Principles of Adsorption and Adsorption Processes

Principles of Adsorption and Adsorption Processes

Author: Douglas M. Ruthven

Publisher: John Wiley & Sons

Published: 1984-06-05

Total Pages: 466

ISBN-13: 9780471866060

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The first up-to-date summary and review for the fundamental principles and industrial practice of adsorption separation processes in more than 30 years. Emphasizes the understanding of adsorption column dynamics and the modeling of adsorption systems, as well as fundamental aspects of kinetics and equilibria.


Principles of Adsorption and Reaction on Solid Surfaces

Principles of Adsorption and Reaction on Solid Surfaces

Author: Richard I. Masel

Publisher: John Wiley & Sons

Published: 1996-03-22

Total Pages: 826

ISBN-13: 9780471303923

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Principles of Adsorption and Reaction on Solid Surfaces As with other books in the field, Principles of Adsorption and Reaction on Solid Surfaces describes what occurs when gases come in contact with various solid surfaces. But, unlike all the others, it also explains why. While the theory of surface reactions is still under active development, the approach Dr. Richard Masel takes in this book is to outline general principles derived from thermodynamics and reaction rate theory that can be applied to reactions on surfaces, and to indicate ways in which these principles may be applied. The book also provides a comprehensive treatment of the latest quantitative surface modeling techniques with numerous examples of their use in the fields of chemical engineering, physical chemistry, and materials science. A valuable working resource and an excellent graduate-level text, Principles of Adsorption and Reaction on Solid Surfaces provides readers with: * A detailed look at the latest advances in understanding and quantifying reactions on surfaces * In-depth reviews of all crucial background material * 40 solved examples illustrating how the methods apply to catalysis, physical vapor deposition, chemical vapor deposition, electrochemistry, and more * 340 problems and practice exercises * Sample computer programs * Universal plots of many key quantities * Detailed, class-tested derivations to help clarify key results The recent development of quantitative techniques for modeling surface reactions has led to a number of exciting breakthroughs in our understanding of what happens when gases come in contact with solid surfaces. While many books have appeared describing various experimental modeling techniques and the results obtained through their application, until now, there has been no single-volume reference devoted to the fundamental principles governing the processes observed. The first book to focus on governing principles rather than experimental techniques or specific results, Principles of Adsorption and Reaction on Solid Surfaces provides students and professionals with a quantitative treatment of the application of principles derived from the fields of thermodynamics and reaction rate theory to the investigation of gas adsorption and reaction on solid surfaces. Writing for a broad-based audience including, among others, chemical engineers, chemists, and materials scientists, Dr. Richard I. Masel deftly balances basic background in areas such as statistical mechanics and kinetics with more advanced applications in specialized areas. Principles of Adsorption and Reaction on Solid Surfaces was also designed to provide readers an opportunity to quickly familiarize themselves with all of the important quantitative surface modeling techniques now in use. To that end, the author has included all of the key equations involved as well as numerous real-world illustrations and solved examples that help to illustrate how the equations can be applied. He has also provided computer programs along with universal plots that make it easy for readers to apply results to their own problems with little computational effort. Principles of Adsorption and Reaction on Solid Surfaces is a valuable working resource for chemical engineers, physical chemists, and materials scientists, and an excellent text for graduate students in those disciplines.


Gas Separation by Adsorption Processes

Gas Separation by Adsorption Processes

Author: Ralph T. Yang

Publisher: Butterworth-Heinemann

Published: 2013-10-22

Total Pages: 363

ISBN-13: 1483162664

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Gas Separation by Adsorption Processes provides a thorough discussion of the advancement in gas adsorption process. The book is comprised of eight chapters that emphasize the fundamentals concept and principles. The text first covers the adsorbents and adsorption isotherms, and then proceeds to detailing the equilibrium adsorption of gas mixtures. Next, the book covers rate processes in adsorbers and adsorber dynamics. The next chapter discusses cyclic gas separation processes, and the remaining two chapters cover pressure-swing adsorption. The book will be of great use to students, researchers, and practitioners of disciplines that involve gas separation processes, such as chemical engineering.


Adsorption Processes for Water Treatment

Adsorption Processes for Water Treatment

Author: Samuel D. Faust

Publisher: Elsevier

Published: 2013-10-22

Total Pages: 522

ISBN-13: 148316263X

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Adsorption Processes for Water Treatment discusses the application of adsorption in water purification. The book is comprised of 10 chapters that detail the carbon and resin adsorptive processes for potable water treatment. The text first covers the elements of surface chemistry and then proceeds to discussing adsorption models. Chapter 3 tackles the kinetics of adsorption, while Chapter 4 deals with batch systems and fixed fluid beds. Next, the book talks about the physical and chemical properties of carbon. The next two chapters discuss the adsorption of organic compounds and the removal of inorganic compounds, respectively. The eighth chapter presents operational, pilot plant, and case studies. Chapter 9 discusses the biological activated carbon treatment of drinking water, and Chapter 10 covers the adsorption of macroreticular resins. The book will be of great use to both researchers and professionals involved in the research and development of water treatment process.


Intensification of Sorption Processes

Intensification of Sorption Processes

Author: Mahmood Reza Rahimi

Publisher: Elsevier

Published: 2021-11-23

Total Pages: 280

ISBN-13: 0128214120

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Intensification of Sorption Processes: Active and Passive Mechanisms introduces a number of selected, advanced topics in sorption processes/process intensification, covering both theoretical and applicable aspects. The first part of the book is devoted to the study of sorption processes based on active mechanisms, including ultrasonic, microwave, high-gravity, electrical and magnetic fields, while the second part covers passive mechanisms like nanostructures and nanofluids, membrane, supercritical fluids and sorption processes based on geometry design and equipment structure. The focus of the book is on key aspects of novel process intensification technologies (processes and equipment), i.e., absorption and adsorption, working principles, and design and applications. Covers all developments in the field of active and passive mechanisms for sorption processes Introduces basic principles of any intensified sorption process, along with details of equipment Evaluates industrial upscaling, economic evaluation/justification, future opportunities and challenges for each sorption process


Adsorption of Gases on Heterogeneous Surfaces

Adsorption of Gases on Heterogeneous Surfaces

Author: W. Rudzinski

Publisher: Academic Press

Published: 2012-12-02

Total Pages: 619

ISBN-13: 0080984363

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All real solid surfaces are heterogeneous to a greater or lesser extent and this book provides a broad yet detailed survey of the present state of gas adsorption. Coverage is comprehensive and extends from basic principles to computer simulation of adsorption. Underlying concepts are clarified and the strengths and weaknesses of the various methods described are discussed. Adsorption isotherm equations for various types of heterogeneous solid surfaces Methods of determining the nature of surface heterogeneity and porosity from experimental data Studies of phase behavior of gases absorbed on heterogeneous solid surfaces Computer simulation of adsorption on heterogeneous solid surfaces


Adsorption by Powders and Porous Solids

Adsorption by Powders and Porous Solids

Author: Jean Rouquerol

Publisher: Academic Press

Published: 2013-09-06

Total Pages: 647

ISBN-13: 0080970362

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The declared objective of this book is to provide an introductory review of the various theoretical and practical aspects of adsorption by powders and porous solids with particular reference to materials of technological importance. The primary aim is to meet the needs of students and non-specialists who are new to surface science or who wish to use the advanced techniques now available for the determination of surface area, pore size and surface characterization. In addition, a critical account is given of recent work on the adsorptive properties of activated carbons, oxides, clays and zeolites. Provides a comprehensive treatment of adsorption at both the gas/solid interface and the liquid/solid interface Includes chapters dealing with experimental methodology and the interpretation of adsorption data obtained with porous oxides, carbons and zeolites Techniques capture the importance of heterogeneous catalysis, chemical engineering and the production of pigments, cements, agrochemicals, and pharmaceuticals


Equilibria and Dynamics of Gas Adsorption on Heterogeneous Solid Surfaces

Equilibria and Dynamics of Gas Adsorption on Heterogeneous Solid Surfaces

Author: W.A. Steele

Publisher: Elsevier

Published: 1996-12-17

Total Pages: 909

ISBN-13: 0080531199

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The fact that the surfaces of real solids are geometrically distorted and chemically non-uniform has long been realized by the scientists investigating various phenomena occurring on solid surfaces. Even in the case when diffraction experiments show a well-organized bulk solid structure, the surface atoms or molecules will usually exhibit a much smaller degree of surface organization. In addition to the results obtained from electron diffraction, this can be seen in the impressive images obtained from STM and AFM microscopies. This geometric and chemical disorder is the source of the energetic heterogeneity for molecules adsorbing on real solid surfaces. Hundreds of papers have been published showing that this heterogeneity is a major factor in determining the behaviour of real adsorption systems. Studies of adsorption on energetically heterogeneous surfaces have proceeded along three somewhat separate paths, with only minor coupling of ideas. One was the study of adsorption equilibria on heterogeneous solid surfaces. The second path was the study of time evolution of adsorption processes such as surface diffusion or adsorption-desorption kinetics on heterogeneous surfaces, and the third was the study of adsorption in porous solids, or more generally, adsorption in systems with limited dimensions. The present monograph is a first attempt to provide a synthesis of the ways that surface geometric and energetic heterogeneities affect both the equilibria and the time evolution of adsorption on real solids. The book contains 17 chapters written by a team of internationally recognized specialists, some of whom have already published books on adsorption.


Adsorption, Ion Exchange and Catalysis

Adsorption, Ion Exchange and Catalysis

Author: Stavros G. Poulopoulos

Publisher: Elsevier

Published: 2006-08-23

Total Pages: 615

ISBN-13: 0080463665

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Adsorption, Ion Exchange and Catalysis is essentially a mixture of environmental science and chemical reactor engineering. More specifically, three important heterogeneous processes, namely, adsorption, ion exchange and catalysis, are analysed, from fundamental kinetics to reactor design with emphasis on their environmental applications. In Chapter 1, the subject of air and water pollution is dealt with. Data about pollutants and emission sources are given and the treatment methods are shortly presented. In Chapter 2, the very basics and historical development of adsorption, ion exchange and catalysis are presented as well as their environmental applications. Chapter 3 is devoted to heterogeneous processes and reactor analysis. All types of reactors are described in depth and reactor modelling, hydraulics and mass/heat transfer phenomena are examined for each type of reactor. Chapters 4 and 5 are dedicated to adsorption & ion exchange and catalysis, respectively. The basic principles are presented including kinetics, equilibrium, mass/heat transfer phenomena as well as the analytical solutions of the reactor models presented in Chapter 3. In the sixth chapter, the subject of scale up is approached. The two Annexes at the end of the book contain physical properties of substances of environmental interest as well as unit conversion tables. Finally, nearly all the examples contained are based on real experimental data found in literature with environmental interest. Most of the examples consider all aspects of operation design – kinetics, hydraulics and mass transfer. * Provides basic knowledge of major environmental problems and connects them to chemical engineering