This book reviews chiral polymer synthesis and its application to asymmetric catalysis. It features the design and use of polymer-immobilized catalysts and methods for their design and synthesis. Chapters cover peptide-catalyzed and enantioselective synthesis, optically-active polymers, and continuous flow processes. It collects recent advances in an important field of polymer and organic chemistry, with leading researchers explaining applications in academic and industry R & D.
Polymer-supported organic catalysts are largely insoluble in most reaction solvents, which allows for easy recovery and recycling of the catalysts. They are generally stable, readily available, and environmental friendly, so they have attracted the interest of many synthetic chemists in the industrial and academic fields. In this book, different types of polymer-supported catalysts based on peptides, polystyrene, polyethers, poly(acrylic acid), poly(ethylene imine), poly(2-oxazoline), poly(isobutylene), poly(norbornene), etc., as well as metals are included with their synthetic organic synthesis applications. It is believed that this work will be of interest to organic chemists, material scientists, chemical engineers, polymer scientists and technologists.
Carraher's Polymer Chemistry, Tenth Edition integrates the core areas of polymer science. Along with updating of each chapter, newly added content reflects the growing applications in Biochemistry, Biomaterials, and Sustainable Industries. Providing a user-friendly approach to the world of polymeric materials, the book allows students to integrate their chemical knowledge and establish a connection between fundamental and applied chemical information. It contains all of the elements of an introductory text with synthesis, property, application, and characterization. Special sections in each chapter contain definitions, learning objectives, questions, case studies and additional reading.
Most of the advancements in communication, computers, medicine, and air and water purity are linked to macromolecules and a fundamental understanding of the principles that govern their behavior. These fundamentals are explored in Carraher's Polymer Chemistry, Ninth Edition. Continuing the tradition of previous volumes, the latest edition provides a well-rounded presentation of the principles and applications of polymers. With an emphasis on the environment and green chemistry and materials, this edition offers detailed coverage of natural and synthetic giant molecules, inorganic and organic polymers, biomacromolecules, elastomers, adhesives, coatings, fibers, plastics, blends, caulks, composites, and ceramics. Using simple fundamentals, this book demonstrates how the basic principles of one polymer group can be applied to all of the other groups. It covers reactivities, synthesis and polymerization reactions, techniques for characterization and analysis, energy absorption and thermal conductivity, physical and optical properties, and practical applications. This edition includes updated techniques, new sections on a number of copolymers, expanded emphasis on nanotechnology and nanomaterials, and increased coverage of topics including carbon nanotubes, tapes and glues, photochemistry, and more. With topics presented so students can understand polymer science even if certain parts of the text are skipped, this book is suitable as an undergraduate as well as an introductory graduate-level text. The author begins most chapters with theory followed by application, and generally addresses the most critical topics first. He provides all of the elements of an introductory text, covering synthesis, properties, applications, and characterization. This user-friendly book also contains definitions, learning objectives, questions, and additional reading in each chapter.
Edited by foremost leaders in chemical research together with a number of distinguished international authors, this fourth volume summarizes the most important and promising recent developments in synthesis, polymer chemistry and supramolecular chemistry. Interdisciplinary and application-oriented, this ready reference focuses on innovative methods, covering new developments in catalysis, synthesis, polymers and more.
This book, Organic Polymers, covers aspects that are of immediate concern to a new entrant to the field of polymers. Taken as a whole, these eight chapters aim to help the readers easily assimilate other specialized and exhaustive treatises on the subject. Topics dealing with the chemistry and technology of polymers are presented in a careful and logical manner so as to provide an easy and enjoyable read. Several examples and analogies are included so to make the main concepts easy to follow and tables and figures are included so that the book can serve, to a limited extent, as a hand book dealing with polysaccharides with different parameters. This book is meant for students studying polysaccharides and those working on graft copolymers and other allied polymer industries but without a formal educational background in organic polymers.
Catalytic Asymmetric Synthesis Seminal text presenting detailed accounts of the most important catalytic asymmetric reactions known today This book covers the preparation of enantiomerically pure or enriched chemical compounds by use of chiral catalyst molecules. While reviewing the most important catalytic methods for asymmetric organic synthesis, this book highlights the most important and recent developments in catalytic asymmetric synthesis. Edited by two well-qualified experts, sample topics covered in the work include: Metal catalysis, organocatalysis, photoredox catalysis, enzyme catalysis C–H bond functionalization reactions Carbon–carbon bond formation reactions, carbon–halogen bond formation reactions, hydrogenations, polymerizations, flow reactions Axially chiral compounds Retaining the best of its predecessors but now thoroughly up to date with the important and recent developments in catalytic asymmetric synthesis, the 4th edition of Catalytic Asymmetric Synthesis serves as an excellent desktop reference and text for researchers and students, from upper-level undergraduates all the way to experienced professionals in industry or academia.
Highlighting the key aspects and latest advances in the rapidly developing field of molecular catalysis, this book covers new strategies to investigate reaction mechanisms, the enhancement of the catalysts' selectivity and efficiency, as well as the rational design of well-defined molecular catalysts. The interdisciplinary author team with an excellent reputation within the community discusses experimental and theoretical studies, along with examples of improved catalysts, and their application in organic synthesis, biocatalysis, and supported organometallic catalysis. As a result, readers will gain a deeper understanding of the catalytic transformations, allowing them to adapt the knowledge to their own investigations. With its ideal combination of fundamental and applied research, this is an essential reference for researchers and graduate students both in academic institutions and in the chemical industry. With a foreword by Nobel laureate Roald Hoffmann.
Organophosphorus Chemistry provides a comprehensive and critical review of the recent literature. Coverage includes phosphines and their chalcogenides, phosphonium salts, low coordination number phosphorus compounds, penta- and hexa- coordinated compounds, quinquevalent phosphorus acids, nucleotides and nucleic acids, ylides and related compounds, phosphazenes and the application of physical methods in the study of organophosphorus compounds. This is the 40th in a series of volumes which first appeared in 1970 under the editorship of Stuart Trippett and which covered the literature of organophosphorus chemistry published in the period from January 1968 to June 1969, citing some 1370 publications. The present volume covers the literature from January 2009 to January 2010, citing more than 2200 publications, continuing our efforts to provide an up to date survey of progress in an area of chemistry that has expanded significantly over the past 40 years.
Organophosphorus Chemistry provides a comprehensive and critical review of the recent literature. Coverage includes phosphines and their chalcogenides, phosphonium salts, low coordination number phosphorus compounds, penta- and hexa- coordinated compounds, quinquevalent phosphorus acids, nucleotides and nucleic acids, ylides and related compounds, phosphazenes and the application of physical methods in the study of organophosphorus compounds. This is the 40th in a series of volumes which first appeared in 1970 under the editorship of Stuart Trippett and which covered the literature of organophosphorus chemistry published in the period from January 1968 to June 1969, citing some 1370 publications. The present volume covers the literature from the last 18 months, citing more than 2200 publications, continuing our efforts to provide an up to date survey of progress in an area of chemistry that has expanded significantly over the past 40 years.
