Phase Transformations of Elements Under High Pressure
Phase Transformations of Elements Under High Pressure

Author: E. Yu Tonkov

Publisher: CRC Press

Published: 2018-10-08

Total Pages: 390

ISBN-13: 1420037609

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As laboratories replace heavy hydraulic presses and bulky high-pressure chambers with miniature diamond anvils, traditional heaters with laser heating, and continue to improve methods of shock compression, there has been considerable new data obtained from the high-pressure, high-temperature modification of pure elements. The dense metallic modification of elements shows the potential for achieving superconductivity akin to theoretical predictions. Phase Transformations of Elements Under High Pressure contains the latest theoretical and experimental information on nearly 100 elements, including first-and second-phase transitions, melting lines, crystal structures of stable and metastable phases, stability of polymorphic modifications, and other useful properties and data. It emphasizes features such as changes in the liquid state, amorphization, and metallization, and provides temperature-pressure diagrams for every element. The book also describes the transitions of polymeric forms of fullerene, crystal modifications of elements stable under high pressures, and provides data that confirms their superconducting and magnetic properties. This handbook will be a lasting reference for scientists in a broad range of disciplines, including solid-state physics, chemistry, crystallography, mineralogy, and materials science.

High Pressure Phase Transformations
High Pressure Phase Transformations

Author: Evgeniĭ I︠U︡rʹevich Tonkov

Publisher: CRC Press

Published: 1992

Total Pages: 408

ISBN-13: 9782881247590

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A comprehensive handbook comprising two volumes, High Pressure Phase Transformations classifies and systemizes data on phase transformations of 2,263 elements and compounds under high pressure (at least 0.1 GPa). Each compound has a separate paragraph and bibliography that includes information on the behavior of the material under normal pressure. A critical analysis is made of experimental data on melting, first- and second-order phase transitions, crystal stuctures and phase diagrams, and data on new materials and compounds synthesized under high pressure are presented and discussed.

Phase Transformations in Materials
Phase Transformations in Materials

Author: G. Kostorz

Publisher: Wiley-VCH

Published: 2001-10-25

Total Pages: 732

ISBN-13:

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For all kinds of materials, phase transformations show common phenomena and mechanisms, and often turn a material, for example metals, multiphase alloys, ceramics or composites, into its technological useful form. The physics and thermodynamics of a transformation from the solid to liquid state or from one crystal form to another are therefore essential for creating high-performance materials. This handbook covers phase transformations, a general phenomenon central to understanding the behavior of materials and for creating high-performance materials. It will be an essential reference for all materials scientists, physicists and engineers involved in the research and development of new high performance materials. It is the revised and enhanced edition of the renowned book edited by the late P. Haasen in 1990 (Vol. 5, Materials Science and Technology).

New Kinds of Phase Transitions: Transformations in Disordered Substances
New Kinds of Phase Transitions: Transformations in Disordered Substances

Author: V.V. Brazhkin

Publisher: Springer

Published: 2002-08-31

Total Pages: 649

ISBN-13: 9781402008269

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Phase transitions are involved in phenomena ranging from the initial stages of the creation of the Universe to the existence of biological objects. It is natural to as whether any phenomena analogous to phase transitions are possible in disordered substances like liquids and glasses. The possibility of such transitions is still very much a matter of debate. Neither the nature nor the features of transformations in liquids and glasses are yet clear, nor is the nature of the order parameters. Investigations in recent years have shown that transformations in liquids and glasses lead to a drastic change of their physical properties and short-range order structure. The papers collected here contribute to a better understanding of the physics of disordered systems and phase transformations in them. An unambiguous identification of transitions in liquids and glasses requires further high-precision experimental study of the thermodynamic and structural properties in the vicinity of transitions in order to test existing theoretical models and develop new, more accurate ones.

High Pressure Surface Science and Engineering
High Pressure Surface Science and Engineering

Author: Yury Gogotsi

Publisher: CRC Press

Published: 2019-09-19

Total Pages: 516

ISBN-13: 042952501X

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In many instances of mechanical interaction between two materials, the physical contact affects only the outermost surface layer, with little discernible influence on the bulk of the material. The resultant high pressures in these localised regimes can induce surface structural changes such as deformation, phase transformation and amorphization.

Phase Transitions in Solids Under High Pressure
Phase Transitions in Solids Under High Pressure

Author: Vladimir Davydovich Blank

Publisher: CRC Press

Published: 2013-10-25

Total Pages: 451

ISBN-13: 146659425X

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The use of high-pressure techniques has become popular for studying the nature of substances and phenomena occurring in them, especially as a means of obtaining new materials (synthesis under high pressure) and processing known materials (hydroextrusion). A product of many years of research by the authors and their colleagues, Phase Transitions in

Phase Equilibria, Phase Diagrams and Phase Transformations
Phase Equilibria, Phase Diagrams and Phase Transformations

Author: Mats Hillert

Publisher: Cambridge University Press

Published: 2007-11-22

Total Pages: 525

ISBN-13: 1139465864

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Computational tools allow material scientists to model and analyze increasingly complicated systems to appreciate material behavior. Accurate use and interpretation however, requires a strong understanding of the thermodynamic principles that underpin phase equilibrium, transformation and state. This fully revised and updated edition covers the fundamentals of thermodynamics, with a view to modern computer applications. The theoretical basis of chemical equilibria and chemical changes is covered with an emphasis on the properties of phase diagrams. Starting with the basic principles, discussion moves to systems involving multiple phases. New chapters cover irreversible thermodynamics, extremum principles, and the thermodynamics of surfaces and interfaces. Theoretical descriptions of equilibrium conditions, the state of systems at equilibrium and the changes as equilibrium is reached, are all demonstrated graphically. With illustrative examples - many computer calculated - and worked examples, this textbook is an valuable resource for advanced undergraduates and graduate students in materials science and engineering.

Pressure-Induced Phase Transitions in AB2X4 Chalcogenide Compounds
Pressure-Induced Phase Transitions in AB2X4 Chalcogenide Compounds

Author: Francisco Javier Manjon

Publisher: Springer Science & Business Media

Published: 2014-01-21

Total Pages: 248

ISBN-13: 3642403670

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This book on pressure-induced phase transitions in AB2X4 chalcogenide compounds deals with one important AmBnXp material. The interest in these materials is caused by their properties. The results are discussed for three main groups of structural families: cubic-spinel structures, defective tetragonal structures, and other structures like layered and wurtzite-type modifications. A systematic analysis of the behavior of cubic (spinel), tetragonal (defect chalcopyrites and stannites) and other crystal modifications of AB2X4 compounds under hydrostatic pressure is performed. The behavior of AIIAl2S4, AIIGa2S4, AIIAl2Se4 and AIIGa2Se4 compounds with defective tetragonal structures, compounds with layered and wurtzite structures under hydrostatic pressure and the pressure dependence of the band gap, lattice parameters, interatomic distances, vibrational modes and pressure-induced phase transitions is discussed. Many of these compounds, except oxide spinels, undergo a pressure-induced phase transition towards the rocksalt-type structure. The phase transition is preceded by disorder in the cation sublattice. The dependence of the transition pressure to the rocksalt-type structure as a function of the compound ionicity and the size criterion is analyzed. At high pressures, all ordered-vacancy compounds are found to exhibit a band anticrossing between several conduction bands that leads to a strong decrease of its pressure coefficient and consequently to a strong non-linear pressure dependence of the direct bandgap energy. Theoretical studies of phase transitions in several ordered-vacancy compounds reveal that the existence of ordered vacancies alter the cation-anion bond distances and their compressibilities. The book is written for students, Ph D. students and specialists in materials science, phase transitions and new materials.