Handbook of Liquid Crystals, 8 Volume Set

Handbook of Liquid Crystals, 8 Volume Set

Author: John W. Goodby

Publisher: John Wiley & Sons

Published: 2014-04-14

Total Pages: 5240

ISBN-13: 3527327738

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Much more than a slight revision, this second edition of the successful "Handbook of Liquid Crystals" is completely restructured and streamlined, with updated as well as completely new topics, 100% more content and a new team of editors and authors. As such, it fills the gap for a definitive, single source reference for all those working in the field of organized fluids and will set the standard for the next decade. The Handbook's new structure facilitates navigation and combines the presentation of the content by topic and by liquid-crystal type: A fundamentals volume sets the stage for an understanding of the liquid crystal state of matter, while individual volumes cover the main types and forms, with a final volume bringing together the diverse liquid crystal phases through their applications. This unrivaled, all-embracing coverage represents the undiluted knowledge on liquid crystals, making the Handbook a must-have wherever liquid crystals are investigated, produced or used, and in institutions where their science and technology is taught. Also available electronically on Wiley Online Library, www.wileyonlinelibrary.com/ref/holc Volume 1: Fundamentals of Liquid Crystals Volume 2: Physical Properties and Phase Behavior of Liquid Crystals Volume 3: Nematic and Chiral Nematic Liquid Crystals Volume 4: Smectic and Columnar Liquid Crystals Volume 5: Non-Conventional Liquid Crystals Volume 6: Nanostructured and Amphiphilic Liquid Crystals Volume 7: Supermolecular and Polymeric Liquid Crystals Volume 8: Applications of Liquid Crystals


Light Scattering Near Phase Transitions

Light Scattering Near Phase Transitions

Author: H.Z. Cummins

Publisher: Elsevier

Published: 2012-12-02

Total Pages: 685

ISBN-13: 0444599851

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Since the development of the laser in the early 1960's, light scattering has played an increasingly crucial role in the investigation of many types of phase transitions and the published work in this field is now widely dispersed in a large number of books and journals.A comprehensive overview of contemporary theoretical and experimental research in this field is presented here. The reviews are written by authors who have actively contributed to the developments that have taken place in both Eastern and Western countries.


Light Scattering Studies of Dynamics of Bent-core Liquid Crystals

Light Scattering Studies of Dynamics of Bent-core Liquid Crystals

Author: Strahinja Stojadinovic

Publisher:

Published: 2005

Total Pages: 219

ISBN-13:

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Dynamical properties of the nematic and isotropic phase of several relatively new bent-core liquid crystals, as contrasted to conventional straight-core ("calamitic") liquid crystals, have been systematically studied by dynamic light scattering. Objective: Comparison of properties of bent-core nematics with straight-core nematics and search for a biaxial nematic phase due to the bent-core shape. Observations: Nematic phases are rather uncommon in bent-core compounds because nematic structure occurs only if the molecules can rotate relatively freely around their long axis, the condition apparently met in only a fraction of bent-core materials synthesized so far. The obtained results show that the elasticity to viscosity ratio for uniaxial bent-core nematics is typically two orders of magnitude lower than for straight-core nematics, due evidently to the large viscosity associated with optic axis distortions in the bent-core case. This result is independent of the normal mode of the director fluctuations probed. In one compound polarized light scattering data reveal fluctuations associated with the biaxial order parameter, occurring as a pretransitional effect on approach to the biaxial smectic-C phase. However, results on a homeotropically-aligned sample of another compound provide preliminary light scattering evidence for nematic biaxiality. Objective: To determine nature of isotropic to nematic phase transition and to measure dielectric fluctuations in the isotropic phase near the transition. Observations: The orientational order parameter fluctuations in the isotropic phase have been studied for the first time in bent-core compounds. Analogous to classic light scattering experiments performed on calamitic liquid crystals, fluctuations in nematic order in bent-core compounds exhibit a mean-field-like critical slowing down on approach to the isotropic-nematic transition from above. The fluctuations are intrinsically several orders of magnitude slower than for typical calamitics. In two related bent-core compounds, the transition is found to be weakly first-order, with the value of T NI -T* being ~3 times lower than the value typically obtained for calamitics. This reduction could be the effect of an enhanced density change at the I-N transition in the case of bent-core mesogens.


Light Scattering

Light Scattering

Author: Wyn Brown

Publisher: Clarendon Press

Published: 1996-05-16

Total Pages: 544

ISBN-13: 9780198517832

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This volume is a complementary, follow-up volume to the author's Dynamic Light Scattering published in 1993. Light scattering is a powerful and widely-used technique for studying macromolecular systems both in the pure state and in solution. It is applied variously on high-molecular-weight polymers, colloids and proteins as well as organized assemblies such as vesicular and micellar systems. Some major applications of the technique are to the study of phase transitions and critical phenomena. This book traces recent developments in light scattering and provides an extensive review of its applications which are of fundamental importance.


Light Scattering from Macromolecular Systems - Molecular Crystals and Polymers

Light Scattering from Macromolecular Systems - Molecular Crystals and Polymers

Author:

Publisher:

Published: 1981

Total Pages: 32

ISBN-13:

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The research objectives of this grant are to (1) characterize phase transitions theoretically and experimentally in molecular crystal systems, (2) use the above understanding gained by light scattering studies and theoretical interpretation to apply to the more complex system of lyotropic liquid crystals, and (3) knowledge gained on the model systems of increasing complexity is then applied to polymer liquid crystals and solid polymers as observed by laser light scattering techniques. Objective one has been definitely achieved as can be seen from the number of papers written in the last few years. Systems to have been experimentally and theoretically discussed are: trioxane, triazine, benzil, and chloranil. Others still to be investigated are: biphenyl, urea, thiourea, and hexamethyl benzene. Studies of lyotropic liquid crystals (sodium decyl sulfate, sodium sulfate, decanol, water) have been progressed to the point at which we will be reporting this data shortly. The major findings are: a number of phase transitions occur between 20 and 60 C; these transitions evidence strong critical behavior and long correlation times for fluctuations; and liquid crystals can be studied by light scattering in a unique and meaningful manner. Finally, some polymer studies were started which will be continued into the coming contract period. Spectra of solid powders, ribbons, and liquid crystals of PBT and solid PBO were obtained.