Modelling the Dissociation Dynamics and Threshold Photoelectron Spectra of Small Halogenated Molecules

Modelling the Dissociation Dynamics and Threshold Photoelectron Spectra of Small Halogenated Molecules

Author: Jonelle Harvey

Publisher: Springer Science & Business Media

Published: 2013-11-09

Total Pages: 184

ISBN-13: 3319029762

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Jonelle Harvey's book outlines two related experimental techniques, threshold photoelectron spectroscopy and threshold photoelectron photoion coincidence techniques, which are utilised to investigate small halogenated molecules. All the experiments were conducted at the vacuum ultraviolet beamline of the Swiss Light Source, a synchrotron photon source, which has the advantage over popular laser photon-sources of extreme ease of tunability. Three studies are presented which combine experimental and computational ab initio approaches: studying the fast dissociations of halogenated methanes in order to construct a self-consistent thermochemical network; investigating the fragmentations of fluoroethenes from timebombs, which break apart very slowly but explosively, to fast dissociators; and uncovering how vital conical interactions underpin both the results of photoelectron spectra and dissociation patterns. The details included in this thesis are useful for researchers working in the same field and those readers wishing to obtain a solid introduction into the types of systems encountered in threshold photoelectron photoion coincidence spectroscopy.


Electronic and Photoelectron Spectroscopy

Electronic and Photoelectron Spectroscopy

Author: Andrew M. Ellis

Publisher: Cambridge University Press

Published: 2005-01-13

Total Pages: 302

ISBN-13: 113944185X

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Electronic and photoelectron spectroscopy can provide extraordinarily detailed information on the properties of molecules and are in widespread use in the physical and chemical sciences. Applications extend beyond spectroscopy into important areas such as chemical dynamics, kinetics and atmospheric chemistry. This book aims to provide the reader with a firm grounding of the basic principles and experimental techniques employed. The extensive use of case studies effectively illustrates how spectra are assigned and how information can be extracted, communicating the matter in a compelling and instructive manner. Topics covered include laser-induced fluorescence, resonance-enhanced multiphoton ionization, cavity ringdown and ZEKE spectroscopy. The volume is for advanced undergraduate and graduate students taking courses in spectroscopy and will also be useful to anyone encountering electronic and/or photoelectron spectroscopy during their research.


Vacuum Ultraviolet Photoionization and Photodissociation of Molecules and Clusters

Vacuum Ultraviolet Photoionization and Photodissociation of Molecules and Clusters

Author: Cheuk-Yiu Ng

Publisher: World Scientific

Published: 1991

Total Pages: 590

ISBN-13: 9789810204303

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This monograph reviews the recent progress in vacuum ultraviolet (VUV) photoionization and photodissociation processes. Photoionization, photoelectron, and fluorescence spectroscopic techniques have played an important role in revealing the photoionization and photodissociation dynamics of molecules in the vacuum ultraviolet region and in providing accurate energetic and spectroscopic information of ions as well as neutral molecules. The book represents the first detailed review of major experimental developments in the studies of single vacuum ultraviolet photon ionization and dissociation processes of gaseous molecules and clusters.


Quantum Optics - Proceedings Of The 13th Summer School On Quantum Optics

Quantum Optics - Proceedings Of The 13th Summer School On Quantum Optics

Author: J Fiutak

Publisher: World Scientific

Published: 1986-06-01

Total Pages: 412

ISBN-13: 9813201835

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Systems and tools of computer algebra (Like AXIOM, Derive, FORM, Mathematica, Maple, Mupad, REDUCE, Macsyma…) let us manipulate extremely complex algebraic formulae symbolically on a computer. Contrary to numerics these computations are exact and there is no loss of accuracy. After decades of research and development, these tools are now becoming as indispensable in Science and Engineering as traditional number crunching already is.The ZiF'94 workshop is amongst the first devoted specifically to applications of computer algebra (CA) in Science and Engineering. The book documents the state of the art in this area and serves as an important reference for future work.


Proceedings of the 11th International Conference on Vacuum Ultraviolet Radiation Physics

Proceedings of the 11th International Conference on Vacuum Ultraviolet Radiation Physics

Author: T. Miyahara

Publisher: Elsevier

Published: 2012-12-02

Total Pages: 590

ISBN-13: 0444597190

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These volumes contain 365 of the 505 papers presented at the VUV-11 Conference, held at Rikkyo University, Tokyo, from August 27th to September 1st 1995. The papers are divided into three sections: atomic and molecular spectroscopy, solid state spectroscopy and instrumentation and technological applications. New aspects presented were both quantitative and qualitative improvements in fluorescence spectroscopy and magnetic circular dichroism measurements. The fluorescence data are complementary to those of photoemission in a sense but they appear to open up a new method to analyze the optical excitation and relaxation processes. The application of magnetic circular dichroism has proved to be useful not only in analyzing the electronic structures of magnetic materials but also in practical applications to material engineering as found in experiments combined with photoelectron microscopy. Excellent developments in applications are only found in the field of surface photochemistry, where the technique of etching using VUV light has been appreciably refined. Although the majority of distinctive scientific features in the VUV-11 Conference have been brought about by the application of synchrotron radiation, experiments using a different type of light source appear to have progressed steadily. This is evident in the studies of plasma radiation.


Conical Intersections

Conical Intersections

Author: Wolfgang Domcke

Publisher: World Scientific

Published: 2011

Total Pages: 769

ISBN-13: 9814313440

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The concept of adiabatic electronic potential-energy surfaces, defined by the Born?Oppenheimer approximation, is fundamental to our thinking about chemical processes. Recent computational as well as experimental studies have produced ample evidence that the so-called conical intersections of electronic energy surfaces, predicted by von Neumann and Wigner in 1929, are the rule rather than the exception in polyatomic molecules. It is nowadays increasingly recognized that conical intersections play a key mechanistic role in chemical reaction dynamics. This volume provides an up-to-date overview of the multi-faceted research on the role of conical intersections in photochemistry and photobiology, including basic theoretical concepts, novel computational strategies as well as innovative experiments. The contents and discussions will be of value to advanced students and researchers in photochemistry, molecular spectroscopy and related areas.


Photoionization and Photodetachment

Photoionization and Photodetachment

Author: Cheuk-Yiu Ng

Publisher: World Scientific

Published: 2000

Total Pages: 1415

ISBN-13: 9812813470

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Owing to the advances of vacuum ultraviolet and ultrafast lasers and third generation synchrotron sources, the research on photoionization, photoelectrons, and photodetachment has gained much vitality in recent years. These new light sources, together with ingenious experimental techniques, such as the coincidence imaging, molecular beam, pulsed field ionization photoelectron, mass-analyzed threshold ion, and pulsed field ion pair schemes, have allowed spectroscopic, dynamic, and energetic studies of gaseous species to a new level of detail and accuracy. Profitable applications of these methods to liquids are emerging.This invaluable two-volume review consists of twenty-two chapters, focusing on recent developments in photoionization and photodetachment studies of atoms; molecules, transient species, clusters, and liquids.


Photoionization And Photodetachment (In 2 Parts)

Photoionization And Photodetachment (In 2 Parts)

Author: Cheuk-yiu Ng

Publisher: World Scientific

Published: 2000-06-30

Total Pages: 684

ISBN-13: 9814494739

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Owing to the advances of vacuum ultraviolet and ultrafast lasers and third generation synchrotron sources, the research on photoionization, photoelectrons, and photodetachment has gained much vitality in recent years. These new light sources, together with ingenious experimental techniques, such as the coincidence imaging, molecular beam, pulsed field ionization photoelectron, mass-analyzed threshold ion, and pulsed field ion pair schemes, have allowed spectroscopic, dynamic, and energetic studies of gaseous species to a new level of detail and accuracy. Profitable applications of these methods to liquids are emerging.This invaluable two-volume review consists of twenty-two chapters, focusing on recent developments in photoionization and photodetachment studies of atoms; molecules, transient species, clusters, and liquids.