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Author: Qi Shao
Publisher: John Wiley & Sons
Published: 2024-08-26
Total Pages: 245
ISBN-13: 3527351051
DOWNLOAD EBOOKThis book summarizes an arising branch of materials, metastable materials, which are rarely discussed before and addresses their applications in catalytic reactions.
Author: Pablo G. Debenedetti
Publisher: Princeton University Press
Published: 1996
Total Pages: 432
ISBN-13: 9780691085951
DOWNLOAD EBOOKBuilding on the interplay of kinetics and thermodynamics that determines the thermophysical properties and structural relaxation of metastable liquids, it offers an in-depth treatment of thermodynamic stability theory, the statistical mechanics of metastability, nucleation, spinodal decomposition, supercooled liquids, and the glass transition.
Author: Stephen Z.D. Cheng
Publisher: Elsevier
Published: 2008-09-10
Total Pages: 325
ISBN-13: 0080558208
DOWNLOAD EBOOKA classical metastable state possesses a local free energy minimum at infinite sizes, but not a global one. This concept is phase size independent. We have studied a number of experimental results and proposed a new concept that there exists a wide range of metastable states in polymers on different length scales where their metastability is critically determined by the phase size and dimensionality. Metastable states are also observed in phase transformations that are kinetically impeded on the pathway to thermodynamic equilibrium. This was illustrated in structural and morphological investigations of crystallization and mesophase transitions, liquid-liquid phase separation, vitrification and gel formation, as well as combinations of these transformation processes. The phase behaviours in polymers are thus dominated by interlinks of metastable states on different length scales. This concept successfully explains many experimental observations and provides a new way to connect different aspects of polymer physics.* Written by a leading scholar and industry expert* Presents new and cutting edge material encouraging innovation and future research* Connects hot topics and leading research in one concise volume
Author: Eugene Machlin
Publisher: Elsevier
Published: 2010-07-07
Total Pages: 478
ISBN-13: 0080549683
DOWNLOAD EBOOKThis book is based on a set of notes developed over many years for an introductory course taught to seniors and entering graduate students in materials science. An Introduction to Aspects of Thermodynamics and Kinetics Relevant to Materials Science is about the application of thermodynamics and kinetics to solve problems within Materials Science. Emphasis is to provide a physical understanding of the phenomenon under discussion, with the mathematics presented as a guide. The problems are used to provide practice in quantitative application of principles, and also to give examples of applications of the general subject matter to problems having current interest and to emphasize the important physical concepts. End of chapter problems are included, as are references, and bibliography to reinforce the text. This book provides students with the theory and mathematics to understand the important physical understanding of phenomena. - Based on a set of notes developed over many years for an introductory course taught to seniors and entering graduate students in materials science - Provides students with the theory and mathematics to understand the important physical understanding of phenomena - Includes end of chapter problems, references, and bibliography to reinforce the text
Author: E. Yu Tonkov
Publisher: CRC Press
Published: 2018-10-08
Total Pages: 390
ISBN-13: 1420037609
DOWNLOAD EBOOKAs laboratories replace heavy hydraulic presses and bulky high-pressure chambers with miniature diamond anvils, traditional heaters with laser heating, and continue to improve methods of shock compression, there has been considerable new data obtained from the high-pressure, high-temperature modification of pure elements. The dense metallic modification of elements shows the potential for achieving superconductivity akin to theoretical predictions. Phase Transformations of Elements Under High Pressure contains the latest theoretical and experimental information on nearly 100 elements, including first-and second-phase transitions, melting lines, crystal structures of stable and metastable phases, stability of polymorphic modifications, and other useful properties and data. It emphasizes features such as changes in the liquid state, amorphization, and metallization, and provides temperature-pressure diagrams for every element. The book also describes the transitions of polymeric forms of fullerene, crystal modifications of elements stable under high pressures, and provides data that confirms their superconducting and magnetic properties. This handbook will be a lasting reference for scientists in a broad range of disciplines, including solid-state physics, chemistry, crystallography, mineralogy, and materials science.
Author: Brent Fultz
Publisher: Cambridge University Press
Published: 2014-08-14
Total Pages: 589
ISBN-13: 1107067243
DOWNLOAD EBOOKA clear, concise and rigorous textbook covering phase transitions in the context of advances in electronic structure and statistical mechanics.
Author: J. W. Martin
Publisher: Cambridge University Press
Published: 1997-03-06
Total Pages: 450
ISBN-13: 9780521423168
DOWNLOAD EBOOKThe second edition of this textbook, popular amongst students and faculty alike, investigates the various causes of thermodynamic instability in metallic microstructures. Materials theoretically well designed for a particular application may prove inefficient or even useless unless stable under normal working conditions. The authors examine current experimental and theoretical understanding of the kinetics behind structural change in metals. The entire text has been updated in this new edition, and a completely new chapter on highly metastable alloys has been added. The degree to which kinetic stability of the material outweighs its thermodynamic instability is very important, and dictates the useful working life of the material. If the structure is initially produced to an optimum, such changes will degrade the properties of the material. This comprehensive and well-illustrated text, accompanied by ample references, will allow final year undergraduates, graduate students and research workers to investigate in detail the stability of microstructure in metallic systems.
Author: Bruno Predel
Publisher: Springer Science & Business Media
Published: 2013-03-09
Total Pages: 357
ISBN-13: 366209276X
DOWNLOAD EBOOKThis advanced comprehensive textbook introduces the practical application of phase diagrams to the thermodynamics of materials consisting of several phases. It describes the fundamental physics and thermodynamics as well as experimental methods, treating all material classes: metals, glasses, ceramics, polymers, organic materials, aqueous solutions. With many application examples and realistic cases from chemistry and materials science, it is intended for students and researchers in chemistry, metallurgy, mineralogy, and materials science as well as in engineering and physics. The authors treat the nucleation of phase transitions, the production and stability of technologically important metastable phases, and metallic glasses. Also concisely presented are the thermodynamics and composition of polymer systems. This innovative text puts this powerful analytical approach into a readily understandable and practical context, perhaps for the first time.
Author: David A. Porter
Publisher: CRC Press
Published: 1992-09-10
Total Pages: 532
ISBN-13: 9780748757411
DOWNLOAD EBOOKIn the decade since the first edition of this popular text was published, the metallurgical field has undergone rapid developments in many sectors. Nonetheless, the underlying principles governing these developments remain the same. A textbook that presents these advances within the context of the fundamentals is greatly needed by instructors in the field Phase Transformations in Metals and Alloys, Second Edition maintains the simplicity that undergraduate instructors and students have come to appreciate while updating and expanding coverage of recently developed methods and materials. The book is effectively divided into two parts. The beginning chapters contain the background material necessary for understanding phase transformations - thermodynamics, kinetics, diffusion theory and the structure and properties of interfaces. The following chapters deal with specific transformations - solidification, diffusional transformation in solids and diffusionless transformation. Case studies of engineering alloys are incorporated to provide a link between theory and practice. New additions include an extended list of further reading at the end of each chapter and a section containing complete solutions to all exercises in the book Designed for final year undergraduate and postgraduate students of metallurgy, materials science, or engineering materials, this is an ideal textbook for both students and instructors.
Author: Max Hansen
Publisher:
Published: 2000
Total Pages: 877
ISBN-13:
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