Nano-(Bio)Catalysis in Lignocellulosic Biomass Valorization
Nano-(Bio)Catalysis in Lignocellulosic Biomass Valorization

Author: Rafael Luque

Publisher: Frontiers Media SA

Published: 2019-03-01

Total Pages: 170

ISBN-13: 2889457729

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The valorization of lignocellulosic biomass, in the form of forest and agricultural wastes, industrial processing side-streams, and dedicated energy crops, toward chemicals, fuels and added-value products has become a major research area with increasing exploitation potential. The efficient and tailored depolymerization of biomass or its primary structural components (hemicellulose, cellulose, and lignin) to platform chemicals, i.e., sugars, phenolics, furans, ketones, organic acids, etc. is highly dependent on the development of novel or modified chemo- and bio-catalytic processes that take into account the peculiarities and recalcitrance of biomass as feedstock, compared for example to petroleum fractions. The present Research Topic in Frontiers in Chemistry, Section of Green and Sustainable Chemistry, entitled “Nano-(bio)catalysis in lignocellulosic biomass valorization” aims to further contribute to the momentum of research and development in the (bio)catalytic conversion of biomass, by featuring original research papers as well as two review papers, authored and reviewed by experts in the field. The Research Topic addresses various representative reactions and processes in biomass valorization, highlighting the importance of developing novel, efficient and stable nano-(bio)catalysts with tailored properties according to the nature of the reactant/feedstock and the targeted products.

Advanced Functional Solid Catalysts for Biomass Valorization
Advanced Functional Solid Catalysts for Biomass Valorization

Author: Chaudhery Mustansar Hussain

Publisher: Elsevier

Published: 2020-05-29

Total Pages: 276

ISBN-13: 0128226730

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Advanced Functional Solid Catalysts for Biomass Valorization presents the basic concepts in catalysis (homogeneous, heterogeneous, and enzymatic) and the properties of various kinds of heterogeneous solid catalysts, including their structure, porosity, particle size, BET surface area, acid-base, and redox properties. Useful information about biorefineries, types of biomass feedstocks, their structures and properties as well as about several potential catalytic routes for biomass upgrading to useful fuels and chemicals is provided in this book. Importantly, this book covers the most recent developments toward functionalization of various solid catalysts, optimization of catalysts’ properties, developing cascade catalytic strategies, exploring reaction kinetics/mechanisms, and evaluating catalysts’ stability/reusability during biomass upgrading. Current challenges and opportunities for the future biorefineries as well as for the design of advanced functional solid catalysts are critically discussed. Describes catalysis as a promising technology for the development of eco-friendly and economically viable strategies for several important energy and environmental applications. Covers heterogeneous solid catalysts because of their versatile benefits in terms of catalysts’ synthesis, production cost, stability, and reusability as compared to homogeneous liquid catalysts. Provides promising strategies for the design of new catalytic materials, such as carbon materials, metal–organic frameworks, zeolites, and mesoporous silicas. Describes functional solid catalysts for developing one-pot cascade processes for efficient biomass valorization and other vital chemical transformations.

Nanomaterials for Biocatalysis
Nanomaterials for Biocatalysis

Author: Guillermo R. Castro

Publisher: Elsevier

Published: 2021-10-12

Total Pages: 755

ISBN-13: 0128244372

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Nanomaterials for Biocatalysis explains the fundamental design concepts and emerging applications of nanoscale biocatalysts, such as bioconversions, bioelectronics, biosensors, biocomputing and therapeutic applications. Nano-biocatalysts refers to the incorporation of enzymes into nanomaterials. These enzyme-enhanced nanocarriers have many advantages, including low mass transfer limitation, high enzyme capacity, better stabilization, and the formation of single-enzyme nanoparticles. Smart nanocontainers have been developed for the smart release of their embedded active substances. These smart releases can be obtained by using smart coatings as their outer nanoshells. In addition, these nanocontainers could protect the enzymes from chemical or metabolic alterations on their delivering pathways towards the target. This is an important reference source for materials scientists and chemical engineers who want to know more about how nanomaterials are being used for biocatalysis applications. Explains the major fabrication techniques and applications of nanobiocatalysts Shows how nanobiocatalysts are used in a variety of environmental and biomedical sectors Assesses the major challenges associated with the widespread manufacture of nanobiocatalysts

Biocatalysis and Nanotechnology
Biocatalysis and Nanotechnology

Author: Peter Grunwald

Publisher: CRC Press

Published: 2017-10-25

Total Pages: 836

ISBN-13: 1351767550

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Nanobiocatalysis has rapidly developed into a subarea of enzyme biotechnology. It combines the advances in nanotechnology that have generated nanoscale materials of different sizes, shapes, and physicochemical properties, and the excellent characteristics of biocatalysts into an innovative technology. This book provides an overview of the various relations between nanotechnology and biocatalysis. It discusses the fabrication and application of nanomaterials for the immobilization of enzymes used in the sustainable production of goods and chemicals. Nanosupports have several advantages compared with bulk solid materials because of their high surface area, which results in a significantly reduced mass transfer limitation and comparatively high enzyme loading. These characteristics are also of great use for applications in the fields of enzymatic biosensors, biofuel cells, bioelectronics, and photoelectrochemical analyte detection, where conductive nanomaterials improve the rate of electron transfer. The book also presents an overview of nanotoxicology and covers nanostructured enzyme catalysis in organic solvents and its potential application for biodiesel production, probing of enzymatic activity, and identification of enzyme functions of inorganic nanoparticles as enzyme mimics.

Lignocellulose for Future Bioeconomy
Lignocellulose for Future Bioeconomy

Author: Hidayah Ariffin

Publisher: Elsevier

Published: 2019-04-20

Total Pages: 360

ISBN-13: 0128166053

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Lignocellulose for Future Bioeconomy discusses the conversion and utilization of lignocellulosic biomass. This book focuses on the utilization of lignocelluloses for various products, including biopolymers, bionanomaterials and bioproducts. Recent findings in scientific investigation, engineering, product development, economic and lifecycle analysis are discussed, as are current synthesis technologies and potential applications. The book progresses from a discussion of the potential sources of biomass, to the refinement and processing of materials. A sampling of various sustainability issues faced by industries in their production methods and a look at real world examples of the use of lignocellulose-based materials in the bioeconomy round out the discussion. Presents information on lignocellulosic biomass management and its utilization for the production of bioproducts, biopolymers and bionanomaterials Highlights the applications of advanced materials developed from lignocellulosic biomass and their contribution towards future bioeconomy Discusses the lifecycle of lignocellulosic biomass

Biomass Valorization
Biomass Valorization

Author: Davide Ravelli

Publisher: John Wiley & Sons

Published: 2021-05-24

Total Pages: 434

ISBN-13: 3527825037

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Explore the potential of biomass-based chemicals with this comprehensive new reference from leading voices in the field With the depletion of fossil raw materials a readily ascertainable inevitability, the exploitation of biomass-based renewable derivatives becomes ever more practical and realistic. In Biomass Valorization: Sustainable Methods for the Production of Chemicals, accomplished researchers and authors Davide Ravelli and Chiara Samori deliver a thorough compilation of state-of-the-art techniques and most advanced strategies used to convert biomass into useful building blocks and commodity chemicals. Each chapter in this collection of insightful papers begins by detailing the core components of the described technology, along with a fulsome description of its advantages and limitations, before moving on to a discussion of recent advancements in the field. The discussions are grouped by the processed biomass, such as terrestrial biomass, aquatic biomass, and biomass-deriving waste. Readers will also benefit from the inclusion of: A thorough introduction to the role of biomass in the production of chemicals An exploration of biomass processing via acid, base and metal catalysis, as well as biocatalysis A practical discussion of biomass processing via pyrolysis and thermochemical-biological hybrid processes A concise treatment of biomass processing assisted by ultrasound and via electrochemical, photochemical and mechanochemical means Perfect for chemical engineers, catalytic chemists, biotechnologists, and polymer chemists, Biomass Valorization: Sustainable Methods for the Production of Chemicals will also earn a place in the libraries of environmental chemists and professionals working with organometallics and natural products chemists.

Reaction Pathways and Mechanisms in Thermocatalytic Biomass Conversion I
Reaction Pathways and Mechanisms in Thermocatalytic Biomass Conversion I

Author: Marcel Schlaf

Publisher: Springer

Published: 2015-09-25

Total Pages: 268

ISBN-13: 981287688X

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Volume I mainly focuses on the current understanding of the reaction pathways and mechanisms involved in several important catalytic conversions of cellulose and carbohydrates. It starts with nanoscale illustrations of biomass structures and describes various reactions including cellulose depolymerization to sugars, catalytic aldose-ketose isomerization and dehydration, selective oxidation, hydrogenolysis of cellulose and sugars, and the conversion of short carbohydrates. The specificity and function of different catalysts and reaction media in relation to the catalytic performances for these reactions are discussed with significant mechanistic details. Marcel Schlaf, PhD, is a Professor at the Department of Chemistry, University of Guelph, Canada. Z. Conrad Zhang, PhD, is a Professor at the Dalian Institute of Chemical Physics, Chinese Academy of Sciences, China.

Producing Fuels and Fine Chemicals from Biomass Using Nanomaterials
Producing Fuels and Fine Chemicals from Biomass Using Nanomaterials

Author: Rafael Luque

Publisher: CRC Press

Published: 2013-10-28

Total Pages: 328

ISBN-13: 1466553405

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Scarcity of resources and increasing population and energy demands are important issues of the twenty-first century. A multidisciplinary approach is needed to produce suitable alternatives-such as renewable resources-for a more sustainable future. One of the most promising and widely available renewable feedstocks is biomass, which has significant

Nanotechnology in Catalysis, 3 Volumes
Nanotechnology in Catalysis, 3 Volumes

Author: Bert F. Sels

Publisher: John Wiley & Sons

Published: 2017-10-16

Total Pages: 1180

ISBN-13: 3527339140

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Dieses Handbuch präsentiert die in den letzten zehn Jahren entstandenen neuen Anwendungsbereiche und gibt einen umfassenden Überblick über dieses wissenschaftlich und ökonomisch wichtige Gebiet. Einzigartig ist die Verbindung von Grundlagenforschung und industrieller Entwicklung.