Polysaccharide Based Graft Copolymers
Polysaccharide Based Graft Copolymers

Author: Susheel Kalia

Publisher: Springer Science & Business Media

Published: 2013-05-23

Total Pages: 358

ISBN-13: 3642365663

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Renowned experts give all essential aspects of the techniques and applications of graft copolymers based on polysaccharides. Polysaccharides are the most abundant natural organic materials and polysaccharide based graft copolymers are of great importance and widely used in various fields. Natural polysaccharides have recently received more attention due to their advantages over synthetic polymers by being non-toxic, biodegradable and available at low cost. Modification of polysaccharides through graft copolymerization improves the properties of polysaccharides. Grafting is known to improve the characteristic properties of the backbones. Such properties include water repellency, thermal stability, flame resistance, dye-ability and resistance towards acid-base attack and abrasion. Polysaccharides and their graft copolymers find extensive applications in diversified fields. Applications of modified polysaccharides include drug delivery devices, controlled release of fungicides, selective water absorption from oil-water emulsions, purification of water etc.

Colloidal and Morphological Behavior of Block and Graft Copolymers
Colloidal and Morphological Behavior of Block and Graft Copolymers

Author: Gunther Molau

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 326

ISBN-13: 1468419080

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The molecules of block and graft copolymers are molecules of a higher order; they consist of homopolymer subchains which are interconnected by chemical valence bonds. This structural com plexity is manifested in the unusual behavior of block and graft copolymers both in solution and in bulk. Many types of interac tions are possible in block and graft copolymers in the solid state. Polymer subchains of one molecule can interact with other polymer subchains which may belong to the same molecule or to different molecules. Since polymer chains of chemically different composition are usually incompatible, thermodynamically unfavorable as well as thermodynamically favorable interactions exist in the solid state. In solutions of block and graft copolymers, the sit uation becomes even more complex, because interactions between the solvent molecules and the various subchains of the copolymer mole cules occur in addition to the interactions between the polymer chains. This multitude of interactions gives rise to a wide spec trum of colloidal and morphological properties which have no paral lel in less complex polymer systems such as homopolymers or random copolymers. Research on the colloidal and morphological behavior of block and graft copolymers is a relatively new field of endeavor. It started in 1954, when F. M. Merrett fractionated mixtures of grafted na tural rubber with the corresponding homopolymers and observed that colloidal sols were formed at certain points during his fractional precipitations.

Cellulose-Based Graft Copolymers
Cellulose-Based Graft Copolymers

Author: Vijay Kumar Thakur

Publisher: CRC Press

Published: 2015-04-23

Total Pages: 622

ISBN-13: 1482242486

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Cellulose-Based Graft Copolymers: Structure and Chemistry discusses the synthesis, characterization, and properties of multifunctional cellulose-based graft copolymers. Presenting the contributions of accomplished experts in the field of natural cellulosic polymers, this authoritative text: Offers an overview of cutting-edge technical accomplishmen

Organic Polymers
Organic Polymers

Author: Arpit Sand

Publisher: BoD – Books on Demand

Published: 2020-03-11

Total Pages: 148

ISBN-13: 1789845734

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This book, Organic Polymers, covers aspects that are of immediate concern to a new entrant to the field of polymers. Taken as a whole, these eight chapters aim to help the readers easily assimilate other specialized and exhaustive treatises on the subject. Topics dealing with the chemistry and technology of polymers are presented in a careful and logical manner so as to provide an easy and enjoyable read. Several examples and analogies are included so to make the main concepts easy to follow and tables and figures are included so that the book can serve, to a limited extent, as a hand book dealing with polysaccharides with different parameters. This book is meant for students studying polysaccharides and those working on graft copolymers and other allied polymer industries but without a formal educational background in organic polymers.

Blends and Graft Copolymers of Cellulosics
Blends and Graft Copolymers of Cellulosics

Author: Yoshiyuki Nishio

Publisher: Springer

Published: 2017-04-07

Total Pages: 136

ISBN-13: 3319553216

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This book reveals how polymer blending and grafting now offer a growing range of new applications for advanced films and fibers. Further, it details how the processing and original physical properties of cellulosics can be improved, and demonstrates how new, cellulose-core polymeric materials offer a wide range of synergistic functionalities. Lastly, it summarizes basic characterization studies and successful fabrications of advanced films and fibers. The book is primarily intended for advanced undergraduates, academic and industrial researchers and professionals studying or using bio-based polymers.

Statistical, Gradient, Block and Graft Copolymers by Controlled/Living Radical Polymerizations
Statistical, Gradient, Block and Graft Copolymers by Controlled/Living Radical Polymerizations

Author: Kelly A. Davis

Publisher: Springer Science & Business Media

Published: 2007-11-02

Total Pages: 202

ISBN-13: 3540458069

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The design and the realisation of well defined polymer architectures has become an important goal in macromolecular science. The prerequisite for achieving this goal is the availability of controlled polymerisation reactions. Living anionic polymerisation was the first reaction fulfilling these requirements. Cationic polymerisation only came into play when it was realised that it was possible to create an equilibrium between active and dormant species with the fraction of the dormant species being far superior to that of active ones. A corresponding principle applies to controlled radical polymerisation per formed in quite a number of modes such as nitroxide mediated polymerisation (NMP), atom transfer radical polymerisation (ATRP), reversible addition frag mentation chain transfer (RAFT) or catalytic chain transfer (CCT) reactions. All of these variants of controlled radical polymerisation lead to well defined archi tectures with the particular advantage that a much larger number of monomers are suitable and the reaction conditions are much less demanding than those of living ionic polymerisation reactions. Although in controlled radical polymerisation, termination reactions cannot be excluded completely, they are limited in their extent and consequently the mol ecular weight is controlled, the polydispersity index is small and functionalities can be attached to the macromolecules. These features are indicative of the real isation of well defined polymer architectures such as block copolymers, star shaped and comb shaped copolymers.

Biopolymer Grafting: Synthesis and Properties
Biopolymer Grafting: Synthesis and Properties

Author: Vijay Kumar Thakur

Publisher: Elsevier

Published: 2017-09-27

Total Pages: 596

ISBN-13: 0128104619

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Biopolymer Grafting: Synthesis and Properties presents the latest research and developments in fundamental of synthesis and properties of biopolymer-based graft copolymers. The book presents a broad overview of the biopolymer grafting process, along with trends in the field. It also introduces a range of grafting methods which lead to materials with enhanced properties for a range of practical applications, along with the positives and limitations of these techniques. The book bridges the knowledge gap between the scientific principles and industrial applications of polymer grafting. This book covers synthesis and characterization of graft-copolymers of plant polysaccharides, functional separation membranes from grafted biopolymers, and polysaccharides in alternative methods for insulin delivery. Recent trends and advances in this area are discussed, assisting materials scientists and researchers in mapping out the future of these new "green" materials through value addition to enhance their use. - Introduces polymer researchers to a promising, rapidly developing method for modifying naturally derived biopolymers - Provides a one-stop shop covering synthesis, properties, characterization and graft copolymerization of bio-based polymeric materials - Increases familiarity with a range of biopolymer grafting processes, enabling materials scientists and engineers to improve material properties and widen the range of potential biopolymer applications

Polymers for Biomedicine
Polymers for Biomedicine

Author: Carmen Scholz

Publisher: John Wiley & Sons

Published: 2017-07-17

Total Pages: 621

ISBN-13: 1118966570

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Highlighting dynamic developments in polymer synthesis, this book focuses on the chemical techniques to synthesize and characterize biomedically relevant polymers and macromolecules. • Aids researchers developing polymers and materials for biomedical applications • Describes biopolymers from a synthetic perspective, which other similar books do not do • Covers areas that include: cationically-charged macromolecules, pseudo-peptides, polydrugs and prodrugs, controlled radical polymerization, self-assembly, polycondensates, and polymers for surface modification

Handbook of Radical Polymerization
Handbook of Radical Polymerization

Author: Krzysztof Matyjaszewski

Publisher: John Wiley & Sons

Published: 2002-08-08

Total Pages: 934

ISBN-13: 047139274X

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* Provides a concise source of information on synthetic techniques, purification, and characterization methods for free-radical polymers. * Presents information on future trends in the synthesis of free-radical polymers.

The Chemistry and Technology of Cellulosic Copolymers
The Chemistry and Technology of Cellulosic Copolymers

Author: A. Hebeish

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 361

ISBN-13: 364267707X

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Many excellent volumes have been written on the chemistry of cellulose and its derivatives. Judging by the number of conferences which have been assembled to deal with the topic, cellulose and its derivatives continue to arouse great scientific interest. Matching this interest has been the development in copolymer science and technology. In both instances the driving force has been the search for products having useful, new or interesting properties. It appeared inevitable that these two concepts would be brought together at some time in the research and development of cellulosic copolymers. That time has arrived. In assembling this text our aim was to present an informative account of the chemistry and technology of cellulosic copolymers. As such, we intended that the contents be of interest to all those concerned with the production and use of cellulosic products whether in academic or industrial circles. Sections of the text should be of value in undergraduate and post-graduate teaching, provided the student is given guidance in following the text. The volume is divided into eight chapters, each dealing with factors which are relevant to an under standing of cellulosic copolymers. Each chapter carries its own bibliography and is reasonably self-contained.