Conformational Properties of Macromolecules

Conformational Properties of Macromolecules

Author: A Hopfinger

Publisher: Elsevier

Published: 2012-12-02

Total Pages: 352

ISBN-13: 032315459X

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Conformational Properties of Macromolecules provides information about the molecular parameters and spatial and thermodynamic properties of macromolecules and the application of theoretical conformational energy calculations. The book covers topics such as macromolecular geometry, the classification of macromolecular structure, and the generation of macromolecular conformations and configurations; conformational energies and potential functions, induced dipole and polymer-solvent interactions; and conformational transition in molecules. Also covered are topics such as absorption and optical rotation spectroscopies, epitaxial crystallization of macromolecules, and conformational fluctuation in macromolecules. The text is recommended for structural chemists, X-ray crystallographers, biophysicists, physical chemists, and macromolecular scientists who would like to know more about this particular area of knowledge.


Conformation of Macromolecules

Conformation of Macromolecules

Author: Y. G. Medvedevskikh

Publisher: Nova Publishers

Published: 2007

Total Pages: 270

ISBN-13: 9781600217555

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Conformation is statistical property of the macromolecules consisting of a number of N structural units, links, position of which in a space one relatively to other is not inflexibly fixed by chemical bonds and assumes the possible random configurations. The number of possible configurations at N ” 1 is so great that permits to use the statistical methods at their analysis. That is why the conformation is a result of statistical averaging on all possible configurations of the macromolecule. It was for a long time notified and confirmed by computer modelling that the conformation of polymeric chain should be described by self-avoiding random walks statistics (SARW) but not Gaussian random walks statistics, assuming the phantom behaviour of polymeric chains. Nevertheless, Gaussian statistics is dominating at the analysis of thermodynamic, dynamic and kinetic stainings of the macromolecules conformation. This book will be useful for scientists who are engaged in the physical chemistry of polymers and their solutions.


Macromolecules

Macromolecules

Author: Hans-Georg Elias

Publisher: Springer Science & Business Media

Published: 2013-06-29

Total Pages: 1228

ISBN-13: 1461573645

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Like so many of its kind, this textbook originated from the requirements of teaching. While lecturing on macromolecular science as a required subject for chemists and materials scientists on the undergraduate, graduate, and postgraduate levels at Swiss Federal Institute of Technology at Zurich (1960-1971), I needed a one-volume textbook which treated the whole field of macromolecular science, from its chemistry and physics to its applications, in a not too elementary manner. This textbook thus intends to bridge the gap between the often oversimplified introductory books and the highly specialized texts and monographs that cover only parts of macromolecular science. This first English edition is based on the third German edition (1975), which is about 40% different from the first German edition (1971), a result of rapid progress in macromolecular science and the less rapid education of the writer. This text intends to survey the whole field of macromolecular science. Its organization results from the following considerations. The chemical structure of macromolecular compounds should be independent of the method of synthesis, at least in the ideal case. Part I is thus concerned with the chemical and physical structure of macro molecules. Properties depend on structure. Solution properties are thus discussed in Part II, solid state properties in Part III. There are other reasons for discussing properties before syntheses: For example, it is difficult to under stand equilibrium polymerization without knowledge of solution thermody of the glass temperature, etc.


Branched Polymers II

Branched Polymers II

Author: Jacques Roovers

Publisher: Springer Science & Business Media

Published: 1998-12-11

Total Pages: 280

ISBN-13: 3540650059

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With contributions by numerous experts


Functional Properties of Food Macromolecules

Functional Properties of Food Macromolecules

Author: S.E. Hill

Publisher: Springer Science & Business Media

Published: 1998-08-31

Total Pages: 374

ISBN-13: 9780751404210

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This edition updates the substantial progress that has occurred since 1988 in many aspects of understanding, measuring and utilizing functional macromolecules.


Conformational Theory of Large Molecules

Conformational Theory of Large Molecules

Author: Wayne L. Mattice

Publisher: Wiley-Interscience

Published: 1994-11-04

Total Pages: 480

ISBN-13:

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Ubiquitous computers, coupled with software packages for the visualization and manipulation of atom-based polymer models, also contribute to increased use of the technique.


An Introduction to Macromolecules

An Introduction to Macromolecules

Author: L. Mandelkern

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 171

ISBN-13: 1461254949

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The reception of the original volume by students, pedagogues, and reviewers has been most gratifying. It appears to have both satisfied a need and served a useful educational purpose. Hence, some ten years later it has been deemed advisable to bring it up to date, if only in a slightly expanded form. The purpose for writing this book and its level remain the same. Many new polymers have been synthesized in the last decade that have found meaningful and novel uses. Examples of these applications are included in this new edition. Major advances have also been made in biophysics and in molecular biology, as well as in our understanding of natural processes on a molecular level. Foremost among these has been the development of recombinant DNA technology. With it has come the potential for large scale synthesis of hormones and proteins. These new developments have also been incorporated into the present volume. It is my hope that this new edition will still have a widespread appeal to students in all of the natural sciences whatever their major interest. It should also be of use and inter est to those starting industrial or academic careers who have not had an extensive background in macromolecular science.


Conformation in Biology and Drug Design

Conformation in Biology and Drug Design

Author: Sidney Udenfriend

Publisher: Elsevier

Published: 2014-05-10

Total Pages: 516

ISBN-13: 1483218007

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The Peptides: Analysis, Synthesis, Biology, Volume 7: Conformation in Biology and Drug Design focuses on the analysis of peptides, emphasizing the use of physical methods in peptide conformational analysis and the relationship of conformational properties of peptides to biological properties. This book consists of nine chapters. Chapter 1 provides a brief overview of the perspective on the application of physical methods to peptide conformational analysis. The use of circular dichroism (CD) spectroscopy to examine the conformational properties of peptides in solution is elaborated in Chapter 2, while the use of fluorescence spectroscopy to examine the special relationships of aromatic side-chain groups to one another is discussed in Chapter 3. In Chapter 4, the use of various theoretical methods to calculate the conformations of peptides is described. The methods used to stimulate peptide conformations and dynamics are outlined in Chapter 5. The last four chapters examine various aspects of the use of nuclear magnetic resonance (NMR) in peptide conformational analysis. This volume is suitable for biologists, specialists, and researchers interested in peptides and proteins.


Polymers in Solution

Polymers in Solution

Author: W.C. Forsman

Publisher: Springer Science & Business Media

Published: 2013-11-11

Total Pages: 312

ISBN-13: 1489904654

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Polymers in Solution was written for scientists and engineers who have serious research interests in newer methods for characterization of polymer solutions, but who are not seasoned experts in the theoretical and experimental aspects of polymer science. In particular, it is assumed that the reader is not familiar with the development of theoretical notions in conformational statistics and the dynamics of chainlike molecules; how these two seemingly diverse theoretical topics are related; and the role played by polymer-solvent interactions. Chapter 1 thus presents background material that introduces most of the essential concepts, including some of the mathematical apparatus most commonly used in these areas of theory. This introduction is followed by five chapters that are more closely related to particular experimental techniques. These chapters introduce further theoretical notions as needed. Three of the chapters present con siderable detail on the experimental methods, while two other chapters deal more with the interpretation of experimental results in terms of current theories. Although neutron scattering has become an almost standard technique for the study of conformational properties of macromolecules in the solid state, there has been less emphasis on its application for characterization of polymer molecules in solution. Chapter 4 covers this growing area of application.