Non-Classical Crystallization of Thin Films and Nanostructures in CVD and PVD Processes

Non-Classical Crystallization of Thin Films and Nanostructures in CVD and PVD Processes

Author: Nong Moon Hwang

Publisher: Springer

Published: 2016-06-14

Total Pages: 338

ISBN-13: 9401776164

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This book provides a comprehensive introduction to a recently-developed approach to the growth mechanism of thin films and nanostructures via chemical vapour deposition (CVD). Starting from the underlying principles of the low pressure synthesis of diamond films, it is shown that diamond growth occurs not by individual atoms but by charged nanoparticles. This newly-discovered growth mechanism turns out to be general to many CVD and some physical vapor deposition (PVD) processes. This non-classical crystallization is a new paradigm of crystal growth, with active research taking place on growth in solution, especially in biomineralization processes. Established understanding of the growth of thin films and nanostructures is based around processes involving individual atoms or molecules. According to the author’s research over the last two decades, however, the generation of charged gas phase nuclei is shown to be the rule rather than the exception in the CVD process, and charged gas phase nuclei are actively involved in the growth of films or nanostructures. This new understanding is called the theory of charged nanoparticles (TCN). This book describes how the non-classical crystallization mechanism can be applied to the growth of thin films and nanostructures in gas phase synthesis. Based on the author’s graduate lecture course, the book is aimed at senior undergraduate and graduate students and researchers in the field of thin film and nanostructure growth or crystal growth. It is hoped that a new understanding of the growth processes of thin films and nanostructures will reduce trial-and-error in research and in industrial fabrication processes.


Chemical Vapor Deposition

Chemical Vapor Deposition

Author: S Neralla

Publisher: BoD – Books on Demand

Published: 2016-08-31

Total Pages: 292

ISBN-13: 9535125729

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This book provides an overview of chemical vapor deposition (CVD) methods and recent advances in developing novel materials for application in various fields. CVD has now evolved into the most widely used technique for growth of thin films in electronics industry. Several books on CVD methods have emerged in the past, and thus the scope of this book goes beyond providing fundamentals of the CVD process. Some of the chapters included highlight current limitations in the CVD methods and offer alternatives in developing coatings through overcoming these limitations.


Nano-sized Multifunctional Materials

Nano-sized Multifunctional Materials

Author:

Publisher: Elsevier

Published: 2018-11-20

Total Pages: 292

ISBN-13: 0128139358

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Nano-sized Multifunctional Materials: Synthesis, Properties and Applications explores how materials can be down-scaled to nanometer-size in order to tailor and control properties. These advanced, low-dimensional materials, ranging from quantum dots and nanoparticles, to ultra-thin films develop multifunctional properties. As well as demonstrating how down-scaling to nano-size can make materials multifunctional, chapters also show how this technology can be applied in electronics, medicine, energy and in the environment. This fresh approach in materials research will provide a valuable resource for materials scientists, materials engineers, chemists, physicists and bioengineers who want to learn more on the special properties of nano-sized materials. - Outlines the major synthesis chemical process and problems of advanced nanomaterials - Shows how multifunctional nanomaterials can be practically used in biomedical area, nanomedicine, and in the treatment of pollutants - Demonstrates how the properties of a variety of materials can be engineered by downscaling them to nano size


Atomic Layer Deposition for Semiconductors

Atomic Layer Deposition for Semiconductors

Author: Cheol Seong Hwang

Publisher: Springer Science & Business Media

Published: 2013-10-18

Total Pages: 266

ISBN-13: 146148054X

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Offering thorough coverage of atomic layer deposition (ALD), this book moves from basic chemistry of ALD and modeling of processes to examine ALD in memory, logic devices and machines. Reviews history, operating principles and ALD processes for each device.


Mesocrystals and Nonclassical Crystallization

Mesocrystals and Nonclassical Crystallization

Author: Helmut Cöelfen

Publisher: John Wiley & Sons

Published: 2008-07-21

Total Pages: 302

ISBN-13:

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"This book gives an introduction to self-assembly, classical crystallization, colloidal crystals, and mesocrystals. - This book will be of value to scientists involved with crystallization, materials science, self-assembly, colloid science, nanosciences, biomineralization, and graduate students of material science."--Jacket.


Crystallization and Growth of Colloidal Nanocrystals

Crystallization and Growth of Colloidal Nanocrystals

Author: Edson Roberto Leite

Publisher: Springer Science & Business Media

Published: 2011-11-17

Total Pages: 101

ISBN-13: 1461413087

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Since the size, shape, and microstructure of nanocrystalline materials strongly impact physical and chemical properties, the development of new synthetic routes to nanocrystals with controlled composition and morphology is a key objective of the nanomaterials community. This objective is dependent on control of the nucleation and growth mechanisms that occur during the synthetic process, which in turn requires a fundamental understanding of both classical nucleation and growth and non-classical growth processes in nanostructured materials. Recently, a novel growth process called Oriented Attachment (OA) was identified which appears to be a fundamental mechanism during the development of nanoscale materials. OA is a special case of aggregation that provides an important route by which nanocrystals grow, defects are formed, and unique—often symmetry-defying—crystal morphologies can be produced. This growth mechanism involves reversible self-assembly of primary nanocrystals followed by reorientation of the assembled nanoparticles to achieve structural accord at the particle-particle interface, the removal of adsorbates and solvent molecules, and, finally, the irreversible formation of chemical bonds to produce new single crystals, twins, and intergrowths. Crystallization and Growth of Colloidal Nanocrystals provides a current understanding of the mechanisms related to nucleation and growth for use in controlling nanocrystal morphology and physical-chemical properties, and is essential reading for any chemist or materials scientist with an interest in using nanocrystals as building blocks for larger structures. This book provides a compendium for the expert reader as well as an excellent introduction for advanced undergraduate and graduate students seeking a gateway into this dynamic area of research.


The Materials Science of Thin Films

The Materials Science of Thin Films

Author: Milton Ohring

Publisher: Academic Press

Published: 1992

Total Pages: 744

ISBN-13: 9780125249904

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Prepared as a textbook complete with problems after each chapter, specifically intended for classroom use in universities.


Handbook of Physical Vapor Deposition (PVD) Processing

Handbook of Physical Vapor Deposition (PVD) Processing

Author: D. M. Mattox

Publisher: Cambridge University Press

Published: 2014-09-19

Total Pages: 947

ISBN-13: 0080946585

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This book covers all aspects of physical vapor deposition (PVD) process technology from the characterizing and preparing the substrate material, through deposition processing and film characterization, to post-deposition processing. The emphasis of the book is on the aspects of the process flow that are critical to economical deposition of films that can meet the required performance specifications. The book covers subjects seldom treated in the literature: substrate characterization, adhesion, cleaning and the processing. The book also covers the widely discussed subjects of vacuum technology and the fundamentals of individual deposition processes. However, the author uniquely relates these topics to the practical issues that arise in PVD processing, such as contamination control and film growth effects, which are also rarely discussed in the literature. In bringing these subjects together in one book, the reader can understand the interrelationship between various aspects of the film deposition processing and the resulting film properties. The author draws upon his long experience with developing PVD processes and troubleshooting the processes in the manufacturing environment, to provide useful hints for not only avoiding problems, but also for solving problems when they arise. He uses actual experiences, called ""war stories"", to emphasize certain points. Special formatting of the text allows a reader who is already knowledgeable in the subject to scan through a section and find discussions that are of particular interest. The author has tried to make the subject index as useful as possible so that the reader can rapidly go to sections of particular interest. Extensive references allow the reader to pursue subjects in greater detail if desired. The book is intended to be both an introduction for those who are new to the field and a valuable resource to those already in the field. The discussion of transferring technology between R&D and manufacturing provided in Appendix 1, will be of special interest to the manager or engineer responsible for moving a PVD product and process from R&D into production. Appendix 2 has an extensive listing of periodical publications and professional societies that relate to PVD processing. The extensive Glossary of Terms and Acronyms provided in Appendix 3 will be of particular use to students and to those not fully conversant with the terminology of PVD processing or with the English language.


1D Semiconducting Nanostructures for Flexible and Large-Area Electronics

1D Semiconducting Nanostructures for Flexible and Large-Area Electronics

Author: Dhayalan Shakthivel

Publisher: Cambridge University Press

Published: 2019-10-31

Total Pages: 163

ISBN-13: 1108624162

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Semiconducting nanostructures such as nanowires (NWs) have been used as building blocks for various types of sensors, energy storage and generation devices, electronic devices and for new manufacturing methods involving printed NWs. The response of these sensing/energy/electronic components and the new fabrication methods depends very much on the quality of NWs and for this reason it is important to understand the growth mechanism of 1D semiconducting nanostructures. This is also important to understand the compatibility of NW growth steps and tools used in the process with these unconventional substrates such as plastic that are used in flexible and large area electronics. Therefore, this Element presents at length discussion about the growth mechanisms, growth conditions and the tools used for the synthesis of NWs. Although NWs from Si, ZnO and carbon nanotubes (CNTs) are included, the discussion is generic and relevant to several other types of NWs as well as heterostructures.


Ceramic Coatings

Ceramic Coatings

Author: Feng Shi

Publisher: BoD – Books on Demand

Published: 2012-02-24

Total Pages: 300

ISBN-13: 9535100831

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The main target of this book is to state the latest advancement in ceramic coatings technology in various industrial fields. The book includes topics related to the applications of ceramic coating covers in enginnering, including fabrication route (electrophoretic deposition and physical deposition) and applications in turbine parts, internal combustion engine, pigment, foundry, etc.