Nanosecond Pulsed Discharge in Water Without Bubbles

Nanosecond Pulsed Discharge in Water Without Bubbles

Author: Yohan Seepersad

Publisher:

Published: 2015

Total Pages: 354

ISBN-13:

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The state of plasma is widely known as a gas-phase phenomenon, but plasma in liquids have also received significant attention over the last century. Generating plasma in liquids however is theoretically challenging, and this problem is often overcome via liquid-gas phase transition preceding the actual plasma formation. In this sense, plasma forms in gas bubbles in the liquid. Recent work at the Drexel Plasma Institute has shown that nanosecond pulsed electric fields can initiate plasma in liquids without any initial cavitation phase, at voltages below theoretical direct-ionization thresholds. This unique regime is poorly understood and does not fit into any current descriptive mechanisms. As with all new phenomena, a complete fundamental description is paramount to understanding its usefulness to practical applications. The primary goals of this research were to qualitatively and quantitatively understand the phenomenon of nanosecond pulsed discharge in liquids as a means to characterizing properties that may open up niche application possibilities. Analysis of the plasma was based on experimental results from non-invasive, sub-nanosecond time-resolved optical diagnostics, including direct imaging, transmission imaging (Schlieren and shadow), and optical emission spectroscopy. The physical characteristics of the plasma were studied as a function of variations in the electric field amplitude and polarity, liquid permittivity, and pulse duration. It was found that the plasma size and emission intensity was dependent on the permittivity of the liquid, as well as the voltage polarity, and the structure and dynamics were explained by a 'cold-lightning' mechanism. The under-breakdown dynamics at the liquid-electrode interface were investigated by transmission imaging to provide evidence for a novel mechanism for initiation based on the electrostriction. This mechanism was proposed by collaborators on the project and developed alongside the experimental work in this research. Finally, analysis of emission spectra obtained from the OH(A-X) band at 308 nm by the excited hydroxyl radical was performed to quantify the temperature parameters of the plasma. Boltzmann analysis was performed to quantify the rotational temperature of OH which correlates well to the liquid temperature, and Stark broadening of the ionic lines belonging to hydrogen and oxygen was analysed to estimate electron temperature. It was found that the liquid temperature remained close to bulk temperature with T_(n,i)


OH LIF Studies of Low Temperature Plasma Assisted Oxidation and Ignition in Nanosecond Pulsed Discharge

OH LIF Studies of Low Temperature Plasma Assisted Oxidation and Ignition in Nanosecond Pulsed Discharge

Author: Inchul Choi

Publisher:

Published: 2011

Total Pages: 146

ISBN-13:

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Abstract: In recent years, plasma assisted ignition and flame-holding in high speed flows has attracted considerable attention due to potential applications for turbojet engines and afterburners operating at high altitudes, as well as scramjet engines. Conventional methods of igniting a flow in the combustor using a spark or an arc discharge are known to be ineffective at low pressures and high flow velocities, since the ignition kernel is limited by a small volume of the spark or arc filament. Single photon LIF spectroscopy is used to study hydroxyl radical formation and loss kinetics in low temperature hydrogen-air repetitively pulsed nanosecond plasmas. Nanosecond pulsed plasmas are created in a rectangular cross section quartz channel / plasma flow reactor. Flow rates of hydrogen-air mixtures are controlled by mass flow controllers at a total pressure of 40-100 torr, initial temperature T0=300-500 K and a flow velocity of approximately u=0.1-0.8 m/sec. Two rectangular copper plate electrodes, rounded at the corners to reduce the electric field non-uniformity, are attached to the outside of the quartz channel. Repetitively pulsed plasmas are generated using a Chemical Physics Technologies (CPT) power supply which produces ~25 nanosecond pulses with ~20 kV peak voltage. Absolute hydroxyl radical mole fraction is determined as both a function of time after application of a single 25 nsec pulse, and 60 microseconds after the final pulse of a variable length "burst" of pulses. Relative LIF signal levels are put on an absolute mole fraction scale by means of calibration with a standard near-adiabatic Hencken flat flame burner at atmospheric pressure. By obtaining OH LIF data in both the plasma and the flame, and correcting for differences in the collisional quenching and Vibrational Energy Transfer (VET) rates, absolute OH mole fraction can be determined. For a single discharge pulse at 27 °C and 100 °C, the absolute OH temporal profile is found to rise rapidly during the initial ~0.1 msec after discharge initiation and decay relatively slowly, with a characteristic time scale of ~1 msec. In repetitive burst mode the absolute OH number density is observed to rise rapidly during the first approximately 10 pulses (0.25 msec), and then level off to a near steady-state plateau. In all cases a large secondary rise in OH number density is also observed, clearly indicative of ignition, with ignition delay equal to approximately 15, 10, and 5 msec, respectively, for initial temperatures of 27 °C, 100 °C, and 200 °C. Plasma kinetic modeling predictions capture this trend quantitatively.


Nanosecond Pulsed Plasmas in Dynamic Combustion Environments

Nanosecond Pulsed Plasmas in Dynamic Combustion Environments

Author: Colin A. Pavan

Publisher:

Published: 2023

Total Pages: 0

ISBN-13:

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Plasma assisted combustion (PAC) is a promising technology for extending combustion operating envelopes with a low energy cost relative to flame power. It has been investigated for use in various situations, particularly those where combustion is being performed near flammability limits imposed by equivalence ratio, residence time, etc. While the fundamental processes allowing plasma to modify combustion dynamics have been well studied, there are still many unresolved questions in determining the relative contribution of different actuation pathways in different situations (thermal enhancement, kinetic enhancement or transport-induced effects) and how the plasma will evolve and interact with the flame in a dynamic combustion environment. The plasmas being used for PAC are typically non-equilibrium and are often produced by the nanosecond repetitively pulsed discharge (NRPD) strategy. The development of these discharges is highly dependent both on applied voltage and also on the gas environment (composition, temperature, flow field, etc.). As the plasma affects the combustion, so too does the combustion affect the plasma structure and energy deposition pathways. This two-way coupling means that the plasma's ability to modify the combustion, and the mechanisms by which it achieves these effects, will vary as the environment changes due to combustion dynamics. This impact of the combustion on the plasma has received considerably less attention than the other direction of interaction, especially in environments with transient or propagating flames. The first main objective of this thesis is to explore the development of NRPDs in dynamic combustion environments and in particular how the plasma develops on the timescales of transient combustion (many accumulated pulses). This is performed first in a laminar, mesoscale platform to probe the interaction in detail, and the important insights are later shown to be relevant to high power systems of practical interest. While the impact of the plasma on the flame has been considerably better studied and the fundamental processes are well understood, there are still hurdles that must be overcome before PAC systems can begin to be designed and implemented for use outside of the laboratory. The development of versatile and flexible engineering models of the impact of the plasma will be necessary to allow system designers to make predictions about combustor operation when plasma is applied. The second main objective of this thesis is to develop such an engineering model and demonstrate its predictive capabilities across a variety of configurations. The model is developed for a laminar mesoscale platform and is shown to correctly predict the impact of the plasma in several different configurations, indicating a path forward towards physics[1]informed design of PAC systems. The model also provides important physical insight of the impact of plasma on flame, such as the role of pressure waves in disturbing the flame dynamics, even when considering uniform DBD discharges.


Plasma Discharge in Liquid

Plasma Discharge in Liquid

Author: Yong Yang

Publisher: CRC Press

Published: 2017-12-19

Total Pages: 210

ISBN-13: 1439866244

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Plasma methods that effectively combine ultraviolet radiation, active chemicals, and high electric fields offer an alternative to conventional water treatment methods. However, knowledge of the electric breakdown of liquids has not kept pace with this increasing interest, mostly due to the complexity of phenomena related to the plasma breakdown process. Plasma Discharge in Liquid: Water Treatment and Applications provides engineers and scientists with a fundamental understanding of the physical and chemical phenomena associated with plasma discharges in liquids, particularly in water. It also examines state-of-the-art plasma-assisted water treatment technologies. The Physics & Applications of Underwater Plasma Discharges The first part of the book describes the physical mechanism of pulsed electric breakdown in water and other liquids. It looks at how plasma is generated in liquids and discusses the electronic and bubble mechanism theories for how the electric discharge in liquid is initiated. The second part of the book focuses on various water treatment applications, including: Decontamination of volatile organic compounds and remediation of contaminated water Microorganism sterilization and other biological applications Cooling water treatment Drawing extensively on recent research, this one-stop reference combines the physics and applications of electric breakdown in liquids in a single volume. It offers a valuable resource for scientists, engineers, and students interested in the topic of plasmas in liquids.


Pulsed Discharge Plasmas

Pulsed Discharge Plasmas

Author: Tao Shao

Publisher: Springer Nature

Published: 2023-07-14

Total Pages: 1028

ISBN-13: 9819911419

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This book highlights the latest progress in pulsed discharge plasmas presented by front-line researchers worldwide. The science and technology surrounding pulsed discharge plasmas is advanced through a wide scope of interdisciplinary studies into pulsed power and plasma physics. Pulsed discharge plasmas with high-power density, high E/N and high-energy electrons can effectively generate highly reactive plasma. Related applications have gathered strong interests in various fields. With contributions from global scientists, the book elaborates on the theories, numerical simulations, diagnostic methods, discharge characteristics and application technologies of pulsed discharge plasmas. The book is divided into three parts with a total of 35 chapters, including 11 chapters on pulsed discharge generation and mechanism, 12 chapters on pulsed discharge characterization and 12 chapters on pulsed discharge applications (wastewater treatments, biomedicine, surface modification, and energy conversion, etc). The book is a must-have reference for researchers and engineers in related fields and graduate students interested in the subject.


Kinetics and Chemistry of Ionization Wave Discharges Propagating Over Dielectric Surfaces

Kinetics and Chemistry of Ionization Wave Discharges Propagating Over Dielectric Surfaces

Author: Vitaly Petrishchev

Publisher:

Published: 2016

Total Pages: 206

ISBN-13:

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Experimental studies of near-surface ionization wave electric discharges generated by high peak voltage (20-30 kV), nanosecond duration pulses (full width at half-maximum 50-100 ns) of positive and negative polarity and propagating over dielectric surfaces have been performed. A novel way to sustain diffuse, reproducible, ns pulse surface plasmas at a liquid-vapor interface is demonstrated at buffer gas pressures ranging from 10 to 200 Torr. Generation of surface ionization waves well reproduced shot-to-shot and sustaining diffuse near-surface plasmas is one of the principal advantages of the use of ns pulse discharge waveforms. This makes possible characterization of these plasmas in repetitively pulsed experiments. Numerous applications of these plasmas include low-temperature plasma assisted combustion, plasma fuel reforming, plasma flow control, plasma materials processing, agriculture, biology, and medicine. The objectives of the present work are (i) to demonstrate that surface ionization wave discharge plasmas sustained at a liquid-vapor interface can be used as an experimental platform for studies of near-surface plasma chemical reaction kinetics, at the conditions when the interface acts as a high-yield source of radical species, and (ii) to obtain quantitative insight into dynamics, kinetics and chemistry of surface ionization wave discharges and provide experimental data for validation of kinetic models, to assess their predictive capability. Generation of the initial radical pool may trigger a number of plasma chemical processes leading to formation of a variety of stable product species, depending on the initial composition of the liquid and the buffer gas flow. One of the products formed and detected during surface plasma / liquid water interaction is hydroxyl radical, which is closely relevant to applications of plasmas for biology and medicine. The present work includes detailed studies of surface ionization wave discharges sustained in different buffer gases over solid and liquid dielectric surfaces, such as quartz, distilled water, saline solution, and alcohols, over a wide range of pressures. Specific experiments include: measurements of ionization wave speed; plasma emission imaging using a ns gate camera; detection of surface discharge plasma chemistry products using Fourier transform infrared absorption spectroscopy; surface charge dynamics on short (ns) and long (hundreds of μs) time scales; time-resolved electron density and electron temperature measurements in a ns pulse surface discharge in helium by Thomson scattering; spatially-resolved absolute OH and H atom concentration measurements in ns pulse discharges over distilled water by single-photon and two-photon Laser Induced Fluorescence; and schlieren imaging of perturbations generated by a ns pulse dielectric barrier discharge in a surface plasma actuator in quiescent atmospheric pressure air.


Nonequilibrium Atmospheric Pressure Plasma Jets

Nonequilibrium Atmospheric Pressure Plasma Jets

Author: XinPei Lu

Publisher: CRC Press

Published: 2019-04-23

Total Pages: 400

ISBN-13: 0429620721

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Nonequilibrium atmospheric pressure plasma jets (N-APPJs) generate plasma in open space rather than in a confined chamber and can be utilized for applications in medicine. This book provides a complete introduction to this fast-emerging field, from the fundamental physics, to experimental approaches, to plasma and reactive species diagnostics. It provides an overview of the development of a wide range of plasma jet devices and their fundamental mechanisms. The book concludes with a discussion of the exciting application of plasmas for cancer treatment. The book provides details on experimental methods including expert tips and caveats. covers novel devices driven by various power sources and the impact of operating conditions on concentrations and fluxes of the reactive species. discusses the latest advances including theory, modeling, and simulation approaches. gives an introduction, overview and details on state of the art diagnostics of small scale high gradient atmospheric pressure plasmas. covers the use of N-APPJs for cancer applications, including discussion of destruction of cancer cells, mechanisms of action, and selectivity studies. XinPei Lu is a Chair Professor in the School of Electrical and Electronic Engineering at Huazhong University of Science and Technology. Stephan Reuter is currently Visiting Professor at Université Paris-Saclay. In a recent Alexander von Humboldt research fellowship at Princeton University, he performed ultrafast laser spectroscopy on cold plasmas. Mounir Laroussi is Professor of Electrical and Computer Engineering and director of the Plasma Engineering and Medicine Institute at Old Dominion University. He is a Fellow of IEEE and recipient of an IEEE Merit Award. DaWei Liu is Professor in the School of Electrical and Electronic Engineering at Huazhong University of Science and Technology.


Design and Implementation of a Combined High Voltage Nanosecond - Radiofrequency Excitation Non-thermal Plasma System

Design and Implementation of a Combined High Voltage Nanosecond - Radiofrequency Excitation Non-thermal Plasma System

Author: Dante Filice

Publisher:

Published: 2022

Total Pages: 0

ISBN-13:

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"The world is rapidly transitioning its energy and chemical feedstocks from carbon intensive sources to renewable sources. Many existing and new technologies that utilize renewable electricity will need to come online in order to reduce CO2 emissions and reach carbon neutral goals. Plasma-driven systems for NH3 synthesis and reactions involving CO2 conversion can not only meet the challenges of carbon neutrality, but also have the potential to increase performance and reduce operational costs.Common excitation sources for non-thermal plasma processing include high voltage nanosecond (ns) pulsed plasma sources and radiofrequency (RF) sources. High voltage ns pulsed plasma sources are effective at igniting and sustaining plasmas in atmospheric pressure gases and gas mixtures. These pulses produce large quantities of excited species and highly reactive radicals participating in the desired chemical reaction pathways. When sufficiently separated in time, the power delivery of each pulse is relatively discrete resulting in minimal memory effect. The rapid quenching of the electron and excited species densities causes the discharge to essentially face re-ignition conditions every pulse. This dynamic load impedance leads to low efficiency of power delivery from the electrical mains to the plasma. On the other hand, conventional RF discharges can provide high electrical power-to-plasma chemical energy conversion efficiency, however sustaining a uniform discharge at atmospheric pressure proves to be challenging. Commercially available RF power supplies cannot reach the breakdown voltage thresholds required to ignite electrical discharges at atmospheric pressure in most gas mixtures and useful interelectrode gaps. This Master's thesis focuses on developing a plasma excitation source that combines a high voltage ns pulsed source with a RF source. Each power supply was designed and characterized to determine the electrical performance of the excitation system. Gas mixtures containing increasing amounts of N2 in Ar were introduced into the system to observe the effects on the plasma characteristics. High speed imaging was also used to focus in on the transition period from high voltage ns pulsed excitation to RF excitation.A parameterization sweep was performed to determine the operational characteristics of the RF power supply with varying gas mixture ratios. Observable RF discharge effects were present in reactor conditions with N2 concentrations up to 50% in Ar. The temporal RF discharge evolution was captured with a high-speed camera, providing insight into the mechanisms involved in obtaining RF discharge effects"--