This book is based on the George Fisher Baker Lecture given by Jean-Michel Savéant at Cornell University in Fall 2002. * The first book focusing on molecular electrochemistry * Relates to other fields, including photochemistry and biochemistry * Outlines clearly the connection between concepts, experimental illustrations, proofs and supporting methods * Appendixes to provide rigorous demonstrations to prevent an overload of algebra in the main text * Applications-oriented, focused on analyzing the results obtained rather than the methodology
Dieses Fachbuch, geschrieben von zwei weltweit führenden Koryphäen auf dem Gebiet der Elektrochemie, beschreibt detailliert die zentralen elektrochemischen Reaktionen, die als Grundlage für die heutige Erforschung alternativer Energielösungen dienen. - Bietet eine zugängliche und gut lesbare Zusammenfassung zu elektrochemischen Verfahren und der Anwendung elektrochemischer Konzepte bei funktionalen Systemen auf Molekularebene. - Enthält ein neues Kapitel zu dem protonengekoppelten Elektronentransfer, ein vollständig überarbeitetes Kapitel zur molekularen Katalyse bei elektrochemischen Reaktionen sowie durchgängig neue Abschnitte. - Stellt die Verbindung zwischen der Elektrochemie, der Molekular- und Biomolekularchemie her und stärkt deren Zusammenspiel, indem eine Vielzahl von Funktionen präsentiert werden, die sich mit Multi-Komponenten-Systemen und Paradigmen aus beiden Bereichen der Chemie erreichen lassen.
Dieses Fachbuch, geschrieben von zwei weltweit führenden Koryphäen auf dem Gebiet der Elektrochemie, beschreibt detailliert die zentralen elektrochemischen Reaktionen, die als Grundlage für die heutige Erforschung alternativer Energielösungen dienen. - Bietet eine zugängliche und gut lesbare Zusammenfassung zu elektrochemischen Verfahren und der Anwendung elektrochemischer Konzepte bei funktionalen Systemen auf Molekularebene. - Enthält ein neues Kapitel zu dem protonengekoppelten Elektronentransfer, ein vollständig überarbeitetes Kapitel zur molekularen Katalyse bei elektrochemischen Reaktionen sowie durchgängig neue Abschnitte. - Stellt die Verbindung zwischen der Elektrochemie, der Molekular- und Biomolekularchemie her und stärkt deren Zusammenspiel, indem eine Vielzahl von Funktionen präsentiert werden, die sich mit Multi-Komponenten-Systemen und Paradigmen aus beiden Bereichen der Chemie erreichen lassen.
Using electrochemical impedance spectroscopy in a broad range of applications This book provides the background and training suitable for application of impedance spectroscopy to varied applications, such as corrosion, biomedical devices, semiconductors and solid-state devices, sensors, batteries, fuel cells, electrochemical capacitors, dielectric measurements, coatings, electrochromic materials, analytical chemistry, and imaging. The emphasis is on generally applicable fundamentals rather than on detailed treatment of applications. With numerous illustrative examples showing how these principles are applied to common impedance problems, Electrochemical Impedance Spectroscopy is ideal either for course study or for independent self-study, covering: Essential background, including complex variables, differential equations, statistics, electrical circuits, electrochemistry, and instrumentation Experimental techniques, including methods used to measure impedance and other transfer functions Process models, demonstrating how deterministic models of impedance response can be developed from physical and kinetic descriptions Interpretation strategies, describing methods of interpretating of impedance data, ranging from graphical methods to complex nonlinear regression Error structure, providing a conceptual understanding of stochastic, bias, and fitting errors in frequency-domain measurements An overview that provides a philosophy for electrochemical impedance spectroscopy that integrates experimental observation, model development, and error analysis This is an excellent textbook for graduate students in electrochemistry, materials science, and chemical engineering. It's also a great self-study guide and reference for scientists and engineers who work with electrochemistry, corrosion, and electrochemical technology, including those in the biomedical field, and for users and vendors of impedance-measuring instrumentation.
Showing how to apply the theoretical knowledge in practice, the one and only compilation of electrochemical experiments on the market now in a new edition. Maintaining its didactic approach, this successful textbook provides clear and easy-to-follow instructions for carrying out the experiments, illustrating the most important principles and applications in modern electrochemistry, while pointing out the potential dangers and risks involved. This second edition contains 84 experiments, many of which cover electrochemical energy conversion and storage as well as electrochemical equilibrium.
Offering a thorough explanation of electrode kinetics, this textbook emphasizes physical phenomena - rather than mathematical formalism - and elucidates the underlying principles of the different experimental techniques. Assuming an elementary knowledge of thermodynamics and chemical kinetics and minimal mathematical skills, coverage explores the arguments of two primary schools of thought: electrode kinetics and interfacial electrochemistry viewed as a branch of physical chemistry and from the perspective of analytical chemistry.
Long-awaited on the importance of halogen bonding in solution, demonstrating the specific advantages in various fields - from synthesis and catalysis to biochemistry and electrochemistry! Halogen bonding (XB) describes the interaction between an electron donor and the electrophilic region of a halogen atom. Its applicability for molecular recognition processes long remained unappreciated and has mostly been studied in solid state until recently. As most physiological processes and chemical reactions take place in solution, investigations in solutions are of highest relevance for its use in organic synthesis and catalysis, pharmaceutical chemistry and drug design, electrochemistry, as well as material synthesis. Halogen Bonding in Solution gives a concise overview of halogen bond interactions in solution. It discusses the history and electronic origin of halogen bonding and summarizes all relevant examples of its application in organocatalysis. It describes the use of molecular iodine in catalysis and industrial applications, as well as recent developments in anion transport and binding. Hot topic: Halogen bonding is an important interaction between molecules or within a molecule. The field has developed considerably in recent years, with numerous different approaches and applications having been published. Unique: There are several books on halogen bonding in solid state available, but this will be the first one focused on halogen bonding in solution. Multi-disciplinary: Summarizes the history and nature of halogen bonding in solution as well as applications in catalysis, anion recognition, biochemistry, and electrochemistry. Aimed at facilitating exciting future developments in the field, Halogen Bonding in Solution is a valuable source of information for researchers and professionals working in the field of supramolecular chemistry, catalysis, biochemistry, drug design, and electrochemistry.
Electrochemistry theme is a component of Encyclopedia of Physical Sciences, Engineering and Technology Resources in the global Encyclopedia of Life Support Systems (EOLSS), which is an integrated compendium of twenty one Encyclopedias. Electrochemistry is the science that studies the properties and chemical transformations of/within ionic conductors (most commonly a solution of a salt) and at the interface between an ionic conductor and an electronic conductor (most commonly a metal) or semiconductor. Electrochemistry is present in many aspects of our everyday life. Probably, batteries are the most common example. However, electrochemistry is also present in many other aspects of vital importance in the chemical industry, like chlorine, caustic soda and aluminum (and many others not described here) are produced through electrochemical processes. This volume is aimed at the following five major target audiences: University and College students Educators, Professional practitioners, Research personnel and Policy analysts, managers, and decision makers and NGOs
Atomic-Scale Modelling of Electrochemical Systems A comprehensive overview of atomistic computational electrochemistry, discussing methods, implementation, and state-of-the-art applications in the field The first book to review state-of-the-art computational and theoretical methods for modelling, understanding, and predicting the properties of electrochemical interfaces. This book presents a detailed description of the current methods, their background, limitations, and use for addressing the electrochemical interface and reactions. It also highlights several applications in electrocatalysis and electrochemistry. Atomic-Scale Modelling of Electrochemical Systems discusses different ways of including the electrode potential in the computational setup and fixed potential calculations within the framework of grand canonical density functional theory. It examines classical and quantum mechanical models for the solid-liquid interface and formation of an electrochemical double-layer using molecular dynamics and/or continuum descriptions. A thermodynamic description of the interface and reactions taking place at the interface as a function of the electrode potential is provided, as are novel ways to describe rates of heterogeneous electron transfer, proton-coupled electron transfer, and other electrocatalytic reactions. The book also covers multiscale modelling, where atomic level information is used for predicting experimental observables to enable direct comparison with experiments, to rationalize experimental results, and to predict the following electrochemical performance. Uniquely explains how to understand, predict, and optimize the properties and reactivity of electrochemical interfaces starting from the atomic scale Uses an engaging “tutorial style” presentation, highlighting a solid physicochemical background, computational implementation, and applications for different methods, including merits and limitations Bridges the gap between experimental electrochemistry and computational atomistic modelling Written by a team of experts within the field of computational electrochemistry and the wider computational condensed matter community, this book serves as an introduction to the subject for readers entering the field of atom-level electrochemical modeling, while also serving as an invaluable reference for advanced practitioners already working in the field.
An excellent resource for all graduate students and researchers using electrochemical techniques. After introducing the reader to the fundamentals, the book focuses on the latest developments in the techniques and applications in this field. This second edition contains new material on environmentally-friendly solvents, such as room-temperature ionic liquids.
