Preparation of the High-Tc Superconductor YBa2Cu3O(7-x) Using Organometallic Precursors

Preparation of the High-Tc Superconductor YBa2Cu3O(7-x) Using Organometallic Precursors

Author: Leonard V. Interrante

Publisher:

Published: 1988

Total Pages: 18

ISBN-13:

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Organic soluble precursors to the high Tc 1-2-3 superconductor, YBa2Cu3O7-x, have been prepared using polyesters derived from the interaction of citric acid (CA) or ethyl-enediaminetetraacetric acid (EDTA) with ethylene glycol. Mixtures of the nitrate, carbonate and/or acetate salts of the three metal ions with CA or EDTA and ethylene glycol were heated to obtain homogeneous green solids containing the desired 1:2:3 ratios of Y3+, Ba2+, and Cu2+ ions. Pyrolysis at 850C-960C in oxygen gave the superconducting, orthorhombic, YBa2Cu3O7-x phase. Films of the superconductor were prepared by dropping ethylene glycol solutions of these precursors onto zirconia and alumina substrates, followed by pyrolysis to 950 C in O2. The results of TGA/DSC and FTIR studies of these precursors, as well as XRD, FTIR, pyrolysis/GC, electrical and magnetic property measurements on the pyrolysis products are presented and discussed in the context of the probable precursor structures and pyrolysis chemistry. Keywords: Superconductor, Precursor, Thin films, Copper oxides, Yttrium compounds, Barium compounds. (MJM).


High Tc Superconductors

High Tc Superconductors

Author: P.F. Bongers

Publisher: Elsevier

Published: 2012-12-02

Total Pages: 510

ISBN-13: 0080983677

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The papers in this two volume set provide the latest information on research and development in the field of high Tc-materials. Special emphasis is placed on methods of preparation and microstructural characterization for both thin films and single crystals. Considerable attention is also paid to the potential applications of thin films and bulk materials. The following topics are covered in detail: New superconductors; Relations between structure and/or substitution and superconductivity in ternary Cu-oxides; Single crystals, microstructure; Thin films, preparation and properties; Technical applications.


YBCO Superconductor Research Progress

YBCO Superconductor Research Progress

Author: Li-Chun Liáng

Publisher: Nova Publishers

Published: 2008

Total Pages: 248

ISBN-13: 9781604560831

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Superconductivity is the ability of certain materials to conduct electrical current with no resistance and extremely low losses. High temperature superconductors, such as La2-xSrxCuOx (Tc=40K) and YBa2Cu3O7-x (Tc=90K), were discovered in 1987 and have been actively studied since. In spite of an intense world-wide research, a complete understanding of the copper oxide (cuprate) materials is still lacking. Many fundamental questions are unanswered, particularly the mechanism by which high-Tc superconductivity occurs. More broadly, the cuprates are in a class of solids with strong electron-electron interactions. An understanding of such 'strongly correlated' solids is perhaps the major unsolved problem of condensed matter physics with over ten thousand researchers working on this topic. High-Tc superconductors also have significant potential for applications in technologies ranging from electric power generation and transmission to digital electronics. This ability to carry large amounts of current can be applied to electric power devices such as motors and generators, and to electricity transmission in power lines. For example, superconductors can carry as much as 100 times the amount of electricity of ordinary copper or aluminium wires of the same size. This Publication presents new research on yttrium barium copper oxide superconductors, often abbreviated YBCO, which is a chemical compound with the formula YBa2Cu3O7. This material, a famous 'high-temperature superconductor', achieved prominence because it was the first material to superconduct above the boiling point of nitrogen. All materials developed before YBCO became superconducting only at temperatures near the boiling points of liquid helium or liquid hydrogen (Tb = 20.1 K). The significance of the discovery of YBCO is the breakthrough in the refrigerant used to cool the material to below the critical temperature.


High-Temperature Superconductors and Novel Inorganic Materials

High-Temperature Superconductors and Novel Inorganic Materials

Author: Gustaaf Tendeloo

Publisher: Springer Science & Business Media

Published: 1999

Total Pages: 328

ISBN-13: 9780792353454

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Research into high-Tc materials demands the co-operation of physicists, chemists and materials scientists to discover the best solutions to the most important challenges presented by the field. In the fifth annual Workshop on High Temperature Superconductors and Novel Inorganic Materials Engineering, the topic is extended beyond high-Tc superconductivity to include other advanced oxide materials, mainly colossal magnetoresistance materials, which are closely related to the ceramic superconductors. This book covers the synthesis, characterisation (both structural and physical) and engineering of this class of materials.


High Temperature Superconductors

High Temperature Superconductors

Author: U. Balachandran

Publisher: Minerals, Metals, & Materials Society

Published: 1996

Total Pages: 376

ISBN-13:

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The 39 peer-reviewed papers in this book provide a state-of-the-art update of exciting work currently being carried on in the area of high-temperature superconductors. Topics of discussion include processing for high critical current densities, flux-pinning mechanisms, processing for the development of flux-pinning centers, chemistry, phase relations, stoichiometry, processing/microstructure relationships, and prototype devices for practical applications.