This book discusses the technical alternatives for cleanup of radioactive fluoride salts that were the fuel for the Molten Salt Reactor Experiment, a novel nuclear reactor design that was tested in the 1960s at the Oak Ridge National Laboratory in Tennessee. These fluoride salts pose an unusual cleanup challenge. The book discusses alternatives for processing and removing the salts based on present knowledge of fluoride salt chemistry and nuclear reactions of the radioactive constituents.
This book discusses the technical alternatives for cleanup of radioactive fluoride salts that were the fuel for the Molten Salt Reactor Experiment, a novel nuclear reactor design that was tested in the 1960s at the Oak Ridge National Laboratory in Tennessee. These fluoride salts pose an unusual cleanup challenge. The book discusses alternatives for processing and removing the salts based on present knowledge of fluoride salt chemistry and nuclear reactions of the radioactive constituents.
The chemistry of molten fluorides is traced from their development as fuels in the Molten Salt Reactor Experiment with important factors in their selection being discussed. Key chemical characteristics such as solubility, redox behavior, and chemical activity are explained as they relate to the behavior of molten fluoride fuel systems. Fission product behavior is described along with processing experience. Development requirements for fitting the current state of the chemistry to modern nuclear fuel system are described. It is concluded that while much is known about molten fluoride behavior, processing and recycle of the fuel components is a necessary factor if future systems are to be established.
Molten Salt Reactors and Thorium Energy, Second Edition is a fully updated comprehensive reference on the latest advances in MSR research and technology. Building on the successful first edition, Tom Dolan and the team of experts have fully updated the content to reflect the impressive advances from the last 5 years, ensuring this book continues to be the go-to reference on the topic. This new edition covers progress made in MSR design, details innovative experiments, and includes molten salt data, corrosion studies and deployment plans. The successful case studies section of the first edition have been removed, expanded, and fully updated, and are now published in a companion title called Global Case Studies on Molten Salt Reactors. Readers will gain a deep understanding of the advantages and challenges of MSR development and thorium fuel use, as well as step-by-step guidance on the latest in MSR reactor design. Each chapter provides a clear introduction, covers technical issues and includes examples and conclusions, while promoting the sustainability benefits throughout. A fully updated comprehensive handbook on Molten Salt Reactors and Thorium Energy, written by a team of global experts Covers MSR applications, technical issues, reactor types and reactor designs Includes 3 brand new chapters which reflect the latest advances in research and technology since the first edition published Presents case studies on molten salt reactors which aid in the transition to net zero by providing abundant clean, safe energy to complement wind and solar powe
Molten salts and fused media provide the key properties and the theory of molten salts, as well as aspects of fused salts chemistry, helping you generate new ideas and applications for fused salts. Molten Salts Chemistry: From Lab to Applications examines how the electrical and thermal properties of molten salts, and generally low vapour pressure are well adapted to high temperature chemistry, enabling fast reaction rates. It also explains how their ability to dissolve many inorganic compounds such as oxides, nitrides, carbides and other salts make molten salts ideal as solvents in electrometallurgy, metal coating, treatment of by-products and energy conversion. This book also reviews newer applications of molten salts including materials for energy storage such as carbon nano-particles for efficient super capacitors, high capacity molten salt batteries and for heat transport and storage in solar plants. In addition, owing to their high thermal stability, they are considered as ideal candidates for the development of safer nuclear reactors and for the treatment of nuclear waste, especially to separate actinides from lanthanides by electrorefining.
Molten salts and fused media provide the key properties and the theory of molten salts, as well as aspects of fused salts chemistry, helping you generate new ideas and applications for fused salts.Molten Salts Chemistry: From Lab to Applications examines how the electrical and thermal properties of molten salts, and generally low vapour pressure are well adapted to high temperature chemistry, enabling fast reaction rates. It also explains how their ability to dissolve many inorganic compounds such as oxides, nitrides, carbides and other salts make molten salts ideal as solvents in electrometallurgy, metal coating, treatment of by-products and energy conversion.This book also reviews newer applications of molten salts including materials for energy storage such as carbon nano-particles for efficient super capacitors, high capacity molten salt batteries and for heat transport and storage in solar plants. In addition, owing to their high thermal stability, they are considered as ideal candidates for the development of safer nuclear reactors and for the treatment of nuclear waste, especially to separate actinides from lanthanides by electrorefining. Explains the theory and properties of molten salts to help scientists understand these unique liquids Provides an ideal introduction to this expanding field Illustrated text with key real-life applications of molten salts in synthesis, energy, nuclear, and metal extraction
