Metal Hydrides

Metal Hydrides

Author: William M. Mueller

Publisher: Elsevier

Published: 2013-09-12

Total Pages: 804

ISBN-13: 1483272931

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Metal Hydrides focuses on the theories of hydride formation as well as on experimental procedures involved in the formation of hydrides, the reactions that occur between hydrides and other media, and the physical and mechanical properties of the several classes of hydrides. The use of metal hydrides in the control of neutron energies is discussed, as are many other immediate or potential uses, e.g., in the production of high-purity hydrogen and in powder metallurgy. It is hoped that this book will serve as a valuable reference to students, research professors, and industrial researchers in metal hydrides and in allied fields. Selected chapters may serve specialists in other fields as an introduction to metal hydrides. The information contained herein will also be of lasting and practical value to the metallurgist, inorganic chemist, solid-state physicist, nuclear engineer, and others working with chemical or physical processes involving metal-hydrogen systems.


Boron Hydride Chemistry

Boron Hydride Chemistry

Author: Earl Muetterties

Publisher: Elsevier

Published: 2012-12-02

Total Pages: 545

ISBN-13: 032314649X

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Boron Hydride Chemistry covers the significant contributions of boron hydride research in the subjects of bonding, structure, and stereochemistry. This book contains 12 chapters that illustrate the merging of certain areas of boron hydride chemistry with other disciplines, such as organic, organometallic, and transition metal chemistry. After providing an overview of the general geometric, stereochemical, and dynamic stereochemical features of boron hydrides, this book goes on exploring the bonding theory and theoretical research on boron hydrides, with an emphasis on boron hydrides that have open polyhedral structures. These topics are followed by discussions on gas phase and solution reactions of borane and substituted boranes. A chapter focuses on the chemistry of cations containing boron atoms bonded to hydrogen. The remaining chapters examine the syntheses, structures, bonding, spectral properties, and chemistry of specific boron hydrides, including borazines, closo-boron hydrides, carboranes, icosahedral carboranes, and close- and nido-heteroboranes. Inorganic chemists and researchers, teachers, and undergraduate inorganic chemistry students will find this book invaluable.


Inorganic Hydrides

Inorganic Hydrides

Author: B. L. Shaw

Publisher: Elsevier

Published: 2013-10-22

Total Pages: 153

ISBN-13: 1483160327

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Inorganic Hydrides focuses on the hydrides of chemical elements. The hydrides discussed in this book are classified into four principal categories — ionic, covalent, transition metal hydrides, and metallic hydrides. Hydrides that do not fit into general classification, such as hydrides of copper and zinc, can be described as borderline hydrides and form a transition in type between the covalent hydrides of the later elements of the periodic table and the metallic hydrides of the transition elements. This text begins with an introduction to the classes of hydrides and hydrides of hydrogen, discussing element by element through frequent comparisons. The transition metal hydrides and metallic hydrides are also elaborated. This selection concludes with the chapter on bonding and bond strengths in hydrides, followed by the applications of infrared, Raman, and nuclear magnetic resonance spectroscopy. The general chemistry of water and its solvent properties are also briefly deliberated. This publication is suitable for undergraduates, particularly on covering the developments and chemistry of inorganic hydrides.


Hydrogen Materials Science and Chemistry of Metal Hydrides

Hydrogen Materials Science and Chemistry of Metal Hydrides

Author: Michael D. Hampton

Publisher: Springer Science & Business Media

Published: 2002-08-31

Total Pages: 500

ISBN-13: 9781402007316

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The study of metal hydrides opens up promising avenues for the solution of world energy problems, as well as casting light on the interactions of hydrogen with materials, the role of hydrogen in materials science, and the chemistry of metal hydrides, all of which are discussed in this book in terms that range from a global look at the new vision of energy and how hydrogen fits into that future to reviews such as a look at nickel hydride over the last 40 years. Very specific current research in such areas as hydrogen in materials science discuss properties like superconductivity, diffusion EMF, magnetic properties, physicochemical properties, phase composition, and permeability. Hydrogen can also be used as a processing or alloying agent, and in the synthesis of battery electrodes, composite materials and alloys. The interaction of hydrogen with many metals, composites and alloys offers potential hydrogen storage systems. There is also a discussion of hydrogen sensors.


Fundamentals of Chemistry

Fundamentals of Chemistry

Author: Frank Brescia

Publisher: Academic Press

Published: 2013-09-11

Total Pages: 54

ISBN-13: 1483213706

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Fundamentals of Chemistry, Fourth Edition covers the fundamentals of chemistry. The book describes the formation of ionic and covalent bonds; the Lewis theory of bonding; resonance; and the shape of molecules. The book then discusses the theory and some applications of the four kinds of spectroscopy: ultraviolet, infrared, nuclear (proton) magnetic resonance, and mass. Topics that combine environmental significance with descriptive chemistry, including atmospheric pollution from automobile exhaust; the metallurgy of iron and aluminum; corrosion; reactions involving ozone in the upper atmosphere; and the methods of controlling the pollution of air and water, are also considered. Chemists and students taking courses related to chemistry and environmental chemistry will find the book invaluable.


The Effect of Hydrogen and Hydrides on the Integrity of Zirconium Alloy Components

The Effect of Hydrogen and Hydrides on the Integrity of Zirconium Alloy Components

Author: Manfred P. Puls

Publisher: Springer Science & Business Media

Published: 2012-08-04

Total Pages: 475

ISBN-13: 1447141954

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By drawing together the current theoretical and experimental understanding of the phenomena of delayed hydride cracking (DHC) in zirconium alloys, The Effect of Hydrogen and Hydrides on the Integrity of Zirconium Alloy Components: Delayed Hydride Cracking provides a detailed explanation focusing on the properties of hydrogen and hydrides in these alloys. Whilst the emphasis lies on zirconium alloys, the combination of both the empirical and mechanistic approaches creates a solid understanding that can also be applied to other hydride forming metals. This up-to-date reference focuses on documented research surrounding DHC, including current methodologies for design and assessment of the results of periodic in-service inspections of pressure tubes in nuclear reactors. Emphasis is placed on showing how our understanding of DHC is supported by progress in general understanding of such broad fields as the study of hysteresis associated with first order phase transformations, phase relationships in coherent crystalline metallic solids, the physics of point and line defects, diffusion of substitutional and interstitial atoms in crystalline solids, and continuum fracture and solid mechanics. Furthermore, an account of current methodologies is given illustrating how such understanding of hydrogen, hydrides and DHC in zirconium alloys underpins these methodologies for assessments of real life cases in the Canadian nuclear industry. The all-encompassing approach makes The Effect of Hydrogen and Hydrides on the Integrity of Zirconium Alloy Component: Delayed Hydride Cracking an ideal reference source for students, researchers and industry professionals alike.


The Organometallic Chemistry of the Transition Metals

The Organometallic Chemistry of the Transition Metals

Author: Robert H. Crabtree

Publisher: John Wiley & Sons

Published: 2011-09-20

Total Pages: 418

ISBN-13: 1118210859

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"One impressive and compressive book. . . . This review would have to be book size to do full justice to all the insights in this volume." —Journal of Metals Online Fully updated and expanded to reflect recent advances, this Fifth Edition of the classic text provides students and professional chemists with a comprehensive introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications. With increased focus on organic synthesis applications, nanoparticle science, and green chemistry, the Fifth Edition brings this vital resource up to date. New to the Fifth Edition: Chapters have been updated with relevant examples in the field, modern trends, and new applications; the organic applications chapter has been completely rewritten New end-of-chapter problems, along with their solutions Coverage enhanced with developments in nanoparticle science Increased focus on green chemistry An unparalleled pedagogic resource as well as a valuable working reference for professional chemists, with comprehensive coverage and up-to-date information, students and researchers in organic and organometallic chemistry will turn to The Organometallic Chemistry of the Transition Metals, Fifth Edition for the critical information they need on organometallic compounds, their preparation, and their use in synthesis.