This handbook is the most comprehensive compilation of data on the optical properties of diamond ever written. It presents a multitude of data previously for the first time in English. The author provides quick access to the most comprehensive information on all aspects of the field.
The unique properties of diamond are responsible for its pre-eminence as a gemstone, and give it a glamour and attraction unprecedented for any other mineral. As the first member of group IV of the periodic table of elements, carbon, in its crystalline form as diamond, has also fascinated scientists for at least 300 years. Many experimental techniques have been employed in the study of diamond, and of these, optical spectroscopy has proven one of the most fruitful. The absorption line at 415 nm, characteristic of "Cape Yellow" diamonds, was first documented by Walter in 1891. Further work on this absorption, now known as "N3", by the Indian school under Sir C. V. Raman in the 1930s and 1940s led to a basic understanding of the system, which they observed in both absorption and luminescence. The N3 center is a structural defect in the diamond, and the absorption of light occurs by exciting electrons in this defect from one well-defined energy state to another. When the electron returns to the original energy level, luminescence is produced. Detailed studies of natural diamonds over the subsequent 60 years have discovered large numbers of absorption and emission lines, characteristic of different defects. In 1904 Sir William Crookes showed that a colorless diamond could be turned green by long exposure to radium salts.
This is the first comprehensive book on the engineering of diamond optical devices. Written by 39 experts in the field, it gives readers an up-to-date review of the properties of optical quality synthetic diamond (single crystal and nanodiamond) and the nascent field of diamond optical device engineering. Application areas covered in detail in this book include quantum information processing, high performance lasers and light sources, and bioimaging. It provides scientists, engineers and physicists with a valuable and practical resource for the design and development of diamond-based optical devices.
Focusing on the physical properties of diamond and sapphire, this monograph provides readers with essential details on crystal structure and growth, mechanical properties, thermal properties, optical properties, light scattering of diamond and sapphire crystals, and sapphire lasers. Various physical properties are comprehensively discussed: Mechanical properties include hardness, tensile strength, compressive strength, and Young’s modulus. Thermal properties include thermal expansion, specific heat, and thermal conductivity. Optical properties of diamond and sapphire include transmission, refractive index, and absorption. Light scattering includes Raman scattering and Brillouin scattering. Sapphire lasers include chromium-doped and titanium-doped lasers. Aimed at researchers and industry professionals working in materials science, physics, electrical engineering, and related fields, this monograph is the first to concentrate solely on physical properties of these increasingly important materials.
This handbook--a sequel to the widely used Handbook of Optical Constants of Solids--contains critical reviews and tabulated values of indexes of refraction (n) and extinction coefficients (k) for almost 50 materials that were not covered in the original handbook. For each material, the best known n and k values have been carefully tabulated, from the x-ray to millimeter-wave region of the spectrum by expert optical scientists. In addition, the handbook features thirteen introductory chapters that discuss the determination of n and k by various techniques.* Contributors have decided the best values for n and k* References in each critique allow the reader to go back to the original data to examine and understand where the values have come from* Allows the reader to determine if any data in a spectral region needs to be filled in* Gives a wide and detailed view of experimental techniques for measuring the optical constants n and k* Incorporates and describes crystal structure, space-group symmetry, unit-cell dimensions, number of optic and acoustic modes, frequencies of optic modes, the irreducible representation, band gap, plasma frequency, and static dielectric constant
The use of diamond for electronic applications is not a new idea. As early as the 1920's diamonds were considered for their use as photoconductive detectors. However limitations in size and control of properties naturally limited the use of diamond to a few specialty applications. With the development of diamond synthesis from the vapor phase has come a more serious interest in developing diamond-based electronic devices. A unique combination of extreme properties makes diamond partiCularly well suited for high speed, high power, and high temperature applications. Vapor phase deposition of diamond allows large area films to be deposited, whose properties can potentially be controlled. Since the process of diamond synthesis was first realized, great progress have been made in understanding the issues important for growing diamond and fabricating electronic devices. The quality of both intrinsic and doped diamond has improved greatly to the point that viable applications are being developed. Our understanding of the properties and limitations has also improved greatly. While a number of excellent references review the general properties of diamond, this volume summarizes the great deal of literature related only to electronic properties and applications of diamond. We concentrate only on diamond; related materials such as diamond-like carbon (DLC) and other wide bandgap semiconductors are not treated here. In the first chapter Profs. C. Y. Fong and B. M. Klein discuss the band structure of single-crystal diamond and its relation to electronic properties.
Recent breakthroughs in the synthesis of diamond have led to increased availability at lower cost. This has spurred R&D into its characterization and application in machine tools, optical coatings, X-ray windows and light-emitting optoelectronic devices. This book draws together expertise from some 60 researchers in Europe and the USA working on bulk and thin film diamond. All fully refereed, the contributions are combined to form a highly structured volume with reviews, evaluations, tables and illustrative material, together with expert guidance to the literature.
Optical Properties of Solids covers the important concepts of intrinsic optical properties and photoelectric emission. The book starts by providing an introduction to the fundamental optical spectra of solids. The text then discusses Maxwell's equations and the dielectric function; absorption and dispersion; and the theory of free-electron metals. The quantum mechanical theory of direct and indirect transitions between bands; the applications of dispersion relations; and the derivation of an expression for the dielectric function in the self-consistent field approximation are also encompassed. The book further tackles current-current correlations; the fluctuation-dissipation theorem; and the effect of surface plasmons on optical properties and photoemission. People involved in the study of the optical properties of solids will find the book invaluable.
The most comprehensive reference on fluorescent nanodiamond physical and chemical properties and contemporary applications Fluorescent nanodiamonds (FNDs) have drawn a great deal of attention over the past several years, and their applications and development potential are proving to be manifold and vast. The first and only book of its kind, Fluorescent Nanodiamonds is a comprehensive guide to the basic science and technical information needed to fully understand the fundamentals of FNDs and their potential applications across an array of domains. In demonstrating the importance of FNDs in biological applications, the authors bring together all relevant chemistry, physics, materials science and biology. Nanodiamonds are produced by powerful cataclysmic events such as explosions, volcanic eruptions and meteorite impacts. They also can be created in the lab by high-pressure high-temperature treatment of graphite or detonating an explosive in a reactor vessel. A single imperfection can give a nanodiamond a specific, isolated color center which allows it to function as a single, trapped atom. Much smaller than the thickness of a human hair, a nanodiamond can have a huge surface area that allows it to bond with a variety of other materials. Because of their non-toxicity, nanodiamonds may be useful in biomedical applications, such as drug delivery and gene therapy. The most comprehensive reference on a topic of rapidly increasing interest among academic and industrial researchers across an array of fields Includes numerous case studies and practical examples from many areas of research and industrial applications, as well as fascinating and instructive historical perspectives Each chapter addresses, in-depth, a single integral topic including the fundamental properties, synthesis, mechanisms and functionalisation of FNDs The first book published by the key patent holder with his research group in the field of FNDs Fluorescent Nanodiamonds is an important working resource for a broad range of scientists and engineers in industry and academia. It will also be a welcome reference for instructors in chemistry, physics, materials science, biology and related fields.
For final year undergraduates and graduate students in physics, this book offers an up-to-date treatment of the optical properties of solid state materials.