Flowing Matter

Flowing Matter

Author: Federico Toschi

Publisher: Springer Nature

Published: 2019-09-25

Total Pages: 309

ISBN-13: 3030233707

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This open access book, published in the Soft and Biological Matter series, presents an introduction to selected research topics in the broad field of flowing matter, including the dynamics of fluids with a complex internal structure -from nematic fluids to soft glasses- as well as active matter and turbulent phenomena. Flowing matter is a subject at the crossroads between physics, mathematics, chemistry, engineering, biology and earth sciences, and relies on a multidisciplinary approach to describe the emergence of the macroscopic behaviours in a system from the coordinated dynamics of its microscopic constituents. Depending on the microscopic interactions, an assembly of molecules or of mesoscopic particles can flow like a simple Newtonian fluid, deform elastically like a solid or behave in a complex manner. When the internal constituents are active, as for biological entities, one generally observes complex large-scale collective motions. Phenomenology is further complicated by the invariable tendency of fluids to display chaos at the large scales or when stirred strongly enough. This volume presents several research topics that address these phenomena encompassing the traditional micro-, meso-, and macro-scales descriptions, and contributes to our understanding of the fundamentals of flowing matter. This book is the legacy of the COST Action MP1305 “Flowing Matter”.


Brownian Motion

Brownian Motion

Author: Robert M. Mazo

Publisher: OUP Oxford

Published: 2008-10-23

Total Pages: 304

ISBN-13: 0191565083

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Brownian motion - the incessant motion of small particles suspended in a fluid - is an important topic in statistical physics and physical chemistry. This book studies its origin in molecular scale fluctuations, its description in terms of random process theory and also in terms of statistical mechanics. A number of new applications of these descriptions to physical and chemical processes, as well as statistical mechanical derivations and the mathematical background are discussed in detail. Graduate students, lecturers, and researchers in statistical physics and physical chemistry will find this an interesting and useful reference work.


Nonequilibrium Signatures and Phase Transitions in Active Matter and Beyond

Nonequilibrium Signatures and Phase Transitions in Active Matter and Beyond

Author: David Martin

Publisher:

Published: 2021

Total Pages: 0

ISBN-13:

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Active Matter deals with the study of colloidal systems for which Brownian motion is replaced by a persistent self-propulsion. The main motivation of Active Matter is to provide a theoretical framework describing ensembles of interacting living entities. Such an approach has already led to breakthroughs in our understanding of living systems, be it in bacterial dynamics or for the analysis of bird flocks. But the successes of active matter extend beyond living matter. The field has inspired a wealth of experiments dealing with artificial materials: Quincke rollers, Janus colloids, or shaken grains among other examples. In these setups, the active entities are synthetic units whose self-propulsion relies on a physical rather than biological mechanism. This manuscript contributes to the active matter roadmap along four axes: the exact study of a workhorse model of active dynamics, the characterization of the order in the flocking transition, the study of the interplay between flocks and jams, and the presentation of anisotropy-induced long-ranged correlations. As a starting point, I present in chapter 2 an exact perturbative analysis of the nonequilibrium model called Active Ornstein Uhlenbeck Particles (AOUPs). Using it, I derive analytically the steady-state distribution of an AOUP and quantify its departure from equilibrium through the characterization of three signatures: the deviation from Boltzmann distribution, the ratchet current, and the entropy production rate. I then generalize these results to the case of a particle experiencing both active and passive noises. The interplay between the two types of fluctuations leads to a rich phenomenology for the ratchet current and the entropy production rate when the temperature is varied: decline or non-monotonicity, divergence or decay at high T. Finally, I discuss the extension of these results to the case of N active particles in dimension d. In the third chapter, I revisit the transition to collective motion according to the type of microscopic alignment at play. Be it so-called metric or topological interactions, I show that the emergence of flocking generically remains discontinuous. To achieve this result, I present the notion of Fluctuation-Induced First Order Phase Transition (FIFOT) and apply it to models of collective motion. In the fourth chapter, I study the outbreak of Motility-Induced Phase Separation (MIPS) in flocking models. To this aim, I report the appearance of jams in dense assemblies of Quincke rollers. At the transition, which we dubbed active solidification, the jams propagate upstream the homogeneous flock of rollers. I then establish a theoretical model for active solidification which allows me to explore the rich phenomenology emerging from the interplay between MIPS and collective motion. By varying relevant 1 parameters, I predict the existence of a phase where flocking bands coexist with active jams. In the fifth chapter, I study long-ranged fluctuations in an active system. Starting from a microscopic dynamics only endowed with short-ranged anisotropic interactions, I show the emergence of macroscopic long-ranged density correlations. I then assess the effect of these correlations on the pressure exerted by the system in order to probe for a possible Casimir-like behaviour. Finally, in the last chapter, I conclude this manuscript by summarizing the contributions developed in the four previous chapters. For each of these works, I propose a possible future research direction. 2.


Synthesis and Characterization of Anisotropic Colloidal Particles

Synthesis and Characterization of Anisotropic Colloidal Particles

Author: Martin Hoffmann

Publisher: Logos Verlag Berlin

Published: 2010

Total Pages: 0

ISBN-13: 9783832526818

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Anisotropic colloids differ from isotropic particles as they may combine a non-spherical shape with a heterogeneous composition or surface chemistry. These versatile colloids have moved into the focus of various research groups in the fields of chemistry and physics. Hence, preparation pathways for novel model systems and their characterization are challenging aspects in fundamental research and material science. In the first part of this work, the author describes the synthesis and characterization of two colloidal systems with dumbbell-shaped core-shell morphology. The core consists of poly(methyl methacrylate) and poly(styrene). As a special feature, the attached shell layer promotes the change of the particle size and the aspect ratio by simply changing the ionic strength or temperature. Depolarized dynamic light scattering (DDLS) was used to investigate how these stimuli affect the translational and the rotational diffusion in the highly diluted state. The hydrodynamics of the particles could be well described with stick-boundary conditions by using analytical expressions for a double sphere, prolate ellipsoid and cylinder or the shell model, respectively. Electron and scanning force microscopy were applied to image the particle morphology in real space. The second part is devoted to the hydrodynamics of monodisperse, submicron-sized colloidal clusters, which consist of one to four spherical building blocks. The author demonstrates that the shell model is an excellent tool to identify the rotational relaxations which are accessible by DDLS.


Dynamical Theories of Brownian Motion

Dynamical Theories of Brownian Motion

Author: Edward Nelson

Publisher: Princeton University Press

Published: 1967-02-21

Total Pages: 147

ISBN-13: 0691079501

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These notes are based on a course of lectures given by Professor Nelson at Princeton during the spring term of 1966. The subject of Brownian motion has long been of interest in mathematical probability. In these lectures, Professor Nelson traces the history of earlier work in Brownian motion, both the mathematical theory, and the natural phenomenon with its physical interpretations. He continues through recent dynamical theories of Brownian motion, and concludes with a discussion of the relevance of these theories to quantum field theory and quantum statistical mechanics.


Brownian Dynamics at Boundaries and Interfaces

Brownian Dynamics at Boundaries and Interfaces

Author: Zeev Schuss

Publisher: Springer Science & Business Media

Published: 2013-08-15

Total Pages: 340

ISBN-13: 1461476879

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Brownian dynamics serve as mathematical models for the diffusive motion of microscopic particles of various shapes in gaseous, liquid, or solid environments. The renewed interest in Brownian dynamics is due primarily to their key role in molecular and cellular biophysics: diffusion of ions and molecules is the driver of all life. Brownian dynamics simulations are the numerical realizations of stochastic differential equations that model the functions of biological micro devices such as protein ionic channels of biological membranes, cardiac myocytes, neuronal synapses, and many more. Stochastic differential equations are ubiquitous models in computational physics, chemistry, biophysics, computer science, communications theory, mathematical finance theory, and many other disciplines. Brownian dynamics simulations of the random motion of particles, be it molecules or stock prices, give rise to mathematical problems that neither the kinetic theory of Maxwell and Boltzmann, nor Einstein’s and Langevin’s theories of Brownian motion could predict. This book takes the readers on a journey that starts with the rigorous definition of mathematical Brownian motion, and ends with the explicit solution of a series of complex problems that have immediate applications. It is aimed at applied mathematicians, physicists, theoretical chemists, and physiologists who are interested in modeling, analysis, and simulation of micro devices of microbiology. The book contains exercises and worked out examples throughout.


Out-of-equilibrium Soft Matter

Out-of-equilibrium Soft Matter

Author: Christina Kurzthaler

Publisher: Royal Society of Chemistry

Published: 2023-03-24

Total Pages: 348

ISBN-13: 1839169478

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The term active fluids refers to motions that are created by transforming energy from the surroundings into directed motion. There are many examples, both natural and synthetic, including individual swimming bacteria or motile cells, drops and bubbles that move owing to surface stresses (so-called Marangoni motions), and chemical- or optical-driven colloids. Investigations into active fluids provide new insights into non-equilibrium systems, have the potential for novel applications, and open new directions in physics, chemistry, biology and engineering. This book provides an expert introduction to active fluids systems, covering simple to complex environments. It explains the interplay of chemical processes and hydrodynamics, including the roles of mechanical and rheological properties across active fluids, with reference to experiments, theory, and simulations. These concepts are discussed for a variety of scenarios, such as the trajectories of microswimmers, cell crawling and fluid stirring, and apply to collective behaviours of dense suspensions and active gels. Emerging avenues of research are highlighted, ranging from the role of active processes for biological functions to programmable active materials, showcasing the exciting potential of this rapidly-evolving research field.