Alicyclic Compounds
Alicyclic Compounds

Author: Malcolm Sainsbury

Publisher: Elsevier

Published: 2016-06-06

Total Pages: 667

ISBN-13: 148310091X

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Rodd's Chemistry of Carbon Compounds, Volume II: Alicyclic Compounds focuses on alicyclic chemistry. The book first ponders on acyclic and monocyclic monoterpenoids, including artemisyl, santolinyl, chrysanthemyl, and other irregular systems; naturally occurring halogenated monoterpenoids; cyclobutanes; and tetramethylcyclohexanes. The text discusses the carotenoid group of natural products. Trends in carotenoid chemical research; improved methodology; optical isomerism including aliene isomerism; and geometrical isomerism are described. The book discusses cycloheptanes and cyclooctanes, large alicyclic ring systems, and polycarbonic compounds with separate ring systems and spiro compounds. The text describes polycyclic compounds and polycarbocyclic bridged ring compounds, and then discusses bicarbocyclic natural products. The Wagner-Meerwein rearrangement; camphor and related compounds; fenchone and related compounds; and carane, thujane, and pinane groups are also considered. The text is a valuable reference for readers interested in the study of carbon compounds.

Stereochemical Analysis of Alicyclic Compounds by C-13 NMR Spectroscopy
Stereochemical Analysis of Alicyclic Compounds by C-13 NMR Spectroscopy

Author: James K. Whitesell

Publisher: Springer

Published: 1987-04-30

Total Pages: 248

ISBN-13:

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Through numerous conversations with other synthetic chemists it became apparent that the great power of carbon nuclear magnetic resonance was being significantly underutilized. In our own work we have found that 13C spectroscopy is a more powerful tool than IH NMR spectroscopy, especially for probing subtle stereochemical questions in complicated systems. This is especially true in five membered ring compounds where IH NMR is at a particular disadvantage. The two techniques can be used independently to solve the same question-that of stereochemistry - but they do so in different ways. Advantage can be taken in IH NMR of a relatively consistent relationship between stereochemical orientation and coupling constants between vicinal protons, while in 13C NMR it is the correlation between spatial relationships of non-hydrogen, y substituents and their effect on chemical shift that can be used to assign stereochemistry. It was also clear that the use of 13C NMR required a different approach to problem solving than that typically used with IH NMR. While the latter technique could be employed with a very general approach (e.g., the Karplus equation), 13C NMR would, at least for the immediate future, require a relatively extensive set of model systems from which the consequences of stereochemical changes could be derived for any given carbon framework.

Alicyclic Chemistry
Alicyclic Chemistry

Author: F. J. McQuillin

Publisher: CUP Archive

Published: 1983-08-04

Total Pages: 248

ISBN-13: 9780521283915

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This 1983 book aims to present the experimental basis for concepts surrounding alicyclic chemistry, a fundamentally important area of chemistry.

Tables of Spectral Data for Structure Determination of Organic Compounds
Tables of Spectral Data for Structure Determination of Organic Compounds

Author: Ernö Pretsch

Publisher: Springer Science & Business Media

Published: 2013-06-29

Total Pages: 325

ISBN-13: 3662224550

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Although numerical data are, in principle, universal, the compilations presented in this book are extensively annotated and interleaved with text. This translation of the second German edition has been prepared to facilitate the use of this work, with all its valuable detail, by the large community of English-speaking scientists. Translation has also provided an opportunity to correct and revise the text, and to update the nomenclature. Fortunately, spectroscopic data and their relationship with structure do not change much with time so one can predict that this book will, for a long period of time, continue to be very useful to organic chemists involved in the identification of organic compounds or the elucidation of their structure. Klaus Biemann Cambridge, MA, April 1983 Preface to the First German Edition Making use of the information provided by various spectroscopic tech niques has become a matter of routine for the analytically oriented organic chemist. Those who have graduated recently received extensive training in these techniques as part of the curriculum while their older colleagues learned to use these methods by necessity. One can, therefore, assume that chemists are well versed in the proper choice of the methods suitable for the solution of a particular problem and to translate the experimental data into structural information.