Computational Thermodynamic Study to Predict Complex Phase Equilibria in the Nickel-Base Superalloy Rene
Computational Thermodynamic Study to Predict Complex Phase Equilibria in the Nickel-Base Superalloy Rene

Author: National Aeronautics and Space Adm Nasa

Publisher: Independently Published

Published: 2018-09-19

Total Pages: 48

ISBN-13: 9781723821837

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A previous study by Ritzert et al. on the formation and prediction of topologically closed packed (TCP) phases in the nickel-base superalloy Rene' N6 is re-examined with computational thermodynamics. The experimental data on phase distribution in forty-four alloys with a composition within the patent limits of the nickel-base superalloy Rene' N6 provide a good basis for comparison to and validation of a commercial nickel superalloy database used with ThermoCalc. Volume fraction of the phases and partitioning of the elements are determined for the forty-four alloys in this dataset. The baseline heat treatment of 400 h at 1366 K was used. This composition set is particularly interesting since small composition differences lead to dramatic changes in phase composition. In general the calculated values follow the experimental trends. However, the calculations indicated no TCP phase formation when the experimental measurements gave a volume percent of TCP phase less than 2 percent. When TCP phases were predicted, the calculations under-predict the volume percent of TCP phases by a factor of 2 to 8. The calculated compositions of the gamma and gamma' phases show fair agreement with the measurements. However, the calculated compositions of the P Phase do not agree with those measured. This may be due to inaccuracies in the model parameters for P phase and/or issues with the microprobe analyses of these phases. In addition, phase fraction diagrams and sigma and P phase solvus temperatures are calculated for each of the alloys. These calculations indicate that P phase is the primary TCP phase formed for the alloys considered here at 1366 K. Finally, a series of isopleths are calculated for each of the seven alloying elements. These show the effect of each alloying element on creating TCP phases.Copland, Evan H. and Jacobson, Nathan S. and Ritzert, Frank J.Glenn Research CenterTHERMODYNAMICS; COMPUTATION; EQUILIBRIUM; NICKEL ALLOYS; DATA BASES; TRENDS; PHASE DIAGRAMS; MICROAN

The Superalloys
The Superalloys

Author: Roger C. Reed

Publisher: Cambridge University Press

Published: 2008-07-31

Total Pages: 363

ISBN-13: 1139458639

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Superalloys are unique high-temperature materials used in gas turbine engines, which display excellent resistance to mechanical and chemical degradation. This book introduces the metallurgical principles which have guided their development. Suitable for graduate students and researchers, it includes exercises and additional resources at www.cambridge.org/9780521859042.

Aerospace Materials and Applications
Aerospace Materials and Applications

Author: Biliyar N. Bhat

Publisher:

Published: 2018

Total Pages: 0

ISBN-13: 9781624104886

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"The present volume is focused on documenting the novel processing, fabrication, characterization, and testing approaches that are unique to aerospace materials/structures/systems"--Preface.

High Temperature Coatings
High Temperature Coatings

Author: Sudhangshu Bose

Publisher: Butterworth-Heinemann

Published: 2017-11-27

Total Pages: 418

ISBN-13: 0128047437

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High Temperature Coatings, Second Edition, demonstrates how to counteract the thermal effects of rapid corrosion and degradation of exposed materials and equipment that can occur under high operating temperatures. This is the first true practical guide on the use of thermally protective coatings for high-temperature applications, including the latest developments in materials used for protective coatings. It covers the make-up and behavior of such materials under thermal stress and the methods used for applying them to specific types of substrates, as well as invaluable advice on inspection and repair of existing thermal coatings. With his long experience in the aerospace gas turbine industry, the author has compiled the very latest in coating materials and coating technologies, as well as hard-to-find guidance on maintaining and repairing thermal coatings, including appropriate inspection protocols. The book is supplemented with the latest reference information and additional support to help readers find more application- and industry-type coatings specifications and uses. - Offers an overview of the underlying fundamental concepts of thermally-protective coatings, including thermodynamics, energy kinetics, crystallography and equilibrium phases - Covers essential chemistry and physics of underlying substrates, including steels, nickel-iron alloys, nickel-cobalt alloys and titanium alloys - Provides detailed guidance on a wide variety of coating types, including those used against high temperature corrosion and oxidative degradation and thermal barrier coatings

Complex Inorganic Solids
Complex Inorganic Solids

Author: Patrice E. A. Turchi

Publisher: Springer Science & Business Media

Published: 2007-12-31

Total Pages: 420

ISBN-13: 0387259538

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One of the key aspects of this volume is to cut across the traditional taxonomy of disciplines in the study of alloys. Hence there has been a deliberate attempt to integrate the different approaches taken towards alloys as a class of materials in different fields, ranging from geology to metallurgical engineering. The emphasis of this book is to highlight commonalities between different fields with respect to how alloys are studied. The topics in this book fall into several themes, which suggest a number of different classification schemes. We have chosen a scheme that classifies the papers in the volume into the categories Microstructural Considerations, Ordering, Kinetics and Diffusion, Magnetic Considerations and Elastic Considerations. The book has juxtaposed apparently disparate approaches to similar physical processes, in the hope of revealing a more dynamic character of the processes under consideration. This monograph will invigorate new kinds of discussion and reveal challenges and new avenues to the description and prediction of properties of materials in the solid state and the conditions that produce them.

Developments in High Temperature Corrosion and Protection of Materials
Developments in High Temperature Corrosion and Protection of Materials

Author: W Gao

Publisher: Elsevier

Published: 2008-04-09

Total Pages: 677

ISBN-13: 1845694252

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High temperature corrosion is a phenomenon that occurs in components that operate at very high temperatures, such as gas turbines, jet engines and industrial plants. Engineers are constantly striving to understand and prevent this type of corrosion. This book examines the latest developments in the understanding of high temperature corrosion processes and protective oxide scales and coatings.Part one looks at high temperature corrosion. Chapters cover diffusion and solid state reactions, external and internal oxidation of alloys, metal dusting corrosion, tribological degradation, hot corrosion, and oxide scales on hot-rolled steel strips. Modern techniques for analysing high temperature oxidation and corrosion are also discussed. Part two discusses methods of protection using ceramics, composites, protective oxide scales and coatings. Chapters focus on layered ternary ceramics, alumina scales, Ti-Al intermetallic compounds, metal matrix composites, chemical vapour deposited silicon carbide, nanocrystalline coatings and thermal barrier coatings. Part three provides case studies illustrating some of the challenges of high temperature corrosion to industry and how they can be overcome. Case studies include the petrochemical industry, modern incinerators and oxidation processing of electronic materials.This book is a valuable reference tool for engineers who develop heat resistant materials, mechanical engineers who design and maintain high temperature equipment and plant, and research scientists and students who study high temperature corrosion and protection of materials. - Describes the latest developments in understanding high temperature corrosion - Presents the latest research by the leading innovators from around the globe - Case studies are provided to illustrate key points

Facing the Heat Barrier
Facing the Heat Barrier

Author: T.A. Heppenheimer

Publisher: Courier Dover Publications

Published: 2018-09-12

Total Pages: 355

ISBN-13: 0486834514

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This volume from The NASA History Series presents an overview of the science of hypersonics, the study of flight at speeds at which the physics of flows is dominated by aerodynamic heating. The survey begins during the years immediately following World War II, with the first steps in hypersonic research: the development of missile nose cones and the X-15; the earliest concepts of hypersonic propulsion; and the origin of the scramjet engine. Next, it addresses the re-entry problem, which came to the forefront during the mid-1950s, showing how work in this area supported the manned space program and contributed to the development of the orbital shuttle. Subsequent chapters explore the fading of scramjet studies and the rise of the National Aerospace Plane (NASP) program of 1985–95, which sought to lay groundwork for single-stage vehicles. The program's ultimate shortcomings — in terms of aerodynamics, propulsion, and materials — are discussed, and the book concludes with a look at hypersonics in the post-NASP era, including the development of the X-33 and X-34 launch vehicles, further uses for scramjets, and advances in fluid mechanics. Clearly, ongoing research in hypersonics has yet to reach its full potential, and readers with an interest in aeronautics and astronautics will find this book a fascinating exploration of the field's history and future.