Fuel cells are attractive electrochemical energy converters featuring potentially very high thermodynamic efficiency factors. The focus of this volume of Advances in Chemical Engineering is on quantitative approaches, particularly based on chemical engineering principles, to analyze, control and optimize the steady state and dynamic behavior of low and high temperature fuel cells (PEMFC, DMFC, SOFC) to be applied in mobile and stationary systems. - Updates and informs the reader on the latest research findings using original reviews - Written by leading industry experts and scholars - Reviews and analyzes developments in the field
Direct Methanol Fuel Cell Technology presents the overall progress witnessed in the field of DMFC over the past decade, highlighting the components, materials, functions, properties and features, designs and configurations, operations, modelling, applications, pros and cons, social, political and market penetration, economics and future directions. The book discusses every single aspect of DMFC device technology, the associated advantages and drawbacks of state-of-the-art materials and design, market opportunities and commercialization aspects, and possible future directions of research and development. This book, containing critical analyses and opinions from experts around the world, will garner considerable interest among actual users/scientists/experts. - Analyzes developments of membrane electrolytes, electrodes, catalysts, catalyst supports, bipolar plates, gas diffusion layers and flow channels as critical components of direct methanol fuel cells - Includes modeling of direct methanol fuel cells to understand their scaling up potentials - Discusses commercial aspects of direct methanol fuel cells in terms of market penetration, end application, cost, viability, reliability, social and commercial perception, drawbacks and prospects
Direct Liquid Fuel Cells is a comprehensive overview of the fundamentals and specificities of the use of methanol, ethanol, glycerol, formic acid and formate, dimethyl ether, borohydride, hydrazine and other promising liquid fuels in fuel cells. Each chapter covers a different liquid fuel-based fuel cell such as: Anode catalysts of direct methanol fuel cells (DMFCs), future system designs and future trends for direct ethanol fuel cells (DEFCs), development of catalysts for direct glycerol fuel cells (DGFCs), the mechanisms of the reactions taking place at the anode and cathode electrodes, and the reported anode catalysts for direct formic acid fuel cell (DFAFC) and direct formate fuel cell (DFFC), characteristics of direct dimethyl ether fuel cell (DDMEFC), including its electrochemical and operating systems and design, the developments in direct borohydride fuel cells, the development of catalysts for direct hydrazine fuel cells (DHFCs), and also the uncommonly used liquids that have a potential for fuel cell applications including 2-propanol, ethylene glycol, ascorbic acid and ascorbate studied in the literature as well as utilization of some blended fuels. In each part, the most recent literature is reviewed and the state of the art is presented. It also includes examples of practical problems with solutions and a summarized comparison of performance, advantages, and limitations of each type of fuel cell discussed. Direct Liquid Fuel Cells is not a typical textbook but rather designed as a reference book of which any level of students (undergraduate or graduate), instructors, field specialists, industry and general audience, who benefit from current and complete understanding of the many aspects involved in the development and operation of these types of fuel cells, could make use of any chapter when necessary.
This book deals with an analysis of materials issues, status of technologies and potential applications of direct methanol fuel cells. The principle of operation of direct methanol fuel cells and the status of knowledge in the basic research areas are presented. The technology of direct methanol fuel cells is discussed in this book with particular regard to fabrication methodologies for the manufacturing of catalysts, electrolytes membrane-electrode assemblies, stack hardware and system design.
This volume contains an archival record of the NATO Advanced Institute on Mini – Micro Fuel Cells – Fundamental and Applications held in Çesme – Izmir, Turkey, July 22–August 3, 2007. The ASIs are intended to be a high-level teaching activity in scientific and technical areas of current concern. In this volume, the reader may find interesting chapters on Mini- Micro Fuel Cells with fundamentals and applications. In recent years, fu- cell development, modeling and performance analysis has received much attention due to their potential for distributed power which is a critical issue for energy security and the environmental protection. Small fuel cells for portable applications are important for the security. The portable devices (many electronic and wireless) operated by fuel cells for providing all-day power, are very valuable for the security, for defense and in the war against terrorism. Many companies in NATO and non-NATO countries have concentrated to promote the fuel cell industry. Many universities with industrial partners committed to the idea of working together to develop fuel cells. As tech- logy advanced in the 1980s and beyond, many government organizations joined in spending money on fuel-cell research. In recent years, interest in using fuel cells to power portable electronic devices and other small equipment (cell phones, mobile phones, lab-tops, they are used as micro power source in biological applications) has increased partly due to the promise of fuel cells having higher energy density.
The Encyclopedia of Electrochemical Power Sources is a truly interdisciplinary reference for those working with batteries, fuel cells, electrolyzers, supercapacitors, and photo-electrochemical cells. With a focus on the environmental and economic impact of electrochemical power sources, this five-volume work consolidates coverage of the field and serves as an entry point to the literature for professionals and students alike. Covers the main types of power sources, including their operating principles, systems, materials, and applications Serves as a primary source of information for electrochemists, materials scientists, energy technologists, and engineers Incorporates nearly 350 articles, with timely coverage of such topics as environmental and sustainability considerations
This book provides a comprehensive overview of methanol fuel. It reviews challenges and solutions in using methanol fuel in the transportation sector. Methanol is also used as the fuel in direct methanol fuel cells (DMFCs), and thus, the book reviews their working principles, performance, challenges, solutions, and applications. It also explores new developments in anode and cathode electrocatalysts, with an emphasis on nanostructured carbon support materials and their structure, electrochemical properties, and performance.
Direct Alcohol Fuel Cells: Materials, Performance, Durability and Applications begins with an introductory overview of direct alcohol fuel cells (DAFC); it focuses on the main goals and challenges in the areas of materials development, performance, and commercialization. The preparation and the properties of the anodic catalysts used for the oxidation of methanol, higher alcohols, and alcohol tolerant cathodes are then described. The membranes used as proton conductors in DAFC are examined, as well as alkaline membranes, focusing on the electrical conductivity and alcohol permeability. The use of different kinds of carbon materials as catalyst supports, gas diffusion layers, and current collectors in DAFC is also discussed. State of the art of the modeling is used to estimate performance and durability. The closing chapter reviews the use of DAFC in portable equipment and mobile devices and features a detailed discussion on the mechanisms of component degradation which limits their durability. This book is written to facilitate the understanding of DAFC technology, applications, and future challenges. It is an excellent introduction for electrochemical and material engineers interested in small fuel cells as portable energy sources, scientists focused on materials science for energy production and storage, as well as policy-makers in the area of renewable energies.
Fuel cells have been recognized to be destined to form the cornerstone of energy technologies in the twenty-first century. The rapid advances in fuel cell system development have left current information available only in scattered journals and Internet sites. Advances in Fuel Cells fills the information gap between regularly scheduled journals and university level textbooks by providing in-depth coverage over a broad scope. The present volume provides informative chapters on thermodynamic performance of fuel cells, macroscopic modeling of polymer-electrolyte membranes, the prospects for phosphonated polymers as proton-exchange fuel cell membranes, polymer electrolyte membranes for direct methanol fuel cells, materials for state of the art PEM fuel cells, and their suitability for operation above 100°C, analytical modelling of direct methanol fuel cells, and methanol reforming processes. - Includes contributions by leading experts working in both academic and industrial R&D - Disseminates the latest research discoveries - A valuable resource for senior undergraduates and graduate students, it provides in-depth coverage over a broad scope
This book covers all the proposed fuel cell systems including PEMFC, SOFC, PAFC, MCFC, regenerative fuel cells, direct alcohol fuel cells, and small fuel cells to replace batteries.
