Polymer Dynamics and Relaxation
Polymer Dynamics and Relaxation

Author: Richard Boyd

Publisher: Cambridge University Press

Published: 2007-09-13

Total Pages: 369

ISBN-13: 1107320259

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Polymers exhibit a range of physical characteristics, from rubber-like elasticity to the glassy state. These particular properties are controlled at the molecular level by the mobility of the structural constituents. Remarkable changes in mobility can be witnessed with temperature, over narrow, well defined regions, termed relaxation processes. This is an important, unique phenomenon controlling polymer transition behaviour and is described here at an introductory level. The important types of relaxation processes from amorphous to crystalline polymers and polymeric miscible blends are covered, in conjunction with the broad spectrum of experimental methods used to study them. In-depth discussion of molecular level interpretation, including atomistic level computer simulations and applications to molecular mechanism elucidation, are discussed. The result is a self-contained approach to polymeric interpretation suitable for researchers in materials science, physics and chemistry interested in the relaxation processes of polymeric systems.

Mechanical Properties and Testing of Polymers
Mechanical Properties and Testing of Polymers

Author: G.M. Swallowe

Publisher: Springer Science & Business Media

Published: 2013-04-17

Total Pages: 313

ISBN-13: 9401592314

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This volume represents a continuation of the Polymer Science and Technology series edited by Dr. D. M. Brewis and Professor D. Briggs. The theme of the series is the production of a number of stand alone volumes on various areas of polymer science and technology. Each volume contains short articles by a variety of expert contributors outlining a particular topic and these articles are extensively cross referenced. References to related topics included in the volume are indicated by bold text in the articles, the bold text being the title of the relevant article. At the end of each article there is a list of bibliographic references where interested readers can obtain further detailed information on the subject of the article. This volume was produced at the invitation of Derek Brewis who asked me to edit a text which concentrated on the mechanical properties of polymers. There are already many excellent books on the mechanical properties of polymers, and a somewhat lesser number of volumes dealing with methods of carrying out mechanical tests on polymers. Some of these books are listed in Appendix 1. In this volume I have attempted to cover basic mechanical properties and test methods as well as the theory of polymer mechanical deformation and hope that the reader will find the approach useful.

Polymer Relaxation
Polymer Relaxation

Author: Peter Jason Graham

Publisher: Nova Science Pub Incorporated

Published: 2012

Total Pages: 182

ISBN-13: 9781614703815

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Stress relaxation describes how polymers relieve stress under constant strain. Because they are viscoelastic, polymers behave in a nonlinear, non-Hookean fashion. This book presents current research in the study of polymer relaxation, including the secondary relaxations in amorphous polymers; nuclear magnetic resonance relaxation approaches; electrochemical relaxation studies of polythiophenes and dielectric relaxation of onion-like carbon based polymer composites.

Relaxation Phenomena
Relaxation Phenomena

Author: Wolfgang Haase

Publisher: Springer Science & Business Media

Published: 2013-03-09

Total Pages: 732

ISBN-13: 3662097478

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The authors describe the electric, magnetic and other relaxational processes in a wide spectrum of materials: liquid crystals, molecular magnets, polymers, high-Tc superconductors and glasses. The book summarizes the phenomenological fundamentals and the experimental methods used. A detailed description of molecular and collective dynamics in the broad range of liquid crystals is presented. Magnetic systems, high-Tc superconductors, polymers and glasses are an important subject of matter. It is shown that the researchers working on relaxation processes in different fields of materials sciences are dealing with the same physical fundamentals, but are sometimes using slightly different terms. The book is addressed to scientists, engineers, graduate and undergraduate students, experimentalists and theorists in physics, chemistry, materials sciences and electronic engineering. Many internationally well known experts contribute to it.

Creep and Fatigue in Polymer Matrix Composites
Creep and Fatigue in Polymer Matrix Composites

Author: Rui Miranda Guedes

Publisher: Woodhead Publishing

Published: 2019-03-14

Total Pages: 590

ISBN-13: 0081026021

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Creep and Fatigue in Polymer Matrix Composites, Second Edition, updates the latest research in modeling and predicting creep and fatigue in polymer matrix composites. The first part of the book reviews the modeling of viscoelastic and viscoplastic behavior as a way of predicting performance and service life. Final sections discuss techniques for modeling creep rupture and failure and how to test and predict long-term creep and fatigue in polymer matrix composites. - Reviews the latest research in modeling and predicting creep and fatigue in polymer matrix composites - Puts a specific focus on viscoelastic and viscoplastic modeling - Features the time-temperature-age superposition principle for predicting long-term response - Examines the creep rupture and damage interaction, with a particular focus on time-dependent failure criteria for the lifetime prediction of polymer matrix composite structures that are illustrated using experimental cases

Disorder Effects on Relaxational Processes
Disorder Effects on Relaxational Processes

Author: Ranko Richert

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 745

ISBN-13: 364278576X

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The field of non-crystalline materials has seen the emergence of many challeng ing problems during its long history. In recent years, the interest in polymeric and biological disordered matter has stimulated new activities which in turn have enlarged the organic and inorganic glass community. The current research fields and recent progress have extended our knowledge of the rich phenomenol ogy of glassy systems, where the role of disorder is fundamental for the underlying microscopic dynamics. In addition, despite the lack of a unified theory, many interesting theoretical models have recently evolved. The present volume offers the reader a collection of topics representing the current state in the understanding of disorder effects as well as a survey of the basic problems and phenomena involved. The task of compiling a book devoted to disordered systems has benefited much from a seminar organized by the W.-E. Heraeus Foundation in Bad Honnef in April 1992, where we had the opportunity to discuss the project with most of the authors. Here we wish to thank the Heraeus Foundation for their support, and the authors and Springer-Verlag, especially Dr. Marion Hertel, for the pleasant cooperation.

Polymer Blends and Composites
Polymer Blends and Composites

Author: John A. Manson

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 520

ISBN-13: 1461517613

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The need for writing a monograph on polymer blends and composites became apparent during presentation of material on this subject to our advanced polymers class. Although the flood of important research in this area in the past decade has resulted in many symposia, edited collections of papers, reviews, contributions to scientific journals, and patents, apparently no organized presentation in book form has been forthcoming. In a closely connected way, another strong impetus for writing this monograph arose out of our research programs in the Materials Research Center at Lehigh University. As part of this effort, we had naturally compiled hundreds of references and become acquainted with many leaders in the field of blend and composite research. Perhaps the most important concept stressed over and over again is that engineering materials are useful because of their complexity, not in spite of it. Blends and composites are toughened because many modes of resistance to failure are available. Although such multimechanism processes are diffi cult to describe with a unified theory. we have presented available develop ments in juxtaposition with the experimental portions. The arguments somewhat resemble the classical discussion of resonance in organic chemistry, where molecular structures increase in stability as more electronic configura tions become available.

Introduction to Polymer Viscoelasticity
Introduction to Polymer Viscoelasticity

Author: Montgomery T. Shaw

Publisher: John Wiley & Sons

Published: 2005-08-19

Total Pages: 339

ISBN-13: 0471741825

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A revised molecular approach to a classic on viscoelasticbehavior Because viscoelasticity affects the properties, appearance,processing, and performance of polymers such as rubber, plastic,and adhesives, a proper utilization of such polymers requires aclear understanding of viscoelastic behavior. Now in its third edition, Introduction to Polymer Viscoelasticityremains a classic in the literature of molecular viscoelasticity,bridging the gap between primers on polymer science and advancedresearch-level monographs. Assuming a molecular, rather than amechanical approach, the text provides a strong grounding in thefundamental concepts, detailed derivations, and particularattention to assumptions, simplifications, and limitations. This Third Edition has been entirely revised and updated to reflectrecent developments in the field. New chapters include: * Phenomenological Treatment of Viscoelasticity * Viscoelastic Models * Time-Temperature Correspondence * Transitions and Relaxation in Polymers * Elasticity of Rubbery Networks * Dielectric and NMR Methods With detailed explanations, corresponding equations, andexperimental methods, supported by real-life applications (as wellas the inclusion of a CD-ROM with data to support the exercises),this Third Edition provides today's students and professionals withthe tools they need to create polymers with more desirablequalities than ever.

Polymer Viscoelasticity
Polymer Viscoelasticity

Author: Evaristo Riande

Publisher: CRC Press

Published: 1999-11-05

Total Pages: 906

ISBN-13: 9780824779047

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Showcasing vital engineering applications to transient and dynamic pertubations of macromolecular materials, structural recovery's role in mechanical responses in the glassy state, and viscoelastic parameters that condition the non-Newtonian behaviour of polymers, this work presents a systematic account of the responses of macromolecular materials to mechanical force fields. It focuses on the most important features of the linear stress-strain relationships for ideal solids and liquids.

Mechanical Properties of Polymers and Composites, Second Edition
Mechanical Properties of Polymers and Composites, Second Edition

Author: Robert F. Landel

Publisher: CRC Press

Published: 1993-12-14

Total Pages: 586

ISBN-13: 9780824789640

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This text, now in its second edition, offers an up-to-date, expanded treatment of the behaviour of polymers with regard to material variables and test and use conditions. It highlights general principles, useful empirical rules and practical equations.;Detailing the specific behaviour of many common polymers, the text: places emphasis on time and frequency dependence over temperature dependence; uses contemporary molecular mechanisms to explain creep, stress relaxation, constant strain rate responses and crazing; provides explicit equations to predict responses; supplies a discussion of large deformation multiaxial responses; compares statistical and continuum theories on the same data set; and updates stress-strain behaviour and particulate filled systems.