This book describes the work performed to develop a new test methodology to characterise the susceptibility of stainless steels to crevice corrosion in natural and treated seawaters. It also describes the experimental procedures to perform crevice corrosion testing.
Crevice corrosion in chloride-containing environments, particularly sea water, poses a serious threat to the integrity of stainless steels and has been responsible for many failures. The need for a reliable test method to measure the susceptibility of passive metals to crevice corrosion in sea water has been addressed recently in a major European Programme, CREVCORR. This work was coordinated by Bard Espelid of DNV (Norway) and involved collaboration between ten different companies in six European countries. Many members of EFC Working Party 9 (Marine Corrosion) participated in the work. The first nine chapters of the book describe the development of the new crevice corrosion test method for plate and tubular materials and its application to a number of austenitic, ferritic and duplex stainless steels. A key aim was to develop a crevice corrosion test procedure where the biological activity and oxidation capacity of natural and treated sea waters are simulated electrochemically. Another important aspect of the work was to formulate a new synthetic sea water capable of simulating the corrosiveness of natural and treated sea waters, including the effects of the bio-films that can form in natural waters. The final chapter presents the results of two large collaborative test programmes involving a total of 19 laboratories in eight countries worldwide. These involved tests in natural and synthetic sea waters to evaluate the new crevice test and synthetic sea water. The book will be of value to scientists and engineers engaged in the selection of stainless steels for applications in sea water and other chlorinated natural environments.
This first edition of Testing Tribocorrosion of Passivating Materials Supporting Research and Industrial Innovation: A Handbook treats in a clear, concise, and practical manner an important material degradation and protection matter. It is designed as a handbook and provides a well structured approach of the basics needed to investigate the tribocorrosion behavior of passivating materials, and to conduct in a correct way a laboratory investigation on it. It provides answers on practical and theoretical approaches of tribocorrosion phenomena to engineers and medical persons involved with material assemblies subjected to aggressive environmental and mechanical conditions. For academic researchers it is a pertinent tool assisting them in how they can perform a tribocorrosion investigation and obtain results that are correctly interpreted and can be exchanged. Different parts of the book are illustrated with practical examples. This handbook is truly an indispensable guide for every professional who comes into contact with the complex material degradation and protection processes that take place under combined corrosion and wear conditions. Fields of interest include: transportation (aeronautics, maritime, rail, automotive), medical implants (orthopaedics, dentistry), biochemistry, food production, energy production, and machining. The coordination of this handbook writing was done by Professor Jean-Pierre Celis (Katholieke Universiteit Leuven, Belgium) and Professor Pierre Ponthiaux (Ecole Centrale Paris, France) assisted by twelve European experts who contributed jointly to the nine chapters of this handbook. Main topics dealt with are tribocorrosion phenomena in medical and industrial sectors, depassivation and repassivation phenomena, impact on synergism in tribocorrosion, specific testing techniques, coupling tribology-to-corrosion, design of a testing protocol, and normalisation.
Engineering Tools for Corrosion: Design and Diagnosis proposes models and equations derived from theory. It includes discussions of the estimation of main corrosion parameters for corrosion rate, electrochemical constraints, thresholds limits and initiation time. The algorithms proposed are the conjugation of theory and engineering practice resulting from research and professional activities carried out by the author for almost four decades. - Presents a rational approach to the corrosion prediction and evaluation dilemma - Illustrates new models and algorithms for quantitative estimation of corrosion related factors and parameters - Includes the design and interpretation of accelerated corrosion tests
This special issue of Corrosion Engineering Science and Technology is dedicated to the study of corrosion of objects from historical sites. The issue contains contributions from the 2009 EUROCORR session on Corrosion of Archaeological and Heritage Artefacts organised by the European Federation of Corrosion's working party and commissioned articles on other key issues. The objective is to give the reader a broad understanding of corrosion of ancient materials, for the most part metal but also glass. Articles shed light on a range of analytical approaches related to the study of the complex systems that make up historical artifacts. In order to arrive at an understanding of the nanometric organisation of rust layers and interphases, such studies must be approached on a macroscopic scale. Techniques used include; macrophotography, synchrotron radiation and transmission electron microscopy (TEM) that ensure results that are both exhaustive and representative of particular observations. This issue demonstrates the wealth of approaches possible in the study of the corrosion of ancient materials.
Corrosion-under-insulation (CUI) refers to the external corrosion of piping and vessels that occurs underneath externally clad/jacketed insulation as a result of the penetration of water. By its very nature CUI tends to remain undetected until the insulation and cladding/jacketing is removed to allow inspection or when leaks occur. CUI is a common problem shared by the refining, petrochemical, power, industrial, onshore and offshore industries. In the first edition of this book published in 2008, the EFC Working Parties WP13 and WP15 engaged together to provide guidelines on managing CUI with contributions from a number of European refining, petrochemical and offshore companies. The guidelines are intended for use on all plants and installation that contain insulated vessels, piping and equipment. The guidelines cover a risk-based inspection methodology for CUI, inspection techniques and recommended best practice for mitigating CUI, including design of plant and equipment, coatings and the use of thermal spray techniques, types of insulation, cladding/jacketing materials and protection guards. The guidelines also include case studies. The original document first published in 2008 was very successful and provided an important resource in the continuing battle to mitigate CUI. Many members of the EFC corrosion community requested an update and this has taken between 18-24 months to do so. Hopefully this revised document will continue to serve the community providing a practical source of information on how to monitor and manage insulated systems. Revised and fully updated technical guidance on managing CUI provided by EFC Working Parties WP13 and WP 15 Contributions from a number of European refining, petrochemical and offshore companies Extensive appendices that provide additional practical guidance on the implementation of corrosion-under-insulation best practice, collected practical expertise and case studies
The conservation of metallic archaeological and historic artefacts is a major challenge whether they are ancient bronzes or relics of our more recent industrial past. Based on the work of Working Party 21 Corrosion of Archaeological and Historical Artefacts within the European Federation of Corrosion (EFC), this important book summarises key recent research on analytical techniques, understanding corrosion processes and preventing the corrosion of cultural heritage metallic artefacts.After an introductory part on some of the key issues in this area, part two reviews the range of analytical techniques for measuring and analysing corrosion processes, including time resolved spectroelectrochemistry, voltammetry and laser induced breakdown spectroscopy. Part three reviews different types of corrosion processes for a range of artefacts, whilst part four discusses on-site monitoring techniques. The final part of the book summaries a range of conservation techniques and strategies to conserve cultural heritage metallic artefacts.Corrosion and conservation of cultural heritage metallic artefacts is an important reference for all those involved in archaeology and conservation, including governments, museums as well as those undertaking research in archaeology and corrosion science. - Summarises key research on analytical techniques for measuring and analysing corrosion processes - Provides detailed understanding of corrosion processes and corrosion prevention - Discusses on-site monitoring techniques
Engineers with an interest in the marine environment can take advantage of many years of accumulated corrosion experience in a quick and concise manner with this publication. It covers the corrosion behavior in sea water of steel, stainless steel and cast iron as well as alloys of copper, aluminum, nickel and titanium. Applications, commonly-used alloy compositions and mechanical properties are also covered for each alloy system, plus a special section is devoted to galvanic corrosion and its avoidance.
Corrosion remains one of the key issues affecting the performance and availability of nuclear power plants. Therefore, reliable in-plant corrosion monitoring methods are essential both for the future operation of existing plants and to ensure the safety of future nuclear waste disposal systems. In two parts, this book was stimulated by a workshop organised by EFC Working Party 4 on Nuclear Corrosion and the European Cooperative Group on Corrosion Monitoring of Nuclear Materials (EGC-COMON). The first part deals mainly with research into the detection of stress corrosion crack initiation in nuclear power plant environments (essentially high temperature water at around 300 °C) by various methods, particularly the electrochemical noise technique but also including the electrochemical impedance, acoustic emission and direct current potential drop methods. The second part addresses the goal to develop in-situ techniques and includes examples of the application of electrochemical corrosion potential monitoring. This book will be of particular interest to scientists and engineers concerned with the mitigation of corrosion in nuclear systems.
First Published in 2017. Pipeline integrity is key to maintaining operational success, safety and security and minimising harm to the environment. Corrosion is a dominant contributory factor to failures, leaks and integrity threats in pipelines. Therefore, its optimum control within an integrity management framework is paramount for the cost-effective design of facilities and ensuring continued, uninterrupted and safe operations within the expected design life. This recommended practice (RP) is a compendium of current best practices and state-of-the-art knowledge by major operators, engineering contractors and service companies involved in hydrocarbon pro-duction and transportation. The RP incorporates some minimum operational requirements and practices to ensure that when man-aging corrosion in pipelines, fundamental principles are followed. It covers management of corrosion for pipelines carrying hydrocarbons, injection water and/or produced water from design to decommissioning. It is structured to follow the logical steps of a basic corrosion management process and makes references to relevant and available international standards and/or recommended practices. It is intended for use by personnel from the petroleum industry having knowledge of corrosion and materials. It is hoped that this RP will prove to be a key reference document for engineers, suppliers and con-tractors working in the oil and gas industry, paving the way for corrosion-free operation of pipelines with the ultimate goal of improving safety, security and minimising the impact on the environment