The present work draws upon Diffusion and Defect Forum's 30-year project of summarizing recent progress in the fields of diffusion and defect research, by collating the relevant data which have been published during that time. The large number of studies of iron alloys reflects the great commercial importance of hydrogen embrittlement; an annoying phenomenon which has long plagued steel fabricators.
Many modern energy systems are reliant on the production, transportation, storage, and use of gaseous hydrogen. The safety, durability, performance and economic operation of these systems is challenged by operating-cycle dependent degradation by hydrogen of otherwise high performance materials. This important two-volume work provides a comprehensive and authoritative overview of the latest research into managing hydrogen embrittlement in energy technologies.Volume 2 is divided into three parts, part one looks at the mechanisms of hydrogen interactions with metals including chapters on the adsorption and trap-sensitive diffusion of hydrogen and its impact on deformation and fracture processes. Part two investigates modern methods of modelling hydrogen damage so as to predict material-cracking properties. The book ends with suggested future directions in science and engineering to manage the hydrogen embrittlement of high-performance metals in energy systems.With its distinguished editors and international team of expert contributors, Volume 2 of Gaseous hydrogen embrittlement of materials in energy technologies is an invaluable reference tool for engineers, designers, materials scientists, and solid mechanicians working with safety-critical components fabricated from high performance materials required to operate in severe environments based on hydrogen. Impacted technologies include aerospace, petrochemical refining, gas transmission, power generation and transportation. - Summarises the wealth of recent research on understanding and dealing with the safety, durability, performance and economic operation of using gaseous hydrogen at high pressure - Chapters review mechanisms of hydrogen embrittlement including absorption, diffusion and trapping of hydrogen in metals - Analyses ways of modelling hydrogen-induced damage and assessing service life
Diffusion in Solids: Recent Developments provides an overview of diffusion in crystalline solids. This book discusses the various aspects of the theory of diffusion. Organized into nine chapters, this volume starts with a discussion on the process of diffusion in solids. This book then examines the tools that supplement the conventional diffusion measurements, including electromigration, ionic conductivity, isotope effects, and vacancy wind effects. This text explores the molecular dynamic calculation by which the interatomic forces must be assumed. Other chapters discuss the method of measurement of the isotope effect on diffusion, which is the most powerful method of determining relevant information about the correlation factor. This volume extensively discusses diffusion in organic and amorphous materials, as well as interstitial diffusion in solids. The final chapter deals with ionic motion and diffusion in various groups of materials called fast ionic conductors. Solid-state physicists, materials scientists, physical chemists, and electrochemists will find this book extremely useful.
This book describes the central aspects of diffusion in solids, and goes on to provide easy access to important information about diffusion in metals, alloys, semiconductors, ion-conducting materials, glasses and nanomaterials. Coverage includes diffusion-controlled phenomena including ionic conduction, grain-boundary and dislocation pipe diffusion. This book will benefit graduate students in such disciplines as solid-state physics, physical metallurgy, materials science, and geophysics, as well as scientists in academic and industrial research laboratories.
Hydrogen in Steel: Effect of Hydrogen on Iron and Steel During Production, Fabrication, and Use focuses on the effect of hydrogen on iron and steel during production, fabrication, and use. Topics covered range from the solubility of hydrogen in iron and ferrous alloys to the diffusion and permeation of hydrogen through iron and steel. Electrochemical problems related to the ability of iron to absorb hydrogen from aqueous solutions are also considered. Comprised of 19 chapters, this book begins with a detailed treatment of the nature and properties of metal-hydrogen systems, paying particular attention to the behavior of hydrogen in the bulk of the metal phase and the mechanism of reactions between metals and hydrogen or hydrogen-producing compounds. The reader is then introduced to the solubility of hydrogen in iron and ferrous alloys as well as the nature of the final product of the hydrogen-iron interaction. Subsequent chapters deal with dimensional changes and stresses produced in steel by cathodically evolved hydrogen; the effects of hydrogen on the physical, mechanical, and chemical properties of iron and steel; influence of welding on hydrogen; and sulfide corrosion cracking of steel. The effects of pickling on steel are also examined, along with the blistering and embrittlement caused by hydrogen on the base metal during electroplating. This book will be of value to students and practitioners in the field of physical chemistry.
The book presents a collection of chapters on the current problems associated with hydrogen damage. It discusses the effect of hydrogen on material properties and its interaction with the material microstructure, physical features of hydrogen transport in metals and alloys, as well as applicable methods of measuring concentration of hydrogen in solid media.
Metal hydrides are of inestimable importance for the future of hydrogen energy. This unique monograph presents a clear and comprehensive description of the bulk properties of the metal-hydrogen system. The statistical thermodynamics is treated over a very wide range of pressure, temperature and composition. Another prominent feature of the book is its elucidation of the quantum mechanical behavior of interstitial hydrogen atoms, including their states and motion. The important topic of hydrogen interaction with lattice defects and its materials-science implications are also discussed thoroughly. This second edition has been substantially revised and updated.
