presented. This monograph will be of interest to chemists.

Spectroscopic Properties of Inorganic and Organometallic Compounds Volume 12
Spectroscopic Properties of Inorganic and Organometallic Compounds Volume 12

Author: David Michael Adams

Publisher: Royal Society of Chemistry

Published: 1980

Total Pages: 424

ISBN-13: 0851869203

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Annotation. Spectroscopic Properties of Inorganic and Organometallic Compounds provides a unique source of information on an important area of chemistry. Divided into sections mainly according to the particular spectroscopic technique used, coverage in each volume includes: NMR (with reference to stereochemistry, dynamic systems, paramagnetic complexes, solid state NMR and Groups 13-18); nuclear quadrupole resonance spectroscopy; vibrational spectroscopy of main group and transition element compounds and coordinated ligands; and electron diffraction. Reflecting the growing volume of published work in this field, researchers will find this Specialist Periodical Report an invaluable source of information on current methods and applications. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading experts in their specialist fields, this series is designed to help the chemistry community keep current with the latest developments in their field. Each volume in the series is published either annually or biennially and is a superb reference point for researchers. www.rsc.org/spr

The Chemistry of Nonaqueous Solvents VB
The Chemistry of Nonaqueous Solvents VB

Author: J.J. Lagowski

Publisher: Elsevier

Published: 2012-12-02

Total Pages: 379

ISBN-13: 0323153321

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The Chemistry of Nonaqueous Solvents, Volume V: Acidic and Aprotic Solvents, Part B covers the theoretical aspects of individual solvents in nonaqueous solution chemistry. This volume is divided into five chapters. The first two chapters discuss the purification, structure, physical properties, electrochemistry, solubilities, and reactions of specific solvents, including trifluoroacetic and halosulfuric acids. Chapter 3 deals briefly with the preparations and properties of the interhalogens, principally in the liquid state. This chapter emphasizes their uses as nonaqueous solvents, especially through extensive study of their acid-base reactions. Spectroscopic data and their contribution to the understanding of their solution chemistries are also considered. Chapter 4 surveys the autoionization, purification methods, solubilities, solvolytic reactions, conductivity, conductometric, potentiometric, spectrophotometric, and visual titrations, as well as the isolation of solid complexes in inorganic halides and oxyhalides. Chapter 5 describes the solubility, reactivity, and spectroscopic data of molten salts. This book is of value to analytical chemists, and analytical chemistry teachers and students.