Development of Vapor Dispersion Models for Nonneutrally Buoyant Gas Mixtures-Analysis of TFI/NH3 Test Data

Development of Vapor Dispersion Models for Nonneutrally Buoyant Gas Mixtures-Analysis of TFI/NH3 Test Data

Author: Thomas O. Spicer

Publisher:

Published: 1988

Total Pages: 133

ISBN-13:

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Field-scale releases of pressurized anhydrous ammonia were performed by the Lawrence Livermore National Laboratories in 1983 for the U.S. Coast Guard, the Fertilizer Institute, and Environment Canada. Release rates for the four experiments ranged between 80 and 130 kilograms per second. The pressurized liquid ammonia jet formed a denser-than-air aerosol cloud. A method of determining the relative importance of jet and nonjet dispersion processes is discussed. The data from these experiments were analyzed to determine the mass flux of ammonia and the lateral and vertical concentration profile parameters for the cloud (sigma y and sigma z for the Gaussian plume model and SY and SZ for DEGADIS) at 800 meters downwind. These observed values of maximum concentration and concentration profile parameters were compared with DEGADIS and Gaussian plume model predictions. (DEGADIS is an atmospheric dispersion model designed to account for the influences of denser-than-air gases.) In addition, analysis of the experimental data indicated heat transfer to the aerosol cloud was insignificant although the cloud temperature was as low as -60 centigrade. (mjm).


Development of an Atmospheric Dispersion Model for Heavier-Than-Air Gas Mixtures

Development of an Atmospheric Dispersion Model for Heavier-Than-Air Gas Mixtures

Author: Jerry A. Havens

Publisher:

Published: 1985

Total Pages: 183

ISBN-13:

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Mathematical modeling techniques use to predict atmospheric dispersion of heavy gases are reviewed and critiqued. These dispersion processes are characterized by three phases: (1) near field, negative buoyancy-domainated flow regime; (2) intermediate field, stably stratified shear flow regime; and (3) far field, passive turbulent diffusion regime. Mathematical models of laboratory and natural gravity currents are used to describe the negative buoyancy-dominated regime flow and dilution processes. A laboratory investigation of instantaneous heavy gas releases in calm air demonstrates scaling from small release volumes (0.5 cu m) to large field (2000 cu m) field releases, and is used to develop a mathematical model for the buoyancy-dominated regime. Laboratory data from stratified shear flow mixing experiments are used to develop a model for vertical diffusion of heavy gases in the atmospheric surface layer. The model concepts are consistent with the limiting passive behavior of demonstrated air pollution models. An interactive computer model for heavy gas dispersion (DEGADIS) is developed. The DEGADIS model accounts for the three regimes of heavy gas dispersion processes and can be used to simulate instantaneous, steady state, and transient releases. The model provides predictions of downwind concentration decay which are in good agreement with the full range of field experimental data currently available, and is recommended for incorporation in the Coast Guard hazard assessment computer system.


Guidelines for Use of Vapor Cloud Dispersion Models

Guidelines for Use of Vapor Cloud Dispersion Models

Author: CCPS (Center for Chemical Process Safety)

Publisher: John Wiley & Sons

Published: 1996-12-15

Total Pages: 308

ISBN-13: 0816907021

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The second edition of this essential reference updates and combines two earlier titles to capture the many technological advances for predicting the "footprint" of a vapor cloud release. Cited by EPA in its 1996 document, "Off-Site Consequence Analysis Guidance," the aim of the book is to encourage and facilitate the development and use of dispersion modeling as an everyday tool, providing practical understanding of basic physical and chemical principles, guidance in selecting release scenarios and the best available models, and information and examples on how to run some models and interpret outputs. Equally useful to beginners and experts, it compares 22 programs based on input from model developers, and presents 7 examples of typical accidental release scenarios. The book comes with a disk providing input and output data for scenarios.